Structures of cerium manganese pivalates View Full Text


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Article Info

DATE

2009-01

AUTHORS

G. V. Romanenko, E. Yu. Fursova, V. I. Ovcharenko

ABSTRACT

The Ce,Mn mixed-metal polynuclear compounds [Ce 3Mn6(O)5(OH)3Piv12Cl2(THF)3]·2THF, [Ce3Mn8(O)8Piv16Cl2(HPiv)2]·C7H16, [Ce10Mn4(O)6(OH)12Piv16Cl2(THF)2]·2THF·2H2O, [CeMn11Cl3(O)8Piv15(H2O)]·CH2Cl2, and [CeMn8(O)8Piv12(HPiv)2(THF)2] were prepared and structurally characterized. The possibility of synthesizing p,d,f-heterospin complexes by replacing coordinated THF molecules by nitroxide molecules was exemplified by the reaction of [Ce3Mn6(O)5(OH)3Piv12Cl2(THF)3]·2THF with nitronyl nitroxides (NIT-R is 2-R-4,4,5,5-tetramethyl-24midazoline-l-oxyl 3-oxide; R is Me or 4-Py). The X-ray diffraction study of these complexes showed that [Ce3Mn6(O)5(OH)3Piv12Cl2(HPiv)(NIT-Me)2] and [CeMn8(O)8Piv12(NIT4-Py) 4] · 2C6H14 have a molecular structure and [Ce3Mn6(O)5(OH)3-Piv12Cl2(NIT-Me)(H2O)] is an infinite chain. More... »

PAGES

1-10

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s11172-009-0001-y

DOI

http://dx.doi.org/10.1007/s11172-009-0001-y

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1028569001


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