Formation of cobalt- and lithium-containing heterometallic pyridonate carboxylate coordination polymers View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2011-02

AUTHORS

N. V. Zauzolkova, M. E. Nikiforova, M. A. Kiskin, A. S. Bogomyakov, A. A. Sidorov, I. L. Eremenko

ABSTRACT

The reaction of cobalt(II) chloride with 2-hydroxypyridine (Hhp) and lithium pivalate in acetonitrile affords the 1D polymer [Li3CoCl(μ-Piv)(μ3-Piv)2(μ3,η2-Piv)(μ-Hhp)2(η1-HPiv)]n, in which the repeating units are linked by bridging pyridone molecules. The reaction of cobalt nitrate hexahydrate with 2-hydroxy-6-methylpyridine (Hmhp) in the presence of the deprotonating agent (Et3N) resulted in the crystallization of the 1D polymer of the composition [Li2Co7(μ3-OH)2(μ3-Piv)3(μ-Piv)2(μ3,η2-mhp)5(μ,η2-mhp)2(μ3-mhp)(μ,η2-NO3)·2MeCN]n, in which the bulky metal fragments {Li2Co7(OH)2(Piv)5)(mhp)8} are linked together through the lithium atoms by chelate bridging nitrate anions. The resulting 1D polymers were characterized by X-ray diffraction, and their magnetic properties were investigated. More... »

PAGES

273

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s11172-011-0046-6

DOI

http://dx.doi.org/10.1007/s11172-011-0046-6

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1035964239


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0303", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Macromolecular and Materials Chemistry", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "Russian Academy of Sciences", 
          "id": "https://www.grid.ac/institutes/grid.4886.2", 
          "name": [
            "N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 31 Leninsky prosp., 119991, Moscow, Russian Federation"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Zauzolkova", 
        "givenName": "N. V.", 
        "id": "sg:person.013111041721.71", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013111041721.71"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Russian Academy of Sciences", 
          "id": "https://www.grid.ac/institutes/grid.4886.2", 
          "name": [
            "N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 31 Leninsky prosp., 119991, Moscow, Russian Federation"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Nikiforova", 
        "givenName": "M. E.", 
        "id": "sg:person.010710432427.45", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010710432427.45"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Russian Academy of Sciences", 
          "id": "https://www.grid.ac/institutes/grid.4886.2", 
          "name": [
            "N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 31 Leninsky prosp., 119991, Moscow, Russian Federation"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Kiskin", 
        "givenName": "M. A.", 
        "id": "sg:person.01172445335.81", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01172445335.81"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Siberian Branch of the Russian Academy of Sciences", 
          "id": "https://www.grid.ac/institutes/grid.415877.8", 
          "name": [
            "International Tomography Center, Siberian Branch of the Russian Academy of Sciences, 3a ul. Institutskaya, 630090, Novosibirsk, Russian Federation"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Bogomyakov", 
        "givenName": "A. S.", 
        "id": "sg:person.011677017467.94", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011677017467.94"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Russian Academy of Sciences", 
          "id": "https://www.grid.ac/institutes/grid.4886.2", 
          "name": [
            "N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 31 Leninsky prosp., 119991, Moscow, Russian Federation"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Sidorov", 
        "givenName": "A. A.", 
        "id": "sg:person.014044746763.06", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014044746763.06"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Russian Academy of Sciences", 
          "id": "https://www.grid.ac/institutes/grid.4886.2", 
          "name": [
            "N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 31 Leninsky prosp., 119991, Moscow, Russian Federation"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Eremenko", 
        "givenName": "I. L.", 
        "id": "sg:person.0745631435.08", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0745631435.08"
        ], 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "https://doi.org/10.1016/0277-5387(94)00431-d", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1004401217"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/chem.200304939", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1012921690"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/s10876-005-0002-4", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1017560423", 
          "https://doi.org/10.1007/s10876-005-0002-4"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/s10876-005-0002-4", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1017560423", 
          "https://doi.org/10.1007/s10876-005-0002-4"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/s10876-005-0002-4", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1017560423", 
          "https://doi.org/10.1007/s10876-005-0002-4"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ic034517y", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055555827"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ic034517y", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055555827"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ja962356+", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055865645"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/ja962356+", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055865645"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "2011-02", 
    "datePublishedReg": "2011-02-01", 
    "description": "The reaction of cobalt(II) chloride with 2-hydroxypyridine (Hhp) and lithium pivalate in acetonitrile affords the 1D polymer [Li3CoCl(\u03bc-Piv)(\u03bc3-Piv)2(\u03bc3,\u03b72-Piv)(\u03bc-Hhp)2(\u03b71-HPiv)]n, in which the repeating units are linked by bridging pyridone molecules. The reaction of cobalt nitrate hexahydrate with 2-hydroxy-6-methylpyridine (Hmhp) in the presence of the deprotonating agent (Et3N) resulted in the crystallization of the 1D polymer of the composition [Li2Co7(\u03bc3-OH)2(\u03bc3-Piv)3(\u03bc-Piv)2(\u03bc3,\u03b72-mhp)5(\u03bc,\u03b72-mhp)2(\u03bc3-mhp)(\u03bc,\u03b72-NO3)\u00b72MeCN]n, in which the bulky metal fragments {Li2Co7(OH)2(Piv)5)(mhp)8} are linked together through the lithium atoms by chelate bridging nitrate anions. The resulting 1D polymers were characterized by X-ray diffraction, and their magnetic properties were investigated.", 
    "genre": "non_research_article", 
    "id": "sg:pub.10.1007/s11172-011-0046-6", 
    "inLanguage": [
      "en"
    ], 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1022309", 
        "issn": [
          "1066-5285", 
          "1573-9171"
        ], 
        "name": "Russian Chemical Bulletin", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "2", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "60"
      }
    ], 
    "name": "Formation of cobalt- and lithium-containing heterometallic pyridonate carboxylate coordination polymers", 
    "pagination": "273", 
    "productId": [
      {
        "name": "readcube_id", 
        "type": "PropertyValue", 
        "value": [
          "ab5219637b85a920d5333e2596af39581eee56618fd652a6642fdd971b095766"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1007/s11172-011-0046-6"
        ]
      }, 
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1035964239"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1007/s11172-011-0046-6", 
      "https://app.dimensions.ai/details/publication/pub.1035964239"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2019-04-11T01:11", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000001_0000000264/records_8697_00000533.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "http://link.springer.com/10.1007%2Fs11172-011-0046-6"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/s11172-011-0046-6'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/s11172-011-0046-6'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/s11172-011-0046-6'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/s11172-011-0046-6'


