Synthesis and structure of chiral coordination polymers of CoII, CuII, and MgII saccharates View Full Text


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Article Info

DATE

2013-03

AUTHORS

M. S. Zavakhina, D. G. Samsonenko, D. N. Dybtsev, M. P. Yutkin, A. V. Virovets, V. P. Fedin

ABSTRACT

Chiral metal-organic coordination polymers [Co2(sacch)2]·1/2H2O·CH3OH (1), [Cu(sacch)(H2O)2]·3H2O (2), and [Mg(H2O)3(sacch)] (3) (H2sacch is d-saccharic acid) were synthesized from aqueous or water-methanol solutions of potassium hydrogen saccharate and a salt of the corresponding metal. The compositions and structures of the resulting compounds were determined by single-crystal X-ray diffraction and confirmed by X-ray powder diffraction, IR spectroscopy, thermogravimetry, and elemental analysis. More... »

PAGES

716-721

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s11172-013-0098-x

DOI

http://dx.doi.org/10.1007/s11172-013-0098-x

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1005932664


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