Formation of cobalt- and lithium-containing heterometallic pyridonate carboxylate coordination polymers View Full Text


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Article Info

DATE

2011-02

AUTHORS

N. V. Zauzolkova, M. E. Nikiforova, M. A. Kiskin, A. S. Bogomyakov, A. A. Sidorov, I. L. Eremenko

ABSTRACT

The reaction of cobalt(II) chloride with 2-hydroxypyridine (Hhp) and lithium pivalate in acetonitrile affords the 1D polymer [Li3CoCl(μ-Piv)(μ3-Piv)2(μ3,η2-Piv)(μ-Hhp)2(η1-HPiv)]n, in which the repeating units are linked by bridging pyridone molecules. The reaction of cobalt nitrate hexahydrate with 2-hydroxy-6-methylpyridine (Hmhp) in the presence of the deprotonating agent (Et3N) resulted in the crystallization of the 1D polymer of the composition [Li2Co7(μ3-OH)2(μ3-Piv)3(μ-Piv)2(μ3,η2-mhp)5(μ,η2-mhp)2(μ3-mhp)(μ,η2-NO3)·2MeCN]n, in which the bulky metal fragments {Li2Co7(OH)2(Piv)5)(mhp)8} are linked together through the lithium atoms by chelate bridging nitrate anions. The resulting 1D polymers were characterized by X-ray diffraction, and their magnetic properties were investigated. More... »

PAGES

273

References to SciGraph publications

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URI

http://scigraph.springernature.com/pub.10.1007/s11172-011-0046-6

DOI

http://dx.doi.org/10.1007/s11172-011-0046-6

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