Synthesis and structure of diethyl (1-benzyloxycarbonylamino-1-carboranyl-3,3,3-trifluoropropyl)phosphonate View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2013-08

AUTHORS

S. V. Timofeev, E. A. Prikaznova, Z. A. Starikova, S. N. Osipov, V. I. Bregadze

ABSTRACT

A reaction of C-carboranylmethylmagnesium bromide with diethyl (N-benzyloxycarbonyl-2,2,2-trifluoroethaneimidoyl)phosphonate gave P- and N-protected aminophosphonic acid, an organophosphorus analog of alanine. The phosphonate was characterized by 1H, 19F, and 31P NMR spectroscopy. X-ray diffraction analysis of diethyl (1-benzyloxycarbonylamino-1-carboranyl-3,3,3-trifluoropropyl)phosphonate showed that the molecules form dimers in crystals due to the intermolecular hydrogen bond.

PAGES

1934-1937

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s11172-013-0279-7

DOI

http://dx.doi.org/10.1007/s11172-013-0279-7

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1049971797


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0306", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Physical Chemistry (incl. Structural)", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "Russian Academy of Sciences", 
          "id": "https://www.grid.ac/institutes/grid.4886.2", 
          "name": [
            "A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991, Moscow, Russian Federation"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Timofeev", 
        "givenName": "S. V.", 
        "id": "sg:person.013515115560.47", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013515115560.47"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Russian Academy of Sciences", 
          "id": "https://www.grid.ac/institutes/grid.4886.2", 
          "name": [
            "A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991, Moscow, Russian Federation"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Prikaznova", 
        "givenName": "E. A.", 
        "id": "sg:person.013251676125.63", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013251676125.63"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Russian Academy of Sciences", 
          "id": "https://www.grid.ac/institutes/grid.4886.2", 
          "name": [
            "A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991, Moscow, Russian Federation"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Starikova", 
        "givenName": "Z. A.", 
        "id": "sg:person.014473641160.05", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014473641160.05"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Russian Academy of Sciences", 
          "id": "https://www.grid.ac/institutes/grid.4886.2", 
          "name": [
            "A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991, Moscow, Russian Federation"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Osipov", 
        "givenName": "S. N.", 
        "id": "sg:person.01211416630.10", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01211416630.10"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Russian Academy of Sciences", 
          "id": "https://www.grid.ac/institutes/grid.4886.2", 
          "name": [
            "A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991, Moscow, Russian Federation"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Bregadze", 
        "givenName": "V. I.", 
        "id": "sg:person.01072634024.08", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01072634024.08"
        ], 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "https://doi.org/10.1002/anie.199309501", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1003189122"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/s11172-010-0051-1", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1027874960", 
          "https://doi.org/10.1007/s11172-010-0051-1"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/s11172-010-0051-1", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1027874960", 
          "https://doi.org/10.1007/s11172-010-0051-1"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/s11172-007-0118-9", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1046186025", 
          "https://doi.org/10.1007/s11172-007-0118-9"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/cr941195u", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1053981434"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/cr941195u", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1053981434"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ic50010a007", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055567051"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/jm00055a001", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055933820"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/jm00396a007", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055946134"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1055/s-2004-825594", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1057433535"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "2013-08", 
    "datePublishedReg": "2013-08-01", 
    "description": "A reaction of C-carboranylmethylmagnesium bromide with diethyl (N-benzyloxycarbonyl-2,2,2-trifluoroethaneimidoyl)phosphonate gave P- and N-protected aminophosphonic acid, an organophosphorus analog of alanine. The phosphonate was characterized by 1H, 19F, and 31P NMR spectroscopy. X-ray diffraction analysis of diethyl (1-benzyloxycarbonylamino-1-carboranyl-3,3,3-trifluoropropyl)phosphonate showed that the molecules form dimers in crystals due to the intermolecular hydrogen bond.", 
    "genre": "research_article", 
    "id": "sg:pub.10.1007/s11172-013-0279-7", 
    "inLanguage": [
      "en"
    ], 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1022309", 
        "issn": [
          "1066-5285", 
          "1573-9171"
        ], 
        "name": "Russian Chemical Bulletin", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "8", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "62"
      }
    ], 
    "name": "Synthesis and structure of diethyl (1-benzyloxycarbonylamino-1-carboranyl-3,3,3-trifluoropropyl)phosphonate", 
    "pagination": "1934-1937", 
    "productId": [
      {
        "name": "readcube_id", 
        "type": "PropertyValue", 
        "value": [
          "ee0c90cddc3def80bef02a29555853547e8c8df8fff0651147d649a7b7eba299"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1007/s11172-013-0279-7"
        ]
      }, 
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1049971797"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1007/s11172-013-0279-7", 
      "https://app.dimensions.ai/details/publication/pub.1049971797"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2019-04-10T17:36", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000001_0000000264/records_8672_00000534.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "http://link.springer.com/10.1007%2Fs11172-013-0279-7"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/s11172-013-0279-7'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/s11172-013-0279-7'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/s11172-013-0279-7'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/s11172-013-0279-7'