 

This table displays all metadata directly associated to this object as RDF triples.

115 TRIPLES      21 PREDICATES      32 URIs      19 LITERALS      7 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1007/s11172-011-0046-6 schema:about anzsrc-for:03
2 anzsrc-for:0303
3 schema:author N134d9ff0d4ae4490a2dabfc171c8cf45
4 schema:citation sg:pub.10.1007/s10876-005-0002-4
5 https://doi.org/10.1002/chem.200304939
6 https://doi.org/10.1016/0277-5387(94)00431-d
7 https://doi.org/10.1021/ic034517y
8 https://doi.org/10.1021/ja962356+
9 schema:datePublished 2011-02
10 schema:datePublishedReg 2011-02-01
11 schema:description The reaction of cobalt(II) chloride with 2-hydroxypyridine (Hhp) and lithium pivalate in acetonitrile affords the 1D polymer [Li3CoCl(μ-Piv)(μ3-Piv)2(μ3,η2-Piv)(μ-Hhp)2(η1-HPiv)]n, in which the repeating units are linked by bridging pyridone molecules. The reaction of cobalt nitrate hexahydrate with 2-hydroxy-6-methylpyridine (Hmhp) in the presence of the deprotonating agent (Et3N) resulted in the crystallization of the 1D polymer of the composition [Li2Co7(μ3-OH)2(μ3-Piv)3(μ-Piv)2(μ3,η2-mhp)5(μ,η2-mhp)2(μ3-mhp)(μ,η2-NO3)·2MeCN]n, in which the bulky metal fragments {Li2Co7(OH)2(Piv)5)(mhp)8} are linked together through the lithium atoms by chelate bridging nitrate anions. The resulting 1D polymers were characterized by X-ray diffraction, and their magnetic properties were investigated.
12 schema:genre non_research_article
13 schema:inLanguage en
14 schema:isAccessibleForFree false
15 schema:isPartOf N72c6e238f7e248e38f3fbd242651953f
16 Nc7d05dc22d4c429dba99a2ba9bc1f595
17 sg:journal.1022309
18 schema:name Formation of cobalt- and lithium-containing heterometallic pyridonate carboxylate coordination polymers
19 schema:pagination 273
20 schema:productId Nd4fdad7e2c19489b81715af9ae11c22e
21 Nd57668d01bd545018e4adc0d1dedb774
22 Ndf5a28ff61584f5b8b56fd149082b442
23 schema:sameAs https://app.dimensions.ai/details/publication/pub.1035964239
24 https://doi.org/10.1007/s11172-011-0046-6
25 schema:sdDatePublished 2019-04-11T01:11
26 schema:sdLicense https://scigraph.springernature.com/explorer/license/
27 schema:sdPublisher Nf7d190c74b814ac481901bea9e6e51bb
28 schema:url http://link.springer.com/10.1007%2Fs11172-011-0046-6
29 sgo:license sg:explorer/license/
30 sgo:sdDataset articles
31 rdf:type schema:ScholarlyArticle
32 N134d9ff0d4ae4490a2dabfc171c8cf45 rdf:first sg:person.013111041721.71
33 rdf:rest Nb2946c419d5e4ddaab02c40b0d5363cd
34 N1777ed745195426ca2f87c9d70ca2891 rdf:first sg:person.0745631435.08
35 rdf:rest rdf:nil
36 N72c6e238f7e248e38f3fbd242651953f schema:volumeNumber 60
37 rdf:type schema:PublicationVolume
38 Na58314db50fc4a009013e9d630d47fd0 rdf:first sg:person.014044746763.06
39 rdf:rest N1777ed745195426ca2f87c9d70ca2891
40 Nae2929097f8f400d87c94f9b1117cd29 rdf:first sg:person.011677017467.94
41 rdf:rest Na58314db50fc4a009013e9d630d47fd0
42 Nb2946c419d5e4ddaab02c40b0d5363cd rdf:first sg:person.010710432427.45
43 rdf:rest Ne6141b8831ad49c0bbf6dc30738ec338
44 Nc7d05dc22d4c429dba99a2ba9bc1f595 schema:issueNumber 2
45 rdf:type schema:PublicationIssue
46 Nd4fdad7e2c19489b81715af9ae11c22e schema:name readcube_id
47 schema:value ab5219637b85a920d5333e2596af39581eee56618fd652a6642fdd971b095766
48 rdf:type schema:PropertyValue
49 Nd57668d01bd545018e4adc0d1dedb774 schema:name dimensions_id
50 schema:value pub.1035964239
51 rdf:type schema:PropertyValue
52 Ndf5a28ff61584f5b8b56fd149082b442 schema:name doi
53 schema:value 10.1007/s11172-011-0046-6
