Synthesis, structures, and photochromic properties of 3-[(E)-alk-1-enyl]-4-(1-alkyl-5-methoxy-2-methyl-1H-indol-3-yl)furan-2,5-diones View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2011-06

AUTHORS

N. I. Makarova, P. V. Levchenko, V. V. Tkachev, E. N. Shepelenko, A. V. Metelitsa, V. P. Rybalkin, L. L. Popova, V. A. Bren’, S. M. Aldoshin, V. I. Minkin

ABSTRACT

New hetarylethenes, viz., 3-[(E)-alk-1-enyl]-4-(1-alkyl-5-methoxy-2-methyl-1H-indol-3-yl)furan-2,5-diones, exhibiting photochromic properties in solution were synthesized. The molecular and crystal structure of 3-(5-methoxy-1,2-dimethyl-1H-indol-3-yl)-4-[(E)-prop-1-enyl]furan-2,5-dione was determined by X-ray diffraction. The initial and photoinduced forms of hetarylethenes are characterized by thermal stability. The open-ring isomers of furandiones exhibit fluorescence with quantum yields of up to 0.1.

PAGES

1090-1095

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s11172-011-0172-1

DOI

http://dx.doi.org/10.1007/s11172-011-0172-1

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1048971087


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