Heterocyclization of hydrazine with acetaldehyde and H2S View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2009-05

AUTHORS

V. R. Akhmetova, G. R. Nadyrgulova, N. N. Murzakova, Z. A. Starikova, M. Yu. Antipin, R. V. Kunakova

ABSTRACT

Hydrazine is regioselectively condensed with a mixture of acetaldehyde and H2S at a temperature below −10 °C to form 2,4,6,8-tetramethyl-3,7-dithia-1,5-diazabicyclo[3.3.0]-octane. The reaction at 0 °C with the reverse order of mixing of the starting reagents affords 2,4,6-trimethyl(1,3,5-dithiazinan-5-yl)amine as the major product.

PAGES

1091-1093

Journal

TITLE

Russian Chemical Bulletin

ISSUE

5

VOLUME

58

Author Affiliations

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s11172-009-0140-1

DOI

http://dx.doi.org/10.1007/s11172-009-0140-1

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1048818413


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