Alkylation of nitrogen heterocycles with 1,3-bis(hydroxymethyl)ferrocene. Generation of the ferrocene dicarbocation [{1,3-(CH2)2C5H3}Fe(C5H5)]2+ View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2010-11

AUTHORS

D. M. Panov, A. V. Polezhaev, A. V. Polukeev, P. V. Petrovskii, A. A. Koridze

ABSTRACT

The alkylation of imidazole and 5-benzyloxycarbonyl-3,4-diethylpyrrole with 1,3-bis-(hydroxymethyl)ferrocene (1) afforded bis-imidazole (4) and bis-pyrrole (7) derivatives of ferrocene, respectively. The reaction of diol 1 with trifluoroacetic acid gave the dicarbocationic complex [{1,3-(CH2)2C5H3}Fe(C5H5)]2+ (2) characterized by 1H NMR spectroscopy.

PAGES

2098-2101

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s11172-010-0361-3

DOI

http://dx.doi.org/10.1007/s11172-010-0361-3

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1003043533


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