A new preparative method for the synthesis of diethyl 1-diazo-2,2,2-trifluoroethylphosphonate via an imino phosphonate View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2010-01

AUTHORS

N. M. Karimova, D. V. Vorobyeva, G. T. Shchetnikov, S. N. Osipov

ABSTRACT

A preparative method for the synthesis of diethyl 1-diazo-2,2,2-trifluoroethylphosphonate from trifluoroacetic anhydride and benzyl carbamate via diethyl 1-benzyloxycarbonylimino-2,2,2-trifluoroethylphosphonate is developed. Optimum conditions for the chlorination of benzyl N-trifluoroacetylcarbamate with SOCl2—Py to afford the imidoyl chloride, phosphorylation of the latter under the conditions of the Arbuzov reaction, as well as diazotization of amino phosphonate with isopropyl nitrite are found. More... »

PAGES

107-109

References to SciGraph publications

Journal

TITLE

Russian Chemical Bulletin

ISSUE

1

VOLUME

59

Author Affiliations

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s11172-010-0051-1

DOI

http://dx.doi.org/10.1007/s11172-010-0051-1

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1027874960


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