Syntheses and structures of magnesium, calcium, europium, gallium, and zinc complexes with bis(imino)acenaphthene ligands View Full Text


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Article Info

DATE

2013-08

AUTHORS

I. L. Fedushkin, A. A. Skatova, N. L. Bazyakina, V. A. Chudakova, N. M. Khvoinova, A. S. Nikipelov, O. V. Eremenko, A. V. Piskunov, G. K. Fukin, K. A. Lyssenko

ABSTRACT

The reduction of 1,2-bis(trimethylsilylimino)acenaphthene and 1,2-bis{[3,5-bis(trifluoromethylphenyl)]imino}acenaphthene with metals gave magnesium, calcium, europium, zinc, and gallium complexes containing radical-anion and dianionic ligands of the 1,2-diiminoacenaphthene type. Their structures were studied by 1H NMR, ESR, and/or single-crystal X-ray analysis. Some chemical transformations of the complexes were carried out.

PAGES

1815-1828

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s11172-013-0262-3

DOI

http://dx.doi.org/10.1007/s11172-013-0262-3

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1039963469


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Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/s11172-013-0262-3'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/s11172-013-0262-3'

Turtle is a human-readable linked data format.

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RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/s11172-013-0262-3'


 

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