Synthesis and structure of 3-arylamino-2-(quinolin-2-yl)tropones View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2013-02

AUTHORS

Yu. A. Sayapin, E. A. Gusakov, Zyong Ngia Bang, I. O. Tupaeva, V. N. Komissarov, I. V. Dorogan, V. V. Tkachev, S. M. Aldoshin, V. I. Minkin

ABSTRACT

A reaction of substituted 2-(quinolin-2-yl)-1,3-tropolones with POCl3 leads to the new3-chloro-2-(quinolin-2-yl)tropone derivatives. New 2-(4-arylaminoquinolin-2-yl)-3-aryl-aminocyclohepta-2,4,6-trien-1-ones and 2-[4-morpholino(piperidino)quinolin-2-yl]-3-aryl-aminocyclohepta-2,4,6-trien-1-ones were obtained by nucleophilic substitution reaction of the halogen atom in 2-(4-chloroquinolin-2-yl)-3-chlorotropones and 3-chloro-2-[4-morpholino-(piperidino)quinolin-2-yl]tropones. Molecular structures of 3-chloro-2-(quinolin-2-yl)tropone and 3-arylamino-2-(quinolin-2-yl)tropone were established by X-ray diffraction analysis. Energy and structural characteristics of isomers of 3-arylamino-2-(quinolin-2-yl)tropones in the gas phase and in solution were calculated by the density functional theory method (PBE0/6-31G**). More... »

PAGES

480-491

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s11172-013-0067-4

DOI

http://dx.doi.org/10.1007/s11172-013-0067-4

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1048008931


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