 

This table displays all metadata directly associated to this object as RDF triples.

115 TRIPLES      21 PREDICATES      35 URIs      19 LITERALS      7 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1007/s11172-013-0279-7 schema:about anzsrc-for:03
2 anzsrc-for:0306
3 schema:author N2eb740aa82534ab2a53d1cc547952e85
4 schema:citation sg:pub.10.1007/s11172-007-0118-9
5 sg:pub.10.1007/s11172-010-0051-1
6 https://doi.org/10.1002/anie.199309501
7 https://doi.org/10.1021/cr941195u
8 https://doi.org/10.1021/ic50010a007
9 https://doi.org/10.1021/jm00055a001
10 https://doi.org/10.1021/jm00396a007
11 https://doi.org/10.1055/s-2004-825594
12 schema:datePublished 2013-08
13 schema:datePublishedReg 2013-08-01
14 schema:description A reaction of C-carboranylmethylmagnesium bromide with diethyl (N-benzyloxycarbonyl-2,2,2-trifluoroethaneimidoyl)phosphonate gave P- and N-protected aminophosphonic acid, an organophosphorus analog of alanine. The phosphonate was characterized by 1H, 19F, and 31P NMR spectroscopy. X-ray diffraction analysis of diethyl (1-benzyloxycarbonylamino-1-carboranyl-3,3,3-trifluoropropyl)phosphonate showed that the molecules form dimers in crystals due to the intermolecular hydrogen bond.
15 schema:genre research_article
16 schema:inLanguage en
17 schema:isAccessibleForFree false
18 schema:isPartOf N094329fa425441d49fed6fd1287553a6
19 N48a73502c47048228e7d415e0c492a4f
20 sg:journal.1022309
21 schema:name Synthesis and structure of diethyl (1-benzyloxycarbonylamino-1-carboranyl-3,3,3-trifluoropropyl)phosphonate
22 schema:pagination 1934-1937
23 schema:productId N631852decdf845f391e7bd54a0802960
24 N6e97bc4bdd37482db7c0cbb511b9229a
25 N752178e144d545e49dbfcf876816af74
26 schema:sameAs https://app.dimensions.ai/details/publication/pub.1049971797
27 https://doi.org/10.1007/s11172-013-0279-7
28 schema:sdDatePublished 2019-04-10T17:36
29 schema:sdLicense https://scigraph.springernature.com/explorer/license/
30 schema:sdPublisher Nc955725e4cc0414087d8001e4cdd80f7
31 schema:url http://link.springer.com/10.1007%2Fs11172-013-0279-7
32 sgo:license sg:explorer/license/
33 sgo:sdDataset articles
34 rdf:type schema:ScholarlyArticle
35 N094329fa425441d49fed6fd1287553a6 schema:issueNumber 8
36 rdf:type schema:PublicationIssue
37 N2eb740aa82534ab2a53d1cc547952e85 rdf:first sg:person.013515115560.47
38 rdf:rest Na794f632be2b42fa8ae955e8d3c55382
39 N48a73502c47048228e7d415e0c492a4f schema:volumeNumber 62
40 rdf:type schema:PublicationVolume
41 N631852decdf845f391e7bd54a0802960 schema:name readcube_id
42 schema:value ee0c90cddc3def80bef02a29555853547e8c8df8fff0651147d649a7b7eba299
43 rdf:type schema:PropertyValue
44 N6e97bc4bdd37482db7c0cbb511b9229a schema:name doi
45 schema:value 10.1007/s11172-013-0279-7
46 rdf:type schema:PropertyValue
47 N752178e144d545e49dbfcf876816af74 schema:name dimensions_id
48 schema:value pub.1049971797
49 rdf:type schema:PropertyValue
50 N7534fffbb2e349b7b5278d0d7f387901 rdf:first sg:person.014473641160.05
51 rdf:rest Necaa4798f55e49bf94590d9fbeec5a5b
52 Na794f632be2b42fa8ae955e8d3c55382 rdf:first sg:person.013251676125.63
53 rdf:rest N7534fffbb2e349b7b5278d0d7f387901
54 Na85048b2039d4569b6c0f65b6d962f93 rdf:first sg:person.01072634024.08
55 rdf:rest rdf:nil
56 Nc955725e4cc0414087d8001e4cdd80f7 schema:name Springer Nature - SN SciGraph project