54 rdf:type schema:PropertyValue
55 Ne6141b8831ad49c0bbf6dc30738ec338 rdf:first sg:person.01172445335.81
56 rdf:rest Nae2929097f8f400d87c94f9b1117cd29
57 Nf7d190c74b814ac481901bea9e6e51bb schema:name Springer Nature - SN SciGraph project
58 rdf:type schema:Organization
59 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
60 schema:name Chemical Sciences
61 rdf:type schema:DefinedTerm
62 anzsrc-for:0303 schema:inDefinedTermSet anzsrc-for:
63 schema:name Macromolecular and Materials Chemistry
64 rdf:type schema:DefinedTerm
65 sg:journal.1022309 schema:issn 1066-5285
66 1573-9171
67 schema:name Russian Chemical Bulletin
68 rdf:type schema:Periodical
69 sg:person.010710432427.45 schema:affiliation https://www.grid.ac/institutes/grid.4886.2
70 schema:familyName Nikiforova
71 schema:givenName M. E.
72 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010710432427.45
73 rdf:type schema:Person
74 sg:person.011677017467.94 schema:affiliation https://www.grid.ac/institutes/grid.415877.8
75 schema:familyName Bogomyakov
76 schema:givenName A. S.
77 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011677017467.94
78 rdf:type schema:Person
79 sg:person.01172445335.81 schema:affiliation https://www.grid.ac/institutes/grid.4886.2
80 schema:familyName Kiskin
81 schema:givenName M. A.
82 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01172445335.81
83 rdf:type schema:Person
84 sg:person.013111041721.71 schema:affiliation https://www.grid.ac/institutes/grid.4886.2
85 schema:familyName Zauzolkova
86 schema:givenName N. V.
87 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013111041721.71
88 rdf:type schema:Person
89 sg:person.014044746763.06 schema:affiliation https://www.grid.ac/institutes/grid.4886.2
90 schema:familyName Sidorov
91 schema:givenName A. A.
92 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014044746763.06
93 rdf:type schema:Person
94 sg:person.0745631435.08 schema:affiliation https://www.grid.ac/institutes/grid.4886.2
95 schema:familyName Eremenko
96 schema:givenName I. L.
97 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0745631435.08
98 rdf:type schema:Person
99 sg:pub.10.1007/s10876-005-0002-4 schema:sameAs https://app.dimensions.ai/details/publication/pub.1017560423
100 https://doi.org/10.1007/s10876-005-0002-4
101 rdf:type schema:CreativeWork
102 https://doi.org/10.1002/chem.200304939 schema:sameAs https://app.dimensions.ai/details/publication/pub.1012921690
103 rdf:type schema:CreativeWork
104 https://doi.org/10.1016/0277-5387(94)00431-d schema:sameAs https://app.dimensions.ai/details/publication/pub.1004401217
105 rdf:type schema:CreativeWork
106 https://doi.org/10.1021/ic034517y schema:sameAs https://app.dimensions.ai/details/publication/pub.1055555827
107 rdf:type schema:CreativeWork
108 https://doi.org/10.1021/ja962356+ schema:sameAs https://app.dimensions.ai/details/publication/pub.1055865645
109 rdf:type schema:CreativeWork
110 https://www.grid.ac/institutes/grid.415877.8 schema:alternateName Siberian Branch of the Russian Academy of Sciences
111 schema:name International Tomography Center, Siberian Branch of the Russian Academy of Sciences, 3a ul. Institutskaya, 630090, Novosibirsk, Russian Federation
112 rdf:type schema:Organization
113 https://www.grid.ac/institutes/grid.4886.2 schema:alternateName Russian Academy of Sciences
114 schema:name N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 31 Leninsky prosp., 119991, Moscow, Russian Federation
115 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...