Kinetics of thermoinitiated oligomerization of 3,3′-(2,4,6-triethyl-1,3-phenylene)bis(5-methyl-1,2,4-oxadiazole) View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2013-06

AUTHORS

T. K. Goncharov, A. I. Kazakov, Z. G. Aliev, G. V. Lagodzinskaya, E. L. Ignat’eva, L. S. Kurochkina

ABSTRACT

The crystal structure of 3,3′-(2,4,6-triethyl-1,3-phenylene)bis(5-methyl-1,2,4-oxadiazole), which models the cross-linking fragment of polynitriles by benzodinitrile oxides, was determined by X-ray diffraction analysis. The kinetic regularities of its thermoinitiated oligomerization were studied by isothermal calorimetry and spectrophotometry. The process proceeds with self-acceleration, and the Arrhenius dependences of the initial and maximum reaction rates were determined. The reaction accelaration is determined by an increase in the viscosity of the reaction medium. Possible mechanisms were proposed for oligomerization. More... »

PAGES

1434-1441

References to SciGraph publications

  • 1991-07. Synthesis of sterically hindered aromatic aldehydes in RUSSIAN CHEMICAL BULLETIN
  • Identifiers

    URI

    http://scigraph.springernature.com/pub.10.1007/s11172-013-0206-y

    DOI

    http://dx.doi.org/10.1007/s11172-013-0206-y

    DIMENSIONS

    https://app.dimensions.ai/details/publication/pub.1053574763


    Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
    Incoming Citations Browse incoming citations for this publication using opencitations.net

    JSON-LD is the canonical representation for SciGraph data.

    TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

    [
      {
        "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
        "about": [
          {
            "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
            "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
            "name": "Chemical Sciences", 
            "type": "DefinedTerm"
          }
        ], 
        "author": [
          {
            "affiliation": {
              "alternateName": "Institute of Problems of Chemical Physics, Russian Academy of Sciences, 1 prosp. Akad. Semenova, 142432, Chernogolovka, Moscow Region, Russian Federation", 
              "id": "http://www.grid.ac/institutes/grid.418949.9", 
              "name": [
                "Institute of Problems of Chemical Physics, Russian Academy of Sciences, 1 prosp. Akad. Semenova, 142432, Chernogolovka, Moscow Region, Russian Federation"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Goncharov", 
            "givenName": "T. K.", 
            "id": "sg:person.016446307341.00", 
            "sameAs": [
              "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016446307341.00"
            ], 
            "type": "Person"
          }, 
          {
            "affiliation": {
              "alternateName": "Institute of Problems of Chemical Physics, Russian Academy of Sciences, 1 prosp. Akad. Semenova, 142432, Chernogolovka, Moscow Region, Russian Federation", 
              "id": "http://www.grid.ac/institutes/grid.418949.9", 
              "name": [
                "Institute of Problems of Chemical Physics, Russian Academy of Sciences, 1 prosp. Akad. Semenova, 142432, Chernogolovka, Moscow Region, Russian Federation"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Kazakov", 
            "givenName": "A. I.", 
            "id": "sg:person.07506317211.96", 
            "sameAs": [
              "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.07506317211.96"
            ], 
            "type": "Person"
          }, 
          {
            "affiliation": {
              "alternateName": "Institute of Problems of Chemical Physics, Russian Academy of Sciences, 1 prosp. Akad. Semenova, 142432, Chernogolovka, Moscow Region, Russian Federation", 
              "id": "http://www.grid.ac/institutes/grid.418949.9", 
              "name": [
                "Institute of Problems of Chemical Physics, Russian Academy of Sciences, 1 prosp. Akad. Semenova, 142432, Chernogolovka, Moscow Region, Russian Federation"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Aliev", 
            "givenName": "Z. G.", 
            "id": "sg:person.010574144735.96", 
            "sameAs": [
              "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010574144735.96"
            ], 
            "type": "Person"
          }, 
          {
            "affiliation": {
              "alternateName": "Institute of Problems of Chemical Physics, Russian Academy of Sciences, 1 prosp. Akad. Semenova, 142432, Chernogolovka, Moscow Region, Russian Federation", 
              "id": "http://www.grid.ac/institutes/grid.418949.9", 
              "name": [
                "Institute of Problems of Chemical Physics, Russian Academy of Sciences, 1 prosp. Akad. Semenova, 142432, Chernogolovka, Moscow Region, Russian Federation"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Lagodzinskaya", 
            "givenName": "G. V.", 
            "id": "sg:person.01076212217.01", 
            "sameAs": [
              "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01076212217.01"
            ], 
            "type": "Person"
          }, 
          {
            "affiliation": {
              "alternateName": "Institute of Problems of Chemical Physics, Russian Academy of Sciences, 1 prosp. Akad. Semenova, 142432, Chernogolovka, Moscow Region, Russian Federation", 
              "id": "http://www.grid.ac/institutes/grid.418949.9", 
              "name": [
                "Institute of Problems of Chemical Physics, Russian Academy of Sciences, 1 prosp. Akad. Semenova, 142432, Chernogolovka, Moscow Region, Russian Federation"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Ignat\u2019eva", 
            "givenName": "E. L.", 
            "id": "sg:person.014715402315.55", 
            "sameAs": [
              "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014715402315.55"
            ], 
            "type": "Person"
          }, 
          {
            "affiliation": {
              "alternateName": "Institute of Problems of Chemical Physics, Russian Academy of Sciences, 1 prosp. Akad. Semenova, 142432, Chernogolovka, Moscow Region, Russian Federation", 
              "id": "http://www.grid.ac/institutes/grid.418949.9", 
              "name": [
                "Institute of Problems of Chemical Physics, Russian Academy of Sciences, 1 prosp. Akad. Semenova, 142432, Chernogolovka, Moscow Region, Russian Federation"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Kurochkina", 
            "givenName": "L. S.", 
            "id": "sg:person.015472062537.13", 
            "sameAs": [
              "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015472062537.13"
            ], 
            "type": "Person"
          }
        ], 
        "citation": [
          {
            "id": "sg:pub.10.1007/bf00961246", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1031171188", 
              "https://doi.org/10.1007/bf00961246"
            ], 
            "type": "CreativeWork"
          }
        ], 
        "datePublished": "2013-06", 
        "datePublishedReg": "2013-06-01", 
        "description": "The crystal structure of 3,3\u2032-(2,4,6-triethyl-1,3-phenylene)bis(5-methyl-1,2,4-oxadiazole), which models the cross-linking fragment of polynitriles by benzodinitrile oxides, was determined by X-ray diffraction analysis. The kinetic regularities of its thermoinitiated oligomerization were studied by isothermal calorimetry and spectrophotometry. The process proceeds with self-acceleration, and the Arrhenius dependences of the initial and maximum reaction rates were determined. The reaction accelaration is determined by an increase in the viscosity of the reaction medium. Possible mechanisms were proposed for oligomerization.", 
        "genre": "article", 
        "id": "sg:pub.10.1007/s11172-013-0206-y", 
        "inLanguage": "en", 
        "isAccessibleForFree": false, 
        "isPartOf": [
          {
            "id": "sg:journal.1022309", 
            "issn": [
              "1063-5211", 
              "1026-3500"
            ], 
            "name": "Russian Chemical Bulletin", 
            "publisher": "Springer Nature", 
            "type": "Periodical"
          }, 
          {
            "issueNumber": "6", 
            "type": "PublicationIssue"
          }, 
          {
            "type": "PublicationVolume", 
            "volumeNumber": "62"
          }
        ], 
        "keywords": [
          "X-ray diffraction analysis", 
          "reaction medium", 
          "crystal structure", 
          "diffraction analysis", 
          "kinetic regularities", 
          "maximum reaction rate", 
          "reaction rate", 
          "oligomerization", 
          "Arrhenius dependence", 
          "isothermal calorimetry", 
          "polynitriles", 
          "calorimetry", 
          "oxide", 
          "spectrophotometry", 
          "kinetics", 
          "possible mechanism", 
          "viscosity", 
          "structure", 
          "fragments", 
          "dependence", 
          "medium", 
          "process", 
          "mechanism", 
          "analysis", 
          "accelaration", 
          "increase", 
          "rate", 
          "regularity"
        ], 
        "name": "Kinetics of thermoinitiated oligomerization of 3,3\u2032-(2,4,6-triethyl-1,3-phenylene)bis(5-methyl-1,2,4-oxadiazole)", 
        "pagination": "1434-1441", 
        "productId": [
          {
            "name": "dimensions_id", 
            "type": "PropertyValue", 
            "value": [
              "pub.1053574763"
            ]
          }, 
          {
            "name": "doi", 
            "type": "PropertyValue", 
            "value": [
              "10.1007/s11172-013-0206-y"
            ]
          }
        ], 
        "sameAs": [
          "https://doi.org/10.1007/s11172-013-0206-y", 
          "https://app.dimensions.ai/details/publication/pub.1053574763"
        ], 
        "sdDataset": "articles", 
        "sdDatePublished": "2022-05-20T07:28", 
        "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
        "sdPublisher": {
          "name": "Springer Nature - SN SciGraph project", 
          "type": "Organization"
        }, 
        "sdSource": "s3://com-springernature-scigraph/baseset/20220519/entities/gbq_results/article/article_590.jsonl", 
        "type": "ScholarlyArticle", 
        "url": "https://doi.org/10.1007/s11172-013-0206-y"
      }
    ]
     

