Heterospin complexes based on cobalt semiquinolate with nitroxides View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2011-05

AUTHORS

E. Yu. Fursova, O. V. Kuznetsova, E. V. Tretyakov, G. V. Romanenko, A. S. Bogomyakov, V. I. Ovcharenko, R. Z. Sagdeev, V. K. Cherkasov, M. P. Bubnov, G. A. Abakumov

ABSTRACT

Heterospin complexes based on cobalt semiquinolate with stable nitroxides of composition [Co(SQ)2(NIT)2]·8CH2Cl2, [Co(SQ)2(NIT)2]·4MeCN, [Co(SQ)2(IN)2]·5Me2CO, [Co(SQ)2(IN)2]·4MeCN, and [Co(SQ)2(IN)2]·2CH2Cl2·C6H14, where SQ is 3,6-di-tert-butyl-o-benzosemiquinolate, NIT is 4,4,5,5-tetramethyl-2-(1-methyl-1H-imidazol-5-yl)-4,5-dihydro-1H-imidazole-3-oxide-1-oxyl, and IN is the imine analog of NIT, viz., 4,4,5,5-tetramethyl-2-(1-methyl-1H-imidazol-5-yl)-4,5-dihydro-1H-imidazole-1-oxyl, were synthesized. The characteristic feature of these compounds is that they contain two different types of paramagnetic organic ligands. The X-ray diffraction study showed that the solid phases of the complexes have a molecular structure. According to the data from thermomagnetic analysis (2–350 K), all complexes exhibit effects of valence tautomerism at ∼20 °C. It was found that incorporated solvent molecules have an effect on the magnetic anomaly temperature. More... »

PAGES

809-815

References to SciGraph publications

  • 2005-10. Solar cells: Later rather than sooner in NATURE MATERIALS
  • Identifiers

    URI

    http://scigraph.springernature.com/pub.10.1007/s11172-011-0129-4

    DOI

    http://dx.doi.org/10.1007/s11172-011-0129-4

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    https://app.dimensions.ai/details/publication/pub.1015024548


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