Kinetics of thermoinitiated oligomerization of 3,3′-(2,4,6-triethyl-1,3-phenylene)bis(5-methyl-1,2,4-oxadiazole) View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2013-06

AUTHORS

T. K. Goncharov, A. I. Kazakov, Z. G. Aliev, G. V. Lagodzinskaya, E. L. Ignat’eva, L. S. Kurochkina

ABSTRACT

The crystal structure of 3,3′-(2,4,6-triethyl-1,3-phenylene)bis(5-methyl-1,2,4-oxadiazole), which models the cross-linking fragment of polynitriles by benzodinitrile oxides, was determined by X-ray diffraction analysis. The kinetic regularities of its thermoinitiated oligomerization were studied by isothermal calorimetry and spectrophotometry. The process proceeds with self-acceleration, and the Arrhenius dependences of the initial and maximum reaction rates were determined. The reaction accelaration is determined by an increase in the viscosity of the reaction medium. Possible mechanisms were proposed for oligomerization. More... »

PAGES

1434-1441

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s11172-013-0206-y

DOI

http://dx.doi.org/10.1007/s11172-013-0206-y

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1053574763


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "Institute of Problems of Chemical Physics, Russian Academy of Sciences, 1 prosp. Akad. Semenova, 142432, Chernogolovka, Moscow Region, Russian Federation", 
          "id": "http://www.grid.ac/institutes/grid.418949.9", 
          "name": [
            "Institute of Problems of Chemical Physics, Russian Academy of Sciences, 1 prosp. Akad. Semenova, 142432, Chernogolovka, Moscow Region, Russian Federation"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Goncharov", 
        "givenName": "T. K.", 
        "id": "sg:person.016446307341.00", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016446307341.00"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Institute of Problems of Chemical Physics, Russian Academy of Sciences, 1 prosp. Akad. Semenova, 142432, Chernogolovka, Moscow Region, Russian Federation", 
          "id": "http://www.grid.ac/institutes/grid.418949.9", 
          "name": [
            "Institute of Problems of Chemical Physics, Russian Academy of Sciences, 1 prosp. Akad. Semenova, 142432, Chernogolovka, Moscow Region, Russian Federation"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Kazakov", 
        "givenName": "A. I.", 
        "id": "sg:person.07506317211.96", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.07506317211.96"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Institute of Problems of Chemical Physics, Russian Academy of Sciences, 1 prosp. Akad. Semenova, 142432, Chernogolovka, Moscow Region, Russian Federation", 
          "id": "http://www.grid.ac/institutes/grid.418949.9", 
          "name": [
            "Institute of Problems of Chemical Physics, Russian Academy of Sciences, 1 prosp. Akad. Semenova, 142432, Chernogolovka, Moscow Region, Russian Federation"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Aliev", 
        "givenName": "Z. G.", 
        "id": "sg:person.010574144735.96", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010574144735.96"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Institute of Problems of Chemical Physics, Russian Academy of Sciences, 1 prosp. Akad. Semenova, 142432, Chernogolovka, Moscow Region, Russian Federation", 
          "id": "http://www.grid.ac/institutes/grid.418949.9", 
          "name": [
            "Institute of Problems of Chemical Physics, Russian Academy of Sciences, 1 prosp. Akad. Semenova, 142432, Chernogolovka, Moscow Region, Russian Federation"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Lagodzinskaya", 
        "givenName": "G. V.", 
        "id": "sg:person.01076212217.01", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01076212217.01"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Institute of Problems of Chemical Physics, Russian Academy of Sciences, 1 prosp. Akad. Semenova, 142432, Chernogolovka, Moscow Region, Russian Federation", 
          "id": "http://www.grid.ac/institutes/grid.418949.9", 
          "name": [
