Synthesis and separation of stereoisomeric 2,4,6,8-tetrasubstituted 3,7-dithia-1,5-diazabicyclo[3.3.0]octanes View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2012-01

AUTHORS

V. R. Akhmetova, N. N. Murzakova, G. R. Khabibullina, T. V. Tyumkina, Z. A. Starikova, I. S. Bushmarinov, L. F. Korzhova

ABSTRACT

Heterocyclization of hydrazine with aldehydes R-CHO (R = Me, Et, Prn, Bun, n-C5H11, Ph, 4-MeOC6H4, 3-Py) and H2S leads to stereoisomeric 2,4,6,8-tetrasubstituted 3,7-dithia-1,5-diazabicyclo[3.3.0]octanes, which were separated by column chromatography. The trans-transoid-trans-configuration of tetramethyl(-ethyl,-propyl)-3,7-dithia-1,5-diazabicyclo-[3.3.0]octanes was inferred from the X-ray diffraction and 1H and 13C NMR spectroscopic data.

PAGES

141-147

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s11172-012-0020-y

DOI

http://dx.doi.org/10.1007/s11172-012-0020-y

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1020119632


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