Ontology type: schema:ScholarlyArticle
2010-11
AUTHORSD. M. Panov, A. V. Polezhaev, A. V. Polukeev, P. V. Petrovskii, A. A. Koridze
ABSTRACTThe alkylation of imidazole and 5-benzyloxycarbonyl-3,4-diethylpyrrole with 1,3-bis-(hydroxymethyl)ferrocene (1) afforded bis-imidazole (4) and bis-pyrrole (7) derivatives of ferrocene, respectively. The reaction of diol 1 with trifluoroacetic acid gave the dicarbocationic complex [{1,3-(CH2)2C5H3}Fe(C5H5)]2+ (2) characterized by 1H NMR spectroscopy.
PAGES2098-2101
http://scigraph.springernature.com/pub.10.1007/s11172-010-0361-3
DOIhttp://dx.doi.org/10.1007/s11172-010-0361-3
DIMENSIONShttps://app.dimensions.ai/details/publication/pub.1003043533
JSON-LD is the canonical representation for SciGraph data.
TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT
[
{
"@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json",
"about": [
{
"id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03",
"inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/",
"name": "Chemical Sciences",
"type": "DefinedTerm"
},
{
"id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0306",
"inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/",
"name": "Physical Chemistry (incl. Structural)",
"type": "DefinedTerm"
}
],
"author": [
{
"affiliation": {
"alternateName": "A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991, Moscow, Russian Federation",
"id": "http://www.grid.ac/institutes/grid.431939.5",
"name": [
"A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991, Moscow, Russian Federation"
],
"type": "Organization"
},
"familyName": "Panov",
"givenName": "D. M.",
"id": "sg:person.0676214111.65",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0676214111.65"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991, Moscow, Russian Federation",
"id": "http://www.grid.ac/institutes/grid.431939.5",
"name": [
"A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991, Moscow, Russian Federation"
],
"type": "Organization"
},
"familyName": "Polezhaev",
"givenName": "A. V.",
"id": "sg:person.013753072661.02",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013753072661.02"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991, Moscow, Russian Federation",
"id": "http://www.grid.ac/institutes/grid.431939.5",
"name": [
"A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991, Moscow, Russian Federation"
],
"type": "Organization"
},
"familyName": "Polukeev",
"givenName": "A. V.",
"id": "sg:person.014163522737.93",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014163522737.93"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991, Moscow, Russian Federation",
"id": "http://www.grid.ac/institutes/grid.431939.5",
"name": [
"A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991, Moscow, Russian Federation"
],
"type": "Organization"
},
"familyName": "Petrovskii",
"givenName": "P. V.",
"id": "sg:person.014725472203.42",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014725472203.42"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "Institute of Metalloorganic Chemistry, I. Javakhishvili Tbilisi State University, 3 Chavchavadze Avenue, 0128, Tbilisi, Georgia",
"id": "http://www.grid.ac/institutes/grid.26193.3f",
"name": [
"A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991, Moscow, Russian Federation",
"Institute of Metalloorganic Chemistry, I. Javakhishvili Tbilisi State University, 3 Chavchavadze Avenue, 0128, Tbilisi, Georgia"
],
"type": "Organization"
},
"familyName": "Koridze",
"givenName": "A. A.",
"id": "sg:person.0613225461.83",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0613225461.83"
],
"type": "Person"
}
],
"datePublished": "2010-11",
"datePublishedReg": "2010-11-01",
"description": "The alkylation of imidazole and 5-benzyloxycarbonyl-3,4-diethylpyrrole with 1,3-bis-(hydroxymethyl)ferrocene (1) afforded bis-imidazole (4) and bis-pyrrole (7) derivatives of ferrocene, respectively. The reaction of diol 1 with trifluoroacetic acid gave the dicarbocationic complex [{1,3-(CH2)2C5H3}Fe(C5H5)]2+ (2) characterized by 1H NMR spectroscopy.",
"genre": "article",
"id": "sg:pub.10.1007/s11172-010-0361-3",
"isAccessibleForFree": false,
"isPartOf": [
{
"id": "sg:journal.1022309",
"issn": [
"1063-5211",
"1026-3500"
],
"name": "Russian Chemical Bulletin",
"publisher": "Springer Nature",
"type": "Periodical"
},
{
"issueNumber": "11",
"type": "PublicationIssue"
},
{
"type": "PublicationVolume",
"volumeNumber": "59"
}
],
"keywords": [
"alkylation of imidazole",
"NMR spectroscopy",
"nitrogen heterocycles",
"trifluoroacetic acid",
"diol 1",
"alkylation",
"diethylpyrrole",
"ferrocene",
"heterocycles",
"imidazole",
"spectroscopy",
"derivatives",
"reaction",
"complexes",
"Bi",
"acid",
"generation"
],
"name": "Alkylation of nitrogen heterocycles with 1,3-bis(hydroxymethyl)ferrocene. Generation of the ferrocene dicarbocation [{1,3-(CH2)2C5H3}Fe(C5H5)]2+",
"pagination": "2098-2101",
"productId": [
{
"name": "dimensions_id",
"type": "PropertyValue",
"value": [
"pub.1003043533"
]
},
{
"name": "doi",
"type": "PropertyValue",
"value": [
"10.1007/s11172-010-0361-3"
]
}
],
"sameAs": [
"https://doi.org/10.1007/s11172-010-0361-3",
"https://app.dimensions.ai/details/publication/pub.1003043533"
],
"sdDataset": "articles",
"sdDatePublished": "2022-08-04T16:58",
"sdLicense": "https://scigraph.springernature.com/explorer/license/",
"sdPublisher": {
"name": "Springer Nature - SN SciGraph project",
"type": "Organization"
},
"sdSource": "s3://com-springernature-scigraph/baseset/20220804/entities/gbq_results/article/article_521.jsonl",
"type": "ScholarlyArticle",
"url": "https://doi.org/10.1007/s11172-010-0361-3"
}
]
Download the RDF metadata as: json-ld nt turtle xml License info
JSON-LD is a popular format for linked data which is fully compatible with JSON.
curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/s11172-010-0361-3'
N-Triples is a line-based linked data format ideal for batch operations.
curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/s11172-010-0361-3'
Turtle is a human-readable linked data format.
curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/s11172-010-0361-3'
RDF/XML is a standard XML format for linked data.
curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/s11172-010-0361-3'
This table displays all metadata directly associated to this object as RDF triples.
106 TRIPLES
20 PREDICATES
42 URIs
34 LITERALS
6 BLANK NODES