Debenzylation of 2,6,8,12-tetraacetyl-4,10-dibenzyl-2,4,6,8,10,12-hexaazatetracyclo[5.5.0.03,11.05,9]dodecane View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2009-10

AUTHORS

A. I. Kalashnikov, S. V. Sysolyatin, G. V. Sakovich, I. A. Surmacheva, V. N. Surmachev, Yu. T. Lapina

ABSTRACT

The debenzylation of 2,6,8,12-tetraacetyl-4,10-dibenzyl-2,4,6,8,10,12-hexaazatetra-cyclo[5.5.0.03,11.05,9]dodecane by catalytic hydrogenolysis in a mixture of HCOOH with other RCOOH (R = Me, Et, Pri) is accompanied by the N-formylation of the liberated secondary amino groups. The alkaline hydrolysis of the obtained products makes it possible to remove the formyl groups with the retention of the acetyl groups. More... »

PAGES

2164-2168

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s11172-009-0295-9

DOI

http://dx.doi.org/10.1007/s11172-009-0295-9

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1033914869


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