Unusual crystal and molecular structure of palladium iminoquinonoid complex Pd2Cl2(PPh3)2L (L = N,N′-di(4-methyl-4-trichloromethylcyclohexa-2,5-dien-1-ylidene)hydrazine) View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2013-08

AUTHORS

Z. A. Starikova

ABSTRACT

The structure of the first iminoquinonoid complex Pd2Cl2(PPh3)2L·0.4(Me2CO), where L = N,N′-di(4-methyl-4-trichloromethylcyclohexa-2,5-dien-1-ylidene)hydrazine, was established by X-ray crystallography. The centrosymmetric and non-centrosymmetric molecules of meso-form (RS) and the molecule of optically active (SS) threo-form were found to be simultaneously present (cocrystallize) in the crystal. The molecule in the crystal has a general formula [Pd(meso-L)]2[Pd(threo-L)]. More... »

PAGES

1866-1870

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s11172-013-0268-x

DOI

http://dx.doi.org/10.1007/s11172-013-0268-x

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1024553533


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