Synthesis and structure of diethyl (1-benzyloxycarbonylamino-1-carboranyl-3,3,3-trifluoropropyl)phosphonate View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2013-08

AUTHORS

S. V. Timofeev, E. A. Prikaznova, Z. A. Starikova, S. N. Osipov, V. I. Bregadze

ABSTRACT

A reaction of C-carboranylmethylmagnesium bromide with diethyl (N-benzyloxycarbonyl-2,2,2-trifluoroethaneimidoyl)phosphonate gave P- and N-protected aminophosphonic acid, an organophosphorus analog of alanine. The phosphonate was characterized by 1H, 19F, and 31P NMR spectroscopy. X-ray diffraction analysis of diethyl (1-benzyloxycarbonylamino-1-carboranyl-3,3,3-trifluoropropyl)phosphonate showed that the molecules form dimers in crystals due to the intermolecular hydrogen bond.

PAGES

1934-1937

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s11172-013-0279-7

DOI

http://dx.doi.org/10.1007/s11172-013-0279-7

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1049971797


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