Ruthenium bis(phosphinite) pincer complexes View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2009-08

AUTHORS

D. M. Ivanov, S. A. Kuklin, A. V. Polezhaev, P. V. Petrovskii, A. F. Smol’yakov, F. M. Dolgushin, M. G. Ezernitskaya, A. S. Peregudov, A. A. Koridze

ABSTRACT

Resorcinol-based ruthenium bis(phosphinite) complexes were synthesized. Complexes RuCl(CO)[2,6-(But2PO)2C6H3] (9) and RuH(CO)[2,6-(But2PO)2C6H3] (10) were obtained by cyclometallation of 1,3-(But2PO)2C6H3 with RuCl2(DMSO)4 in 2-methoxyethanol in the presence of Hünig’s base. The interconversion of complexes 9 and 10 was studied. The addition of carbon monoxide to complexes 9 and 10 yielded 18e adducts, RuCl(CO)2[2,6-(But2PO)2C6H3] (11) and RuH(CO)2[2,6-(But2PO)2C6H3] (12), respectively. In the case of complex 9, this reaction is reversible. Reaction of complex 10 with trifluoroacetic acid resulted in complex Ru(CF3COO)(CO)[2,6-(But2PO)2C6H3] (13), which reacted with carbon monoxide to give complex Ru(CF3COO)(CO)2[2,6-(But2PO)2C6H3] (14). Based on the IR spectral data, the TFA ligand in complexes 13 and 14 is bound in a bi- and monodentate fashion, respectively. The structure of compound 9 was determined by X-ray diffraction analysis. More... »

PAGES

1701-1706

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s11172-009-0235-8

DOI

http://dx.doi.org/10.1007/s11172-009-0235-8

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1047918076


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