    Download the RDF metadata as:  json-ld nt turtle xml License info

    HOW TO GET THIS DATA PROGRAMMATICALLY:

    JSON-LD is a popular format for linked data which is fully compatible with JSON.

    curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/s11172-013-0206-y'

    N-Triples is a line-based linked data format ideal for batch operations.

    curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/s11172-013-0206-y'

    Turtle is a human-readable linked data format.

    curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/s11172-013-0206-y'

    RDF/XML is a standard XML format for linked data.

    curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/s11172-013-0206-y'


     

    This table displays all metadata directly associated to this object as RDF triples.

    121 TRIPLES      22 PREDICATES      54 URIs      46 LITERALS      6 BLANK NODES

    Subject Predicate Object
    1 sg:pub.10.1007/s11172-013-0206-y schema:about anzsrc-for:03
    2 schema:author N6d2c377a6cbb4730a5ed4eb4f48499cb
    3 schema:citation sg:pub.10.1007/bf00961246
    4 schema:datePublished 2013-06
    5 schema:datePublishedReg 2013-06-01
    6 schema:description The crystal structure of 3,3′-(2,4,6-triethyl-1,3-phenylene)bis(5-methyl-1,2,4-oxadiazole), which models the cross-linking fragment of polynitriles by benzodinitrile oxides, was determined by X-ray diffraction analysis. The kinetic regularities of its thermoinitiated oligomerization were studied by isothermal calorimetry and spectrophotometry. The process proceeds with self-acceleration, and the Arrhenius dependences of the initial and maximum reaction rates were determined. The reaction accelaration is determined by an increase in the viscosity of the reaction medium. Possible mechanisms were proposed for oligomerization.
    7 schema:genre article
    8 schema:inLanguage en
    9 schema:isAccessibleForFree false
    10 schema:isPartOf N3f4df8898d8c4811a355d8c6b0c12b1e
    11 N4df1b7e996304f4a8d7ca8a44a06904c
    12 sg:journal.1022309
    13 schema:keywords Arrhenius dependence
    14 X-ray diffraction analysis
    15 accelaration
    16 analysis
    17 calorimetry
    18 crystal structure
    19 dependence
    20 diffraction analysis
    21 fragments
    22 increase
    23 isothermal calorimetry
    24 kinetic regularities
    25 kinetics
    26 maximum reaction rate
    27 mechanism
    28 medium
    29 oligomerization
    30 oxide
    31 polynitriles
    32 possible mechanism
    33 process
    34 rate
    35 reaction medium
    36 reaction rate
    37 regularity
    38 spectrophotometry
    39 structure
    40 viscosity
    41 schema:name Kinetics of thermoinitiated oligomerization of 3,3′-(2,4,6-triethyl-1,3-phenylene)bis(5-methyl-1,2,4-oxadiazole)
    42 schema:pagination 1434-1441
    43 schema:productId N0f1738d9e5ea4b23a41222ad5ea381f5
    44 N231b1f71c46f4d1baba399ff76fed9dc
    45 schema:sameAs https://app.dimensions.ai/details/publication/pub.1053574763
    46 https://doi.org/10.1007/s11172-013-0206-y
    47 schema:sdDatePublished 2022-05-20T07:28
    48 schema:sdLicense https://scigraph.springernature.com/explorer/license/
    49 schema:sdPublisher N7c59493b270145d19b1a09e233acb518
    50 schema:url https://doi.org/10.1007/s11172-013-0206-y
    51 sgo:license sg:explorer/license/
    52 sgo:sdDataset articles
    53 rdf:type schema:ScholarlyArticle
    54 N0f1738d9e5ea4b23a41222ad5ea381f5 schema:name doi
    55 schema:value 10.1007/s11172-013-0206-y
    56 rdf:type schema:PropertyValue
    57 N19ef6f8b8ee54b4982ed7d095d9037d2 rdf:first sg:person.015472062537.13
    58 rdf:rest rdf:nil
