Synthesis and structures of complexes Os3(μ-H)2(CO)7(μ-RC5H3N){μ3-Ph2PCH2P(C6H4)Ph} (R = H, Me) with ortho-metalated pyridine ligands. The revised structure of the triosmium ... View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2008-10

AUTHORS

A. A. Koridze, S. A. Kuklin, N. A. Shtelzer, P. V. Petrovskii, F. M. Dolgushin, M. G. Ezernitskaya

ABSTRACT

The structure of the previously synthesized triosmium cluster was revised. The structure Os3(μ-H)2(CO)7(μ-C6H4){μ3-Ph2PCH2P(C6H4)Ph} suggested earlier was not confirmed. The cluster has the composition Os3(μ-H)2(CO)7(μ-C5H4N){μ3-Ph2PCH2P(C6H4)Ph} and contains the ortho-metalated pyridine ligand. The X-ray diffraction study of the complex Os3(μ-H)2(CO)7(μ-MeC5H3N){μ3-Ph2PCH2P(C6H4)Ph} containing the ortho-metalated 4-methylpyridine ligand made it possible to distinguish between the C and N atoms of the pyridine ligands in the resulting triosmium clusters. More... »

PAGES

2194

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s11172-008-0299-x

DOI

http://dx.doi.org/10.1007/s11172-008-0299-x

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1000596984


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