Reactivity of metal-containing monomers 66. Hydrogenation of nitrotoluene derivatives in the presence of polymer-immobilized Pd nanoparticles View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2009-10

AUTHORS

G. I. Dzhardimalieva, V. G. Dorokhov, N. D. Golubeva, S. I. Pomogailo, A. M. Lyakhovich, V. I. Savchenko, A. D. Pomogailo

ABSTRACT

A new approach to the synthesis of immobilized catalysts of the mixed type was developed: frontal polymerization of metal-containing monomers in the presence of a highly dispersed inorganic support. The synthesis of the acrylamide complex of PdII nitrate on the SiO2 surface followed by polymerization and reduction results in the formation of a polymer-inorganic composite with inclusions of Pd nanoparticles stabilized by the polymer matrix on the support surface. The study of the catalytic properties in the hydrogenation of nitrotoluene derivatives showed that the polymer-immobilized Pd nanoparticles on the inorganic support are efficient catalysts for the reduction of the nitrocompounds. More... »

PAGES

2070-2076

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s11172-009-0284-z

DOI

http://dx.doi.org/10.1007/s11172-009-0284-z

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1021337666


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