Synthesis of [1,2,4]triazolo[4,3-b]-s-tetrazines with incorporated furazan ring View Full Text


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Article Info

DATE

2012-01

AUTHORS

A. B. Sheremetev, N. V. Palysaeva, K. Yu. Suponitskii, M. I. Struchkova

ABSTRACT

Furazancarboxylic hydrazides can serve as nucleophiles to substitute for one dimethylpyrazole fragment in bis(3,5-dimethylpyrazol-1-yl)-s-tetrazine, giving the corresponding N′-[6-(3,5-dimethylpyrazol-1-yl)-s-tetrazin-3-yl]-4-R-furazan-3-carbohydrazides in good yields. Dehydration of the indicated carbohydrazides in polyphosphoric acid for the first time gave rise to [1,2,4]triazolo[4,3-b]-s-tetrazines containing the furazan ring as a substituent at the triazole ring.

PAGES

121-130

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s11172-012-0017-6

DOI

http://dx.doi.org/10.1007/s11172-012-0017-6

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1036177110


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