P,C,P-Pincer complexes of ruthenium based on ruthenocene and pentamethylruthenocene View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2010-09

AUTHORS

S. V. Safronov, A. M. Sheloumov, A. Z. Kreindlin, A. A. Kamyshova, F. M. Dolgushin, A. F. Smolyakov, P. V. Petrovskii, M. G. Ezernitskaya, A. A. Koridze

ABSTRACT

The first ruthenocene- and pentamethylruthenocene-based ruthenium pincer complexes, RuCl(CO)[{2,5-(But2PCH2)2C5H2}Ru(C5H5)] and RuCl(CO)[{2,5-(But2PCH2)2C5H2}Ru-(C5Me5)], were synthesized by cyclometallation of {1,3-(But2PCH2)2C5H2}Ru(C5H5) and {1,3-(But2PCH2)2C5H2}Ru(C5Me5), respectively, with RuCl2(DMSO)4 in 2-methoxyethanol and characterized by 1H and 31P{1H} NMR spectroscopy, and X-ray diffraction.

PAGES

1740-1744

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s11172-010-0306-x

DOI

http://dx.doi.org/10.1007/s11172-010-0306-x

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1005739514


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