57 rdf:type schema:Organization
58 Necaa4798f55e49bf94590d9fbeec5a5b rdf:first sg:person.01211416630.10
59 rdf:rest Na85048b2039d4569b6c0f65b6d962f93
60 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
61 schema:name Chemical Sciences
62 rdf:type schema:DefinedTerm
63 anzsrc-for:0306 schema:inDefinedTermSet anzsrc-for:
64 schema:name Physical Chemistry (incl. Structural)
65 rdf:type schema:DefinedTerm
66 sg:journal.1022309 schema:issn 1066-5285
67 1573-9171
68 schema:name Russian Chemical Bulletin
69 rdf:type schema:Periodical
70 sg:person.01072634024.08 schema:affiliation https://www.grid.ac/institutes/grid.4886.2
71 schema:familyName Bregadze
72 schema:givenName V. I.
73 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01072634024.08
74 rdf:type schema:Person
75 sg:person.01211416630.10 schema:affiliation https://www.grid.ac/institutes/grid.4886.2
76 schema:familyName Osipov
77 schema:givenName S. N.
78 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01211416630.10
79 rdf:type schema:Person
80 sg:person.013251676125.63 schema:affiliation https://www.grid.ac/institutes/grid.4886.2
81 schema:familyName Prikaznova
82 schema:givenName E. A.
83 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013251676125.63
84 rdf:type schema:Person
85 sg:person.013515115560.47 schema:affiliation https://www.grid.ac/institutes/grid.4886.2
86 schema:familyName Timofeev
87 schema:givenName S. V.
88 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013515115560.47
89 rdf:type schema:Person
90 sg:person.014473641160.05 schema:affiliation https://www.grid.ac/institutes/grid.4886.2
91 schema:familyName Starikova
92 schema:givenName Z. A.
93 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014473641160.05
94 rdf:type schema:Person
95 sg:pub.10.1007/s11172-007-0118-9 schema:sameAs https://app.dimensions.ai/details/publication/pub.1046186025
96 https://doi.org/10.1007/s11172-007-0118-9
97 rdf:type schema:CreativeWork
98 sg:pub.10.1007/s11172-010-0051-1 schema:sameAs https://app.dimensions.ai/details/publication/pub.1027874960
99 https://doi.org/10.1007/s11172-010-0051-1
100 rdf:type schema:CreativeWork
101 https://doi.org/10.1002/anie.199309501 schema:sameAs https://app.dimensions.ai/details/publication/pub.1003189122
102 rdf:type schema:CreativeWork
103 https://doi.org/10.1021/cr941195u schema:sameAs https://app.dimensions.ai/details/publication/pub.1053981434
104 rdf:type schema:CreativeWork
105 https://doi.org/10.1021/ic50010a007 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055567051
106 rdf:type schema:CreativeWork
107 https://doi.org/10.1021/jm00055a001 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055933820
108 rdf:type schema:CreativeWork
109 https://doi.org/10.1021/jm00396a007 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055946134
110 rdf:type schema:CreativeWork
111 https://doi.org/10.1055/s-2004-825594 schema:sameAs https://app.dimensions.ai/details/publication/pub.1057433535
112 rdf:type schema:CreativeWork
113 https://www.grid.ac/institutes/grid.4886.2 schema:alternateName Russian Academy of Sciences
114 schema:name A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991, Moscow, Russian Federation
115 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...