            "Institute of Problems of Chemical Physics, Russian Academy of Sciences, 1 prosp. Akad. Semenova, 142432, Chernogolovka, Moscow Region, Russian Federation"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Ignat\u2019eva", 
        "givenName": "E. L.", 
        "id": "sg:person.014715402315.55", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014715402315.55"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Institute of Problems of Chemical Physics, Russian Academy of Sciences, 1 prosp. Akad. Semenova, 142432, Chernogolovka, Moscow Region, Russian Federation", 
          "id": "http://www.grid.ac/institutes/grid.418949.9", 
          "name": [
            "Institute of Problems of Chemical Physics, Russian Academy of Sciences, 1 prosp. Akad. Semenova, 142432, Chernogolovka, Moscow Region, Russian Federation"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Kurochkina", 
        "givenName": "L. S.", 
        "id": "sg:person.015472062537.13", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015472062537.13"
        ], 
        "type": "Person"
      }
    ], 
    "datePublished": "2013-06", 
    "datePublishedReg": "2013-06-01", 
    "description": "The crystal structure of 3,3\u2032-(2,4,6-triethyl-1,3-phenylene)bis(5-methyl-1,2,4-oxadiazole), which models the cross-linking fragment of polynitriles by benzodinitrile oxides, was determined by X-ray diffraction analysis. The kinetic regularities of its thermoinitiated oligomerization were studied by isothermal calorimetry and spectrophotometry. The process proceeds with self-acceleration, and the Arrhenius dependences of the initial and maximum reaction rates were determined. The reaction accelaration is determined by an increase in the viscosity of the reaction medium. Possible mechanisms were proposed for oligomerization.", 
    "genre": "article", 
    "id": "sg:pub.10.1007/s11172-013-0206-y", 
    "inLanguage": "en", 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1022309", 
        "issn": [
          "1063-5211", 
          "1026-3500"
        ], 
        "name": "Russian Chemical Bulletin", 
        "publisher": "Springer Nature", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "6", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "62"
      }
    ], 
    "keywords": [
      "ray diffraction analysis", 
      "reaction medium", 
      "kinetic regularities", 
      "maximum reaction rate", 
      "diffraction analysis", 
      "crystal structure", 
      "reaction rate", 
      "Arrhenius dependence", 
      "isothermal calorimetry", 
      "oligomerization", 
      "polynitriles", 
      "calorimetry", 
      "oxide", 
      "spectrophotometry", 
      "kinetics", 
      "viscosity", 
      "possible mechanism", 
      "structure", 
      "dependence", 
      "medium", 
      "fragments", 
      "process", 
      "accelaration", 
      "mechanism", 
      "analysis", 
      "increase", 
      "regularity", 
      "rate", 
      "cross-linking fragment", 
      "benzodinitrile oxides", 
      "reaction accelaration"
    ], 
    "name": "Kinetics of thermoinitiated oligomerization of 3,3\u2032-(2,4,6-triethyl-1,3-phenylene)bis(5-methyl-1,2,4-oxadiazole)", 
    "pagination": "1434-1441", 
    "productId": [
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1053574763"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1007/s11172-013-0206-y"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1007/s11172-013-0206-y", 
      "https://app.dimensions.ai/details/publication/pub.1053574763"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2022-01-01T18:30", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-springernature-scigraph/baseset/20220101/entities/gbq_results/article/article_605.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "https://doi.org/10.1007/s11172-013-0206-y"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/s11172-013-0206-y'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/s11172-013-0206-y'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/s11172-013-0206-y'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/s11172-013-0206-y'


