Cyclothiomethylation of carboxylic acid hydrazides with aldehydes and H2S View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2010-02

AUTHORS

V. R. Akhmetova, R. R. Khairullina, T. V. Tyumkina, Yu. V. Nelyubina, A. F. Smol’yakov, I. S. Bushmarinov, Z. A. Starikova, M. F. Abdullin, R. V. Kunakova

ABSTRACT

The cyclothiomethylation of carboxylic acid hydrazides RCONHNH2 (R = C5H4N, Ph, 2-MeOC6H4, or 4-HOC6H4CH2) with formaldehyde and H2S at 70 °C affords predominantly the corresponding N-(1,3,5-dithiazinan-5-yl)amides, whereas this reaction at 0–−50 °C gives a mixture of the latter compounds with 3-acyl-1,3,4-thiadiazolidines. N-(1,3,5-Dithiazinan-5-yl)-amides were selectively synthesized by the reaction of carboxylic acid hydrazides with formaldehyde and H2S in the presence of BuONa in BuOH. More... »

PAGES

425-433

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s11172-010-0096-1

DOI

http://dx.doi.org/10.1007/s11172-010-0096-1

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1006539182


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