Unusual structure of new dimethylmalonate coordination polymer with strontium atoms and VO2+ fragments View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2012-07

AUTHORS

E. S. Bazhina, M. E. Nikiforova, G. G. Aleksandrov, N. N. Efimov, M. A. Kiskin, E. A. Ugolkova, V. V. Minin, A. A. Sidorov, V. M. Novotortsev, I. L. Eremenko

ABSTRACT

A reaction of vanadyl sulfate VOSO4·3H2O with dimethylmalonic acid strontium salt led to the coordination polymer {Sr(H2O)8[VO(Me2mal)2]}n (1, Me2mal is the dimethylmalonic acid dianion), in which the carboxylate dianions did not form chelate metallocycles with the vanadyl ions. The complex was studied by ESR spectroscopy. The compound 1 exhibited weak spin-spin exchange interactions of ferromagnetic type between the VIV atoms. More... »

PAGES

1426-1429

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s11172-012-0184-5

DOI

http://dx.doi.org/10.1007/s11172-012-0184-5

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1031940853


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