A specific intramolecular interaction in a bis(2-thienyl)maleimide derivative View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2011-03

AUTHORS

M. M. Krayushkin, L. G. Vorontsova, A. A. Shimkin, Z. A. Starikova

ABSTRACT

3,4-Bis(4-ethoxycarbonyl-3-hydroxy-5-methyl-2-thienyl)-1-phenyl-1H-pyrrole-2,5-dione shows no photochromism in the crystalline state, despite its typical “photochromic” structure (X-ray diffraction data): the anti-parallel orientation of the thienyl fragments relative to the plane of pyrrole-2,5-dione and a short distance between potential reactive sites (C(3′)...C(3′A), 3.27 Å). The absence of photochromism was explained by a specific attractive interaction between the O atoms of the maleimide ring and the thiophene S atoms, which can preclude UV-induced photocyclization. More... »

PAGES

595

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s11172-011-0094-y

DOI

http://dx.doi.org/10.1007/s11172-011-0094-y

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1006216972


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