Stereoselective addition of aliphatic thiols to internal alkynes in a catalytic system with palladium “nanosalt” as an active site View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2013-01

AUTHORS

N. V. Orlov, I. V. Chistyakov, Z. A. Starikova, V. P. Ananikov, I. P. Beletskaya

ABSTRACT

An efficient catalytic system based on easily available palladium acetate was developed for the selective addition of aliphatic thiols to the triple bond of internal alkynes. Formed in situ [M(SR)2]n nanostructured particles were found to be an active form of the catalyst. It was experimentally confirmed for the first time that the most active form of the catalyst for thiol addition to internal alkynes is formed only in the reaction mixture containing the both reactants, namely, alkyne and thiol. More... »

PAGES

47-54

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s11172-013-0007-3

DOI

http://dx.doi.org/10.1007/s11172-013-0007-3

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1049306843


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