    59 N231b1f71c46f4d1baba399ff76fed9dc schema:name dimensions_id
    60 schema:value pub.1053574763
    61 rdf:type schema:PropertyValue
    62 N2b9827d16f0e4c989a1063679c7c3f46 rdf:first sg:person.014715402315.55
    63 rdf:rest N19ef6f8b8ee54b4982ed7d095d9037d2
    64 N3f4df8898d8c4811a355d8c6b0c12b1e schema:issueNumber 6
    65 rdf:type schema:PublicationIssue
    66 N4df1b7e996304f4a8d7ca8a44a06904c schema:volumeNumber 62
    67 rdf:type schema:PublicationVolume
    68 N6d2c377a6cbb4730a5ed4eb4f48499cb rdf:first sg:person.016446307341.00
    69 rdf:rest Nc1c377319b7e465b90d1907dfb65d66e
    70 N7c59493b270145d19b1a09e233acb518 schema:name Springer Nature - SN SciGraph project
    71 rdf:type schema:Organization
    72 Nb62aa781844841558e67cf70fafd8de5 rdf:first sg:person.010574144735.96
    73 rdf:rest Ncc0afac83f6b430eaa5781264d38b28d
    74 Nc1c377319b7e465b90d1907dfb65d66e rdf:first sg:person.07506317211.96
    75 rdf:rest Nb62aa781844841558e67cf70fafd8de5
    76 Ncc0afac83f6b430eaa5781264d38b28d rdf:first sg:person.01076212217.01
    77 rdf:rest N2b9827d16f0e4c989a1063679c7c3f46
    78 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
    79 schema:name Chemical Sciences
    80 rdf:type schema:DefinedTerm
    81 sg:journal.1022309 schema:issn 1026-3500
    82 1063-5211
    83 schema:name Russian Chemical Bulletin
    84 schema:publisher Springer Nature
    85 rdf:type schema:Periodical
    86 sg:person.010574144735.96 schema:affiliation grid-institutes:grid.418949.9
    87 schema:familyName Aliev
    88 schema:givenName Z. G.
    89 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010574144735.96
    90 rdf:type schema:Person
    91 sg:person.01076212217.01 schema:affiliation grid-institutes:grid.418949.9
    92 schema:familyName Lagodzinskaya
    93 schema:givenName G. V.
    94 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01076212217.01
    95 rdf:type schema:Person
    96 sg:person.014715402315.55 schema:affiliation grid-institutes:grid.418949.9
    97 schema:familyName Ignat’eva
    98 schema:givenName E. L.
    99 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014715402315.55
    100 rdf:type schema:Person
    101 sg:person.015472062537.13 schema:affiliation grid-institutes:grid.418949.9
    102 schema:familyName Kurochkina
    103 schema:givenName L. S.
    104 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015472062537.13
    105 rdf:type schema:Person
    106 sg:person.016446307341.00 schema:affiliation grid-institutes:grid.418949.9
    107 schema:familyName Goncharov
    108 schema:givenName T. K.
    109 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016446307341.00
    110 rdf:type schema:Person
    111 sg:person.07506317211.96 schema:affiliation grid-institutes:grid.418949.9
    112 schema:familyName Kazakov
    113 schema:givenName A. I.
    114 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.07506317211.96
    115 rdf:type schema:Person
    116 sg:pub.10.1007/bf00961246 schema:sameAs https://app.dimensions.ai/details/publication/pub.1031171188
    117 https://doi.org/10.1007/bf00961246
    118 rdf:type schema:CreativeWork
    119 grid-institutes:grid.418949.9 schema:alternateName Institute of Problems of Chemical Physics, Russian Academy of Sciences, 1 prosp. Akad. Semenova, 142432, Chernogolovka, Moscow Region, Russian Federation
    120 schema:name Institute of Problems of Chemical Physics, Russian Academy of Sciences, 1 prosp. Akad. Semenova, 142432, Chernogolovka, Moscow Region, Russian Federation
    121 rdf:type schema:Organization
     




    Preview window. Press ESC to close (or click here)


    ...