Synthesis of 12-vertex mixed ligand closo-cobaltacarborane complexes and molecular structure of [3,3-(Ph2P(CH2)2PPh2)-3-Cl-closo-3,1,2-CoC2B9H11] View Full Text


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Article Info

DATE

2013-08

AUTHORS

A. P. Tyurin, A. F. Smol’yakov, F. M. Dolgushin, I. A. Godovikov, I. T. Chizhevsky

ABSTRACT

A reaction of complexes CoCl2(dppe) (dppe is the 1,2-bis(diphenylphosphino)ethane) or CoCl2(dppp) (dppp is the 1,3-bis(diphenylphosphino)propane) with [K][7,8-nido-C2B9H12] upon reflux in benzene led to the mixed ligand closo-cobaltacarboranes [3,3-(Ph2P(CH2)nPPh2)-3-Cl-closo-3,1,2-CoIIIC2B9H11] (n = 2 and 3, respectively) in moderate yields (34 and 16%). The structure of the 18-electron complexes in solution and the solid state was studied by NMR and IR spectroscopy, the structure in the case of the closo-complex with dppe-ligand was confirmed by X-ray crystallography. More... »

PAGES

1938-1940

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s11172-013-0280-1

DOI

http://dx.doi.org/10.1007/s11172-013-0280-1

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1050330332


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