Ontology type: schema:ScholarlyArticle
2010-06
AUTHORSN. V. Zauzolkova, M. E. Nikiforova, A. A. Sidorov, I. A. Apolonskaya, M. V. Fedin, V. V. Minin, A. V. Rotov, E. A. Ugolkova, M. A. Kiskin, G. G. Aleksandrov, V. M. Novotortsev, I. L. Eremenko
ABSTRACTThe reaction of copper nitrate Cu(NO3)2·3H2O with potassium salt of 1,1-cyclohexanediacetic acid (H2CHDAA) in an EtOH-toluene mixture affords the polymeric complex {[(EtOH)2Cu2(CHDAA)2]·EtOHn (1). The addition of pyridine to the Cu(NO3)2·3H2O-K2CHDAA reaction system in an EtOH-MeCN mixture results in the isolation of the unusual octadecanuclear heterometallic cluster [K2(η1-H2O)6(η1-py)8Cu16-(η1-OH)2(μ4-CHDAA)16]·EtOH·MeCN·3H2O (2). In complex 2, the hexadecanuclear metal carboxylate dianion (η1-H2O)6(η1-py)8Cu16(η1-OH)2(μ4-CHDAA)16 acts as the metal-containing macropolycyclic ligand. The newly synthesized compounds 1 and 2 were characterized by X-ray diffraction and EPR. More... »
PAGES1186-1191
http://scigraph.springernature.com/pub.10.1007/s11172-010-0221-1
DOIhttp://dx.doi.org/10.1007/s11172-010-0221-1
DIMENSIONShttps://app.dimensions.ai/details/publication/pub.1051057503
JSON-LD is the canonical representation for SciGraph data.
TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT
[
{
"@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json",
"about": [
{
"id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03",
"inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/",
"name": "Chemical Sciences",
"type": "DefinedTerm"
},
{
"id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0302",
"inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/",
"name": "Inorganic Chemistry",
"type": "DefinedTerm"
}
],
"author": [
{
"affiliation": {
"alternateName": "N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 31 Leninsky prosp., 119991, Moscow, Russian Federation",
"id": "http://www.grid.ac/institutes/grid.435216.7",
"name": [
"N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 31 Leninsky prosp., 119991, Moscow, Russian Federation"
],
"type": "Organization"
},
"familyName": "Zauzolkova",
"givenName": "N. V.",
"id": "sg:person.013111041721.71",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013111041721.71"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 31 Leninsky prosp., 119991, Moscow, Russian Federation",
"id": "http://www.grid.ac/institutes/grid.435216.7",
"name": [
"N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 31 Leninsky prosp., 119991, Moscow, Russian Federation"
],
"type": "Organization"
},
"familyName": "Nikiforova",
"givenName": "M. E.",
"id": "sg:person.010710432427.45",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010710432427.45"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 31 Leninsky prosp., 119991, Moscow, Russian Federation",
"id": "http://www.grid.ac/institutes/grid.435216.7",
"name": [
"N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 31 Leninsky prosp., 119991, Moscow, Russian Federation"
],
"type": "Organization"
},
"familyName": "Sidorov",
"givenName": "A. A.",
"id": "sg:person.014044746763.06",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014044746763.06"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 31 Leninsky prosp., 119991, Moscow, Russian Federation",
"id": "http://www.grid.ac/institutes/grid.435216.7",
"name": [
"N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 31 Leninsky prosp., 119991, Moscow, Russian Federation"
],
"type": "Organization"
},
"familyName": "Apolonskaya",
"givenName": "I. A.",
"id": "sg:person.01274367752.26",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01274367752.26"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "International Tomography Center, Siberian Branch of the Russian Academy of Sciences, 3a ul. Institutskaya, 630090, Novosibirsk, Russian Federation",
"id": "http://www.grid.ac/institutes/grid.415877.8",
"name": [
"International Tomography Center, Siberian Branch of the Russian Academy of Sciences, 3a ul. Institutskaya, 630090, Novosibirsk, Russian Federation"
],
"type": "Organization"
},
"familyName": "Fedin",
"givenName": "M. V.",
"id": "sg:person.01062002050.07",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01062002050.07"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 31 Leninsky prosp., 119991, Moscow, Russian Federation",
"id": "http://www.grid.ac/institutes/grid.435216.7",
"name": [
"N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 31 Leninsky prosp., 119991, Moscow, Russian Federation"
],
"type": "Organization"
},
"familyName": "Minin",
"givenName": "V. V.",
"id": "sg:person.011207441575.56",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.011207441575.56"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 31 Leninsky prosp., 119991, Moscow, Russian Federation",
"id": "http://www.grid.ac/institutes/grid.435216.7",
"name": [
"N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 31 Leninsky prosp., 119991, Moscow, Russian Federation"
],
"type": "Organization"
},
"familyName": "Rotov",
"givenName": "A. V.",
"id": "sg:person.010424144647.30",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010424144647.30"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 31 Leninsky prosp., 119991, Moscow, Russian Federation",
"id": "http://www.grid.ac/institutes/grid.435216.7",
"name": [
"N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 31 Leninsky prosp., 119991, Moscow, Russian Federation"
],
"type": "Organization"
},
"familyName": "Ugolkova",
"givenName": "E. A.",
