3D coordination polymers with vanadyl fragments and alkaline earth metal ions View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2011-05

AUTHORS

E. S. Bazhina, M. E. Nikiforova, G. G. Aleksandrov, V. V. Minin, N. N. Efimov, A. A. Sidorov, V. M. Novotortsev, I. L. Eremenko

ABSTRACT

The reactions of vanadyl sulfate VOSO4·3H2O with barium or strontium cyclopropane-1,1-dicarboxylate (MCpdc, M = Ba, Sr, H2Cpdc = C3H4(COOH)2) afforded the polymeric heterometallic complexes {[(H2O)8Ba2(VO)2(Cpdc)4]·2H2O}n (1) and {[(H2O)6Sr(VO)(Cpdc)2]}n (2), respectively. These complexes differ in the binding mode of mononuclear vanadyl fragments with alkaline earth metal ions. Coordination polymers 1 and 2 were characterized by ESR spectroscopy. More... »

PAGES

797-802

Journal

TITLE

Russian Chemical Bulletin

ISSUE

5

VOLUME

60

Author Affiliations

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s11172-011-0127-6

DOI

http://dx.doi.org/10.1007/s11172-011-0127-6

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1052050111


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