Polyphenylcyclopentadienyl complexes of rare earth elements View Full Text


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Article Info

DATE

2012-09

AUTHORS

D. M. Roitershtein, M. E. Minyaev, A. A. Mikhaylyuk, K. A. Lyssenko, I. V. Glukhov, P. A. Belyakov

ABSTRACT

Reaction of LnCl3(thf)x (Ln = Y, La, Yb, Lu) with NaCpPhn (CpPhn = 1,3-Ph2C5H3, 1,2,4-Ph3C5H2, Ph4C5H) leads to formation of monocyclopentadienyl dichloride complexes Yb(Ph2C5H3)Cl2(thf)3 (1), Ln(Ph3C5H2)Cl2(thf)3 (Ln = Y (2), Lu (3)), La(Ph4C5H)Cl2(thf)3 (4). Molecular structures of 1, 2 and the polynuclear complex [(Ph3C5H2)3Lu4(Cl)7(O)(thf)3] (5), which is a partial hydrolysis product of 3, have been established by the X-ray method. More... »

PAGES

1726-1732

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s11172-012-0238-8

DOI

http://dx.doi.org/10.1007/s11172-012-0238-8

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1011360103


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