Influence of a doubly charged cation nature on the formation and properties of mixed oxides MAlOx (M = Mg2+, Zn2+, ... View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2013-11

AUTHORS

O. B. Belskaya, N. N. Leont’eva, T. I. Gulyaeva, S. V. Cherepanova, V. P. Talzi, V. A. Drozdov, V. A. Likholobov

ABSTRACT

Influence of the nature of a doubly charged cation in the layered double hydroxides (LDH) on the conditions of formation and properties of mixed oxide phase MAlOx (M = Mg2+, Zn2+ and Ni2+), its ability to reconstruct the structure of the original precursor under contact with water has been studied. Hydrotalcite-like compounds and corresponding oxides with different M2+: M3+ ratio were investigated by XRD, TEM, TG-DTG-DTA, 27Al NMR, N2 adsorption, and differentiating dissolution. It has been found that the nature of the cation M2+ influences the conditions of LDH thermal decomposition, structural and textural characteristics of the formed mixed oxides. The obtained data can be used to synthesize the oxide supports with desired acid-base and adsorption properties. More... »

PAGES

2349-2361

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s11172-013-0341-5

DOI

http://dx.doi.org/10.1007/s11172-013-0341-5

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1014546287


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