Thermal decomposition of cis-2, 4, 6, 8-tetranitro-1H, 5H-2, 4, 6, 8-tetraazabicyclo[3.3.0]octane View Full Text


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Article Info

DATE

2011-06

AUTHORS

T. K. Goncharov, V. V. Dubikhin, G. M. Nazin, V. G. Prokudin, Z. G. Aliev

ABSTRACT

The thermal decomposition kinetics of cis-2, 4, 6, 8-tetranitro-1H, 5H-2, 4, 6, 8-tetraazabicyclo[3.3.0]octane was measured in various solvents and in the solid phase by the manometric method. The general regularities for cyclic nitramines concerning the possibility of chain decomposition in hydrocarbon solvents, the kinetic display of cell effect in viscous media, a decrease in the decomposition rate in the solid state, and the quantitative description of this effect in terms of the model of monomolecular reactions in molecular crystals are supplemented and discussed. The dependence of the decomposition rate constants in solutions on the N-N bond lengths in a series of secondary nitramines was shown using the correct values of decomposition rate constants. More... »

PAGES

1138-1143

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s11172-011-0178-8

DOI

http://dx.doi.org/10.1007/s11172-011-0178-8

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1030548204


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