Influence of π stacking on the magnetic properties of the copper(II) complex with 6-phenyl-3-(2-pyridyl)-5-trifluoroacetylmethylidene-4,5-dihydro-1,2,4-triazine View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2008-03

AUTHORS

A. M. Prokhorov, D. N. Kozhevnikov, V. L. Rusinov, O. N. Chupakhin, G. G. Aleksandrov, Yu. N. Shvachko, D. V. Starichenko, A. V. Korolev, D. V. Bukhvalov, V. V. Ustinov

ABSTRACT

The new N,N,O-ligand 6-phenyl-3-(2-pyridyl)-5-(trifluoroacetylmethylidene)-4,5-dihydro-1,2,4-triazine (L) was synthesized, and its complex with CuII was prepared. The structure of the complex was established by X-ray diffraction. Magnetic measurements and ESR studies were carried out. Ab initio calculations of the electronic structure, exchange interactions, and the effective magnetic moment were performed. The intrastack polarization effect between the π states of 1,2,4-triazine and the d states of copper was revealed and numerically validated. More... »

PAGES

561-566

References to SciGraph publications

  • 1986. Magnetochemistry in NONE
  • Identifiers

    URI

    http://scigraph.springernature.com/pub.10.1007/s11172-008-0087-7

    DOI

    http://dx.doi.org/10.1007/s11172-008-0087-7

    DIMENSIONS

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