Synthesis of N-glycyl-β-glycopyranosylamines, human milk fucooligosaccharide derivatives View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2012-09

AUTHORS

L. M. Likhosherstov, O. S. Novikova, I. A. Yamskov, V. E. Piskarev

ABSTRACT

The action of ammonium carbamate in aqueous methanol in the presence of NH3 on three-, penta-, hexa-, octa-, and nonasaccharides of human milk and on decasaccharide (N-glycan from human immunoglobulin (IgG)) containing one or two a-l-fucose residues led to the corresponding β-glycopyranosylamines. After their N-acylation upon treatment with N-hydroxysuccinimide ester of N-Boc-glycine or N-Boc-glycine anhydride (Boc is the tert-butyloxycarbonyl) with subsequent removal of the Boc group, N-glycyl-β-glycopyranosylamines were obtained in up to 75% yield. More... »

PAGES

1816-1821

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s11172-012-0250-z

DOI

http://dx.doi.org/10.1007/s11172-012-0250-z

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1039013642


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