"id": "sg:person.015265162315.78",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.015265162315.78"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 31 Leninsky prosp., 119991, Moscow, Russian Federation",
"id": "http://www.grid.ac/institutes/grid.435216.7",
"name": [
"N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 31 Leninsky prosp., 119991, Moscow, Russian Federation"
],
"type": "Organization"
},
"familyName": "Kiskin",
"givenName": "M. A.",
"id": "sg:person.01172445335.81",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01172445335.81"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 31 Leninsky prosp., 119991, Moscow, Russian Federation",
"id": "http://www.grid.ac/institutes/grid.435216.7",
"name": [
"N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 31 Leninsky prosp., 119991, Moscow, Russian Federation"
],
"type": "Organization"
},
"familyName": "Aleksandrov",
"givenName": "G. G.",
"id": "sg:person.014422304747.19",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014422304747.19"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 31 Leninsky prosp., 119991, Moscow, Russian Federation",
"id": "http://www.grid.ac/institutes/grid.435216.7",
"name": [
"N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 31 Leninsky prosp., 119991, Moscow, Russian Federation"
],
"type": "Organization"
},
"familyName": "Novotortsev",
"givenName": "V. M.",
"id": "sg:person.01013744635.03",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01013744635.03"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 31 Leninsky prosp., 119991, Moscow, Russian Federation",
"id": "http://www.grid.ac/institutes/grid.435216.7",
"name": [
"N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 31 Leninsky prosp., 119991, Moscow, Russian Federation"
],
"type": "Organization"
},
"familyName": "Eremenko",
"givenName": "I. L.",
"id": "sg:person.0745631435.08",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0745631435.08"
],
"type": "Person"
}
],
"citation": [
{
"id": "sg:pub.10.1007/s10870-005-9001-4",
"sameAs": [
"https://app.dimensions.ai/details/publication/pub.1036380892",
"https://doi.org/10.1007/s10870-005-9001-4"
],
"type": "CreativeWork"
}
],
"datePublished": "2010-06",
"datePublishedReg": "2010-06-01",
"description": "The reaction of copper nitrate Cu(NO3)2\u00b73H2O with potassium salt of 1,1-cyclohexanediacetic acid (H2CHDAA) in an EtOH-toluene mixture affords the polymeric complex {[(EtOH)2Cu2(CHDAA)2]\u00b7EtOHn (1). The addition of pyridine to the Cu(NO3)2\u00b73H2O-K2CHDAA reaction system in an EtOH-MeCN mixture results in the isolation of the unusual octadecanuclear heterometallic cluster [K2(\u03b71-H2O)6(\u03b71-py)8Cu16-(\u03b71-OH)2(\u03bc4-CHDAA)16]\u00b7EtOH\u00b7MeCN\u00b73H2O (2). In complex 2, the hexadecanuclear metal carboxylate dianion (\u03b71-H2O)6(\u03b71-py)8Cu16(\u03b71-OH)2(\u03bc4-CHDAA)16 acts as the metal-containing macropolycyclic ligand. The newly synthesized compounds 1 and 2 were characterized by X-ray diffraction and EPR.",
"genre": "article",
"id": "sg:pub.10.1007/s11172-010-0221-1",
"inLanguage": "en",
"isAccessibleForFree": false,
"isPartOf": [
{
"id": "sg:journal.1022309",
"issn": [
"1026-3500",
"1066-5285"
],
"name": "Russian Chemical Bulletin",
"publisher": "Springer Nature",
"type": "Periodical"
},
{
"issueNumber": "6",
"type": "PublicationIssue"
},
{
"type": "PublicationVolume",
"volumeNumber": "59"
}
],
"keywords": [
"addition of pyridine",
"polynuclear architectures",
"polymeric complexes",
"macropolycyclic ligands",
"carboxylate dianions",
"heterometallic clusters",
"copper nitrate",
"copper atoms",
"compound 1",
"ray diffraction",
"reaction system",
"potassium salt",
"mixture results",
"dianion",
"anions",
"\u03b71",
"pyridine",
"EPR",
"ligands",
"diffraction",
"salt",
"atoms",
"reaction",
"complexes",
"mixture",
"nitrate",
"acid",
"formation",
"clusters",
"isolation",
"addition",
"system",
"architecture",
"results"
],
"name": "Formation of polynuclear architectures with copper atoms and 1,1-cyclohexanediacetate anions",
"pagination": "1186-1191",
"productId": [
{
"name": "dimensions_id",
"type": "PropertyValue",
"value": [
"pub.1051057503"
]
},
{
"name": "doi",
"type": "PropertyValue",
"value": [
"10.1007/s11172-010-0221-1"
]
}
],
"sameAs": [
"https://doi.org/10.1007/s11172-010-0221-1",
"https://app.dimensions.ai/details/publication/pub.1051057503"
],
"sdDataset": "articles",
"sdDatePublished": "2022-06-01T22:07",
"sdLicense": "https://scigraph.springernature.com/explorer/license/",
"sdPublisher": {
"name": "Springer Nature - SN SciGraph project",
"type": "Organization"
},
"sdSource": "s3://com-springernature-scigraph/baseset/20220601/entities/gbq_results/article/article_502.jsonl",
"type": "ScholarlyArticle",
"url": "https://doi.org/10.1007/s11172-010-0221-1"
}
]Download the RDF metadata as: json-ld nt turtle xml License info
JSON-LD is a popular format for linked data which is fully compatible with JSON.
curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/s11172-010-0221-1'
N-Triples is a line-based linked data format ideal for batch operations.
curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/s11172-010-0221-1'
Turtle is a human-readable linked data format.
curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/s11172-010-0221-1'
RDF/XML is a standard XML format for linked data.
curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/s11172-010-0221-1'
This table displays all metadata directly associated to this object as RDF triples.
176 TRIPLES
22 PREDICATES
61 URIs
52 LITERALS
6 BLANK NODES