Crystals of the CuII complex with nitronyl nitroxide and imino nitroxide exhibiting mechanical activity View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2013-08

AUTHORS

E. V. Tretyakov, S. V. Fokin, E. Yu. Fursova, O. V. Kuznetsova, G. V. Romanenko, R. Z. Sagdeev, V. I. Ovcharenko

ABSTRACT

As part of continuing studies of multispin compounds capable of exhibiting chemomechanical activity, a series of heterospin solids of the composition [Cu(hfac)2LxL′2−x], [Cu(hfac)2L′], [Cu2(Piv)4L′2]·0.5C6H14, and [Cu2(hfac)2(Piv)2L′2], where hfac is the hexafluoroacetylacetonate anion, L is 4,4,5,5-tetramethyl-2-(1-methyl-1H-imidazol-5-yl)-4,5-dihydro-1H-imidazole-3-oxide-1-oxyl, L′ is the imino nitroxide analog of L, viz., 4,4,5,5-tetramethyl-2-(1-methyl-1H-imidazol-5-yl)-4,5-dihydro-1H-imidazole-1-oxyl, and Piv is the 2,2-dimethylpropionate anion, were synthesized and characterized. The packing of the synthesized crystals of the solid solutions [Cu(hfac)2LxL′2-x], where L predominates, is similar to that for [Cu(hfac)2L2], and these crystals are able to undergo chemomechanical motion. On the contrary, the crystals of [Cu(hfac)2LxL′2−x], where L′ predominates, have structural parameters similar to those of [Cu(hfac)2L′2] and do not exhibit thermally activated or photoactivated chemomechanical activity. More... »

PAGES

1803-1808

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s11172-013-0260-5

DOI

http://dx.doi.org/10.1007/s11172-013-0260-5

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1018957300


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