4,5-Dihydroxyimidazolidin-2-ones in α-ureidoalkylation of N-carboxy-, N-hydroxy-, and N-aminoalkylureas 2. α-Ureidoalkylation of N-(hydroxyalkyl)ureas View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2009-06

AUTHORS

A. N. Kravchenko, A. S. Sigachev, P. A. Belyakov, M. M. Ilyin, K. A. Lyssenko, V. A. Davankov, O. V. Lebedev, N. N. Makhova, V. A. Tartakovsky

ABSTRACT

The α-ureidoalkylation of N-(hydroxyalkyl)ureas (ureido alcohols) with 1,3-H2- and 1,3-Me2-4,5-dihydroxyimidazolidin-2-ones was systematically studied. The yields of glycolurils decrease both in going from 1,3-H2- to 1,3-Me2-4,5-dihydroxyimidazolidin-2-one and with increasing length (or with branching) of the hydroxyalkyl chain in ureido alcohols. The optimal reaction time for ureido alcohols is 1 h. The X-ray diffraction study showed that 2-(2-hydroxy-1,1-dimethylethyl)glycoluril crystallizes as a conglomerate. The enantiomeric analysis of 2-(2-hydroxyethyl)glycoluril was carried out by chiral-phase HPLC. More... »

PAGES

1264-1269

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s11172-009-0165-5

DOI

http://dx.doi.org/10.1007/s11172-009-0165-5

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1009071567


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