Quantum chemical interpretation of different types of exchange magnetic interactions in dinuclear copper azomethine chelates View Full Text


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Article Info

DATE

2010-03

AUTHORS

K. V. Bozhenko, S. M. Aldoshin, V. I. Minkin, A. D. Garnovskii, I. S. Vasilchenko, A. N. Utenyshev, A. A. Khrulev

ABSTRACT

B3LYP/LANL2DZ calculations of two series of isomeric dinuclear copper chelates based on the tridentate dibasic salicylaldimines from aromatic and heterocyclic amines were performed. According to calculations, the complexes with N,N-or S,S-donor atoms in the exchange fragment are mainly characterized by ferromagnetic exchange, whereas the formation of O, O-bridging fragments leads to antiferromagnetic spin-spin interaction. More... »

PAGES

489-496

References to SciGraph publications

  • 2007-03. 1-amino-2-thiobenzimidazoleimines as novel ambidentate ligand systems in RUSSIAN JOURNAL OF COORDINATION CHEMISTRY
  • Identifiers

    URI

    http://scigraph.springernature.com/pub.10.1007/s11172-010-0140-1

    DOI

    http://dx.doi.org/10.1007/s11172-010-0140-1

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