Novel 1,10-diaza-18-crown-6 derivatives View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2014-03

AUTHORS

R. G. Kostyanovsky, K. A. Lyssenko, O. G. Nabiev, G. K. Kadorkina, I. I. Chervin

ABSTRACT

Reaction of 1,10-bis(methoxymethyl)-1,10-diaza-18-crown-6 (1) with trimethylsilyl azide resulted in hitherto unknown 1,10-bis(azidomethyl)-1,10-diaza-18-crown-6 (2) and novel ionic compound 1,10-bis(azide anion)-1,10-dihydro-1,10-diaza-18-crown-6 (3). Compound 2 rnneacted with dimethyl acetylenedicarboxylate to give 1,10-bis(4,5-dimethoxycarbonyltriazolomethyl)-1,10-diaza-18-crown-6 (4). Carbamoylation of 1,10-diaza-18-crown-6 (5) with optically active α-phenylethyl amine yielded optically active 1,10-bis(α-phenylethylcarbamoyl)-1,10-diaza-18-crown-6 (6).

PAGES

772-774

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s11172-014-0507-9

DOI

http://dx.doi.org/10.1007/s11172-014-0507-9

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1053418305


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