Polymeric heterometallic CuII dimethylmalonate complexes with potassium and cadmium ions View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2012-07

AUTHORS

N. V. Zauzolkova, E. N. Zorina, A. A. Sidorov, G. G. Aleksandrov, A. S. Lermontov, V. V. Minin, A. V. Rotov, E. A. Ugolkova, N. N. Efimov, M. A. Kiskin, V. M. Novotortsev, I. L. Eremenko

ABSTRACT

A reaction of (HPiv)2Cu2(Piv)4 with dimethylmalonic acid dipotassium salt (K2Me2mal) leads to the formation of a cage coordination polymer {(μ-H2O)6K8[(μ-H2O)Cu-(μ3,κ2-Me2mal)(μ6,κ2-Me2mal)]2[Cu2(μ5,κ2-Me2mal)2(μ5,κ2-Me2mal)2]}n (1). It was found that when 1 reacted with CdSO4·8H2O in a mixture of EtOH-H2O (3: 1), the potassium ions in 1 were displaced with cadmium(ii) ions with the formation of a heterometallic 1D-polymer [(κ1-H2O)4CdCu(μ,κ2-Me2mal)2]n (2). Compounds 1 and 2 were characterized by X-ray crystallography and ESR spectroscopy. More... »

PAGES

1419-1425

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s11172-012-0183-6

DOI

http://dx.doi.org/10.1007/s11172-012-0183-6

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1045437492


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