 

This table displays all metadata directly associated to this object as RDF triples.

120 TRIPLES      21 PREDICATES      56 URIs      49 LITERALS      6 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1007/s11172-013-0206-y schema:about anzsrc-for:03
2 schema:author Nd3ece121dede4591850facae2e34b518
3 schema:datePublished 2013-06
4 schema:datePublishedReg 2013-06-01
5 schema:description The crystal structure of 3,3′-(2,4,6-triethyl-1,3-phenylene)bis(5-methyl-1,2,4-oxadiazole), which models the cross-linking fragment of polynitriles by benzodinitrile oxides, was determined by X-ray diffraction analysis. The kinetic regularities of its thermoinitiated oligomerization were studied by isothermal calorimetry and spectrophotometry. The process proceeds with self-acceleration, and the Arrhenius dependences of the initial and maximum reaction rates were determined. The reaction accelaration is determined by an increase in the viscosity of the reaction medium. Possible mechanisms were proposed for oligomerization.
6 schema:genre article
7 schema:inLanguage en
8 schema:isAccessibleForFree false
9 schema:isPartOf N1d357898111643e496c3bc66bcf5f94c
10 N6d9bafd084d24f9b9b344f43a89f3cc9
11 sg:journal.1022309
12 schema:keywords Arrhenius dependence
13 accelaration
14 analysis
15 benzodinitrile oxides
16 calorimetry
17 cross-linking fragment
18 crystal structure
19 dependence
20 diffraction analysis
21 fragments
22 increase
23 isothermal calorimetry
24 kinetic regularities
25 kinetics
26 maximum reaction rate
27 mechanism
28 medium
29 oligomerization
30 oxide
31 polynitriles
32 possible mechanism
33 process
34 rate
35 ray diffraction analysis
36 reaction accelaration
37 reaction medium
38 reaction rate
39 regularity
40 spectrophotometry
41 structure
42 viscosity
43 schema:name Kinetics of thermoinitiated oligomerization of 3,3′-(2,4,6-triethyl-1,3-phenylene)bis(5-methyl-1,2,4-oxadiazole)
44 schema:pagination 1434-1441
45 schema:productId Ncf453334b9674a67b9323c4aa6359a2f
46 Nd409ad65ee4b476da4c134f968ada891
47 schema:sameAs https://app.dimensions.ai/details/publication/pub.1053574763
48 https://doi.org/10.1007/s11172-013-0206-y
49 schema:sdDatePublished 2022-01-01T18:30
50 schema:sdLicense https://scigraph.springernature.com/explorer/license/
51 schema:sdPublisher N20200a579d6c42d69192a1abe2a628c0
52 schema:url https://doi.org/10.1007/s11172-013-0206-y
53 sgo:license sg:explorer/license/
54 sgo:sdDataset articles
55 rdf:type schema:ScholarlyArticle
56 N16ee2504a142415ea0f446e31ad75e41 rdf:first sg:person.01076212217.01
57 rdf:rest N4a754192fb0a45f2a764e4f74424fbf8
58 N1d357898111643e496c3bc66bcf5f94c schema:issueNumber 6
59 rdf:type schema:PublicationIssue
60 N20200a579d6c42d69192a1abe2a628c0 schema:name Springer Nature - SN SciGraph project
61 rdf:type schema:Organization
62 N4a754192fb0a45f2a764e4f74424fbf8 rdf:first sg:person.014715402315.55
63 rdf:rest Nc68dd6c57192494a9fc4ef0cebdaaa43
64 N511e951cfc5947ff8b42ba15db659428 rdf:first sg:person.010574144735.96
65 rdf:rest N16ee2504a142415ea0f446e31ad75e41
66 N6d9bafd084d24f9b9b344f43a89f3cc9 schema:volumeNumber 62
67 rdf:type schema:PublicationVolume
68 Nc68dd6c57192494a9fc4ef0cebdaaa43 rdf:first sg:person.015472062537.13
69 rdf:rest rdf:nil
70 Ncf453334b9674a67b9323c4aa6359a2f schema:name dimensions_id
71 schema:value pub.1053574763
72 rdf:type schema:PropertyValue
73 Nd3ece121dede4591850facae2e34b518 rdf:first sg:person.016446307341.00
74 rdf:rest Nec6417845c9d41c690b4e3c5ebfbe265
75 Nd409ad65ee4b476da4c134f968ada891 schema:name doi
76 schema:value 10.1007/s11172-013-0206-y
77 rdf:type schema:PropertyValue
78 Nec6417845c9d41c690b4e3c5ebfbe265 rdf:first sg:person.07506317211.96
79 rdf:rest N511e951cfc5947ff8b42ba15db659428
80 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
81 schema:name Chemical Sciences
82 rdf:type schema:DefinedTerm
83 sg:journal.1022309 schema:issn 1026-3500
84 1063-5211
85 schema:name Russian Chemical Bulletin
86 schema:publisher Springer Nature
87 rdf:type schema:Periodical
88 sg:person.010574144735.96 schema:affiliation grid-institutes:grid.418949.9
89 schema:familyName Aliev
90 schema:givenName Z. G.
91 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010574144735.96
92 rdf:type schema:Person
93 sg:person.01076212217.01 schema:affiliation grid-institutes:grid.418949.9
94 schema:familyName Lagodzinskaya
95 schema:givenName G. V.
96 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01076212217.01
97 rdf:type schema:Person
98 sg:person.014715402315.55 schema:affiliation grid-institutes:grid.418949.9
99 schema:familyName Ignat’eva
100 schema:givenName E. L.
101 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014715402315.55
102 rdf:type schema:Person
103 sg:person.015472062537.13 schema:affiliation grid-institutes:grid.418949.9
104 schema:familyName Kurochkina
105 schema:givenName L. S.
106 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015472062537.13
107 rdf:type schema:Person
108 sg:person.016446307341.00 schema:affiliation grid-institutes:grid.418949.9
109 schema:familyName Goncharov
110 schema:givenName T. K.
111 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016446307341.00
112 rdf:type schema:Person
113 sg:person.07506317211.96 schema:affiliation grid-institutes:grid.418949.9
114 schema:familyName Kazakov
115 schema:givenName A. I.
116 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.07506317211.96
117 rdf:type schema:Person
118 grid-institutes:grid.418949.9 schema:alternateName Institute of Problems of Chemical Physics, Russian Academy of Sciences, 1 prosp. Akad. Semenova, 142432, Chernogolovka, Moscow Region, Russian Federation
119 schema:name Institute of Problems of Chemical Physics, Russian Academy of Sciences, 1 prosp. Akad. Semenova, 142432, Chernogolovka, Moscow Region, Russian Federation
120 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...