Hydrates and ammonium salts of 4-nitrobenzenesulfonic acid: supramolecular organization and its relation to proton conductivity View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2011-06

AUTHORS

P. Yu. Barzilovich, K. A. Lyssenko, M. Yu. Antipin, S. M. Aldoshin

ABSTRACT

Structural features, the crystal packing, and the proton conductivity of a series of hydrates and ammonium salts of 4-nitrobenzenesulfonic acid were studied. It was shown that infinite cation associates containing the onium moiety are responsible for a substantial increase in the proton conductivity. The nature of the disorder in a series of crystals was investigated by performing X-ray diffraction studies at different temperatures. A new type of structural synthons, viz., anion-anion dimers stabilized by the SO3−…NO2 interaction, was found and characterized and the role of solvent water molecules was elucidated based on high-resolution X-ray diffraction data. The water molecules serve mainly as channels for charge transfer from the cation to the anion with retention of the electroneutrality. More... »

PAGES

1185-1195

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s11172-011-0187-7

DOI

http://dx.doi.org/10.1007/s11172-011-0187-7

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1032331649


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