On the mechanism of ferrocene oxidation under the conditions of electrospray ionization View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2009-07

AUTHORS

Yu. S. Nekrasov, Yu. A. Borisov, R. S. Skazov, A. N. Rodionov, A. A. Simenel, Yu. A. Belousov

ABSTRACT

The formation of molecular ions of ferrocene is detected under the «inverse» conditions of electrospray ionization where the pure solvent alone is electrosprayed in the presence of ferrocene vapor. The quantum chemical calculations using the B3LYP/LanL2DZ method suggest that the ferrocene oxidation occurs in the gas phase and follows the mechanism of activating protonation where a protonated molecule acts as an oxidant for another ferrocene molecule. More... »

PAGES

1521-1523

References to SciGraph publications

  • 2004-12-01. Effects of ground loop currents on signal intensities in electrospray mass spectrometry in JOURNAL OF THE AMERICAN SOCIETY FOR MASS SPECTROMETRY
  • Identifiers

    URI

    http://scigraph.springernature.com/pub.10.1007/s11172-009-0205-1

    DOI

    http://dx.doi.org/10.1007/s11172-009-0205-1

    DIMENSIONS

    https://app.dimensions.ai/details/publication/pub.1052964359


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