Ontology type: schema:ScholarlyArticle
2012-07
AUTHORSN. V. Zauzolkova, E. N. Zorina, A. A. Sidorov, G. G. Aleksandrov, A. S. Lermontov, V. V. Minin, A. V. Rotov, E. A. Ugolkova, N. N. Efimov, M. A. Kiskin, V. M. Novotortsev, I. L. Eremenko
ABSTRACTA reaction of (HPiv)2Cu2(Piv)4 with dimethylmalonic acid dipotassium salt (K2Me2mal) leads to the formation of a cage coordination polymer {(μ-H2O)6K8[(μ-H2O)Cu-(μ3,κ2-Me2mal)(μ6,κ2-Me2mal)]2[Cu2(μ5,κ2-Me2mal)2(μ5,κ2-Me2mal)2]}n (1). It was found that when 1 reacted with CdSO4·8H2O in a mixture of EtOH-H2O (3: 1), the potassium ions in 1 were displaced with cadmium(ii) ions with the formation of a heterometallic 1D-polymer [(κ1-H2O)4CdCu(μ,κ2-Me2mal)2]n (2). Compounds 1 and 2 were characterized by X-ray crystallography and ESR spectroscopy. More... »
PAGES1419-1425
http://scigraph.springernature.com/pub.10.1007/s11172-012-0183-6
DOIhttp://dx.doi.org/10.1007/s11172-012-0183-6
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