Ontology type: schema:ScholarlyArticle
2010-06
AUTHORSN. V. Zauzolkova, M. E. Nikiforova, A. A. Sidorov, I. A. Apolonskaya, M. V. Fedin, V. V. Minin, A. V. Rotov, E. A. Ugolkova, M. A. Kiskin, G. G. Aleksandrov, V. M. Novotortsev, I. L. Eremenko
ABSTRACTThe reaction of copper nitrate Cu(NO3)2·3H2O with potassium salt of 1,1-cyclohexanediacetic acid (H2CHDAA) in an EtOH-toluene mixture affords the polymeric complex {[(EtOH)2Cu2(CHDAA)2]·EtOHn (1). The addition of pyridine to the Cu(NO3)2·3H2O-K2CHDAA reaction system in an EtOH-MeCN mixture results in the isolation of the unusual octadecanuclear heterometallic cluster [K2(η1-H2O)6(η1-py)8Cu16-(η1-OH)2(μ4-CHDAA)16]·EtOH·MeCN·3H2O (2). In complex 2, the hexadecanuclear metal carboxylate dianion (η1-H2O)6(η1-py)8Cu16(η1-OH)2(μ4-CHDAA)16 acts as the metal-containing macropolycyclic ligand. The newly synthesized compounds 1 and 2 were characterized by X-ray diffraction and EPR. More... »
PAGES1186-1191
http://scigraph.springernature.com/pub.10.1007/s11172-010-0221-1
DOIhttp://dx.doi.org/10.1007/s11172-010-0221-1
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