Tandem ESI mass spectrometry of 11α- and 11β-{4-[N,N-bis(2-chloroethyl)amino]phenyl}acetates of the estrane steroids View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2008-01

AUTHORS

V. I. Kadentsev, A. O. Chizhov, O. S. Chizhov, N. G. Kolotyrkina, A. A. Kutin, V. M. Rzheznikov, L. E. Golubovskaya

ABSTRACT

ESI MS studies showed that the major collision-activated fragmentation pathway of the [M + Na]+ ions of the title estranes involves elimination of NaCl and HCl molecules. Fragmentation of the [M + H]+ ions involves the functional groups, which provides information on their structures. The fragmentation of the [M + Na]+ and [M + H]+ ions was estimated by quantum-chemical calculations. More... »

PAGES

95-98

References to SciGraph publications

  • 1999-12. New developments in plant pathology in Japan in AUSTRALASIAN PLANT PATHOLOGY
  • Identifiers

    URI

    http://scigraph.springernature.com/pub.10.1007/s11172-008-0014-y

    DOI

    http://dx.doi.org/10.1007/s11172-008-0014-y

    DIMENSIONS

    https://app.dimensions.ai/details/publication/pub.1013829165


    Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
    Incoming Citations Browse incoming citations for this publication using opencitations.net

    JSON-LD is the canonical representation for SciGraph data.

    TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

    [
      {
        "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
        "about": [
          {
            "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
            "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
            "name": "Chemical Sciences", 
            "type": "DefinedTerm"
          }
        ], 
        "author": [
          {
            "affiliation": {
              "alternateName": "N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 119991, Moscow, Russian Federation", 
              "id": "http://www.grid.ac/institutes/grid.439283.7", 
              "name": [
                "N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 119991, Moscow, Russian Federation"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Kadentsev", 
            "givenName": "V. I.", 
            "id": "sg:person.01270127225.37", 
            "sameAs": [
              "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01270127225.37"
            ], 
            "type": "Person"
          }, 
          {
            "affiliation": {
              "alternateName": "N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 119991, Moscow, Russian Federation", 
              "id": "http://www.grid.ac/institutes/grid.439283.7", 
              "name": [
                "N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 119991, Moscow, Russian Federation"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Chizhov", 
            "givenName": "A. O.", 
            "id": "sg:person.01074552527.75", 
            "sameAs": [
              "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01074552527.75"
            ], 
            "type": "Person"
          }, 
          {
            "affiliation": {
              "alternateName": "N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 119991, Moscow, Russian Federation", 
              "id": "http://www.grid.ac/institutes/grid.439283.7", 
              "name": [
                "N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 119991, Moscow, Russian Federation"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Chizhov", 
            "givenName": "O. S.", 
            "id": "sg:person.014663256724.68", 
            "sameAs": [
              "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014663256724.68"
            ], 
            "type": "Person"
          }, 
          {
            "affiliation": {
              "alternateName": "N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 119991, Moscow, Russian Federation", 
              "id": "http://www.grid.ac/institutes/grid.439283.7", 
              "name": [
                "N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 119991, Moscow, Russian Federation"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Kolotyrkina", 
            "givenName": "N. G.", 
            "id": "sg:person.016374705303.78", 
            "sameAs": [
              "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016374705303.78"
            ], 
            "type": "Person"
          }, 
          {
            "affiliation": {
              "alternateName": "N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 119991, Moscow, Russian Federation", 
              "id": "http://www.grid.ac/institutes/grid.439283.7", 
              "name": [
                "N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 119991, Moscow, Russian Federation"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Kutin", 
            "givenName": "A. A.", 
            "id": "sg:person.0576251203.31", 
            "sameAs": [
              "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0576251203.31"
            ], 
            "type": "Person"
          }, 
          {
            "affiliation": {
              "alternateName": "Endocrinological Research Center of the Federal Agency for High-Technology Medical Assistance, 11 ul. Dmitriya Ul\u2019yanova, 117036, Moscow, Russian Federation", 
              "id": "http://www.grid.ac/institutes/None", 
              "name": [
                "Endocrinological Research Center of the Federal Agency for High-Technology Medical Assistance, 11 ul. Dmitriya Ul\u2019yanova, 117036, Moscow, Russian Federation"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Rzheznikov", 
            "givenName": "V. M.", 
            "id": "sg:person.01311323323.92", 
            "sameAs": [
              "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01311323323.92"
            ], 
            "type": "Person"
          }, 
          {
            "affiliation": {
              "alternateName": "Endocrinological Research Center of the Federal Agency for High-Technology Medical Assistance, 11 ul. Dmitriya Ul\u2019yanova, 117036, Moscow, Russian Federation", 
              "id": "http://www.grid.ac/institutes/None", 
              "name": [
                "Endocrinological Research Center of the Federal Agency for High-Technology Medical Assistance, 11 ul. Dmitriya Ul\u2019yanova, 117036, Moscow, Russian Federation"
              ], 
              "type": "Organization"
            }, 
            "familyName": "Golubovskaya", 
            "givenName": "L. E.", 
            "id": "sg:person.010013357101.22", 
            "sameAs": [
              "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010013357101.22"
            ], 
            "type": "Person"
          }
        ], 
        "citation": [
          {
            "id": "sg:pub.10.1071/ap99046", 
            "sameAs": [
              "https://app.dimensions.ai/details/publication/pub.1021830414", 
              "https://doi.org/10.1071/ap99046"
            ], 
            "type": "CreativeWork"
          }
        ], 
        "datePublished": "2008-01", 
        "datePublishedReg": "2008-01-01", 
        "description": "ESI MS studies showed that the major collision-activated fragmentation pathway of the [M + Na]+ ions of the title estranes involves elimination of NaCl and HCl molecules. Fragmentation of the [M + H]+ ions involves the functional groups, which provides information on their structures. The fragmentation of the [M + Na]+ and [M + H]+ ions was estimated by quantum-chemical calculations.", 
        "genre": "article", 
        "id": "sg:pub.10.1007/s11172-008-0014-y", 
        "inLanguage": "en", 
        "isAccessibleForFree": false, 
        "isPartOf": [
          {
            "id": "sg:journal.1022309", 
            "issn": [
              "1063-5211", 
              "1026-3500"
            ], 
            "name": "Russian Chemical Bulletin", 
            "publisher": "Springer Nature", 
            "type": "Periodical"
          }, 
          {
            "issueNumber": "1", 
            "type": "PublicationIssue"
          }, 
          {
            "type": "PublicationVolume", 
            "volumeNumber": "57"
          }
        ], 
        "keywords": [
          "quantum-chemical calculations", 
          "ESI MS studies", 
          "ESI mass spectrometry", 
          "fragmentation pathways", 
          "functional groups", 
          "HCl molecules", 
          "mass spectrometry", 
          "elimination of NaCl", 
          "MS studies", 
          "ions", 
          "spectrometry", 
          "molecules", 
          "estrane", 
          "calculations", 
          "fragmentation", 
          "structure", 
          "NaCl", 
          "elimination", 
          "group", 
          "study", 
          "pathway", 
          "steroids", 
          "information", 
          "major collision-activated fragmentation pathway", 
          "collision-activated fragmentation pathway", 
          "title estranes", 
          "Tandem ESI mass spectrometry", 
          "estrane steroids"
        ], 
        "name": "Tandem ESI mass spectrometry of 11\u03b1- and 11\u03b2-{4-[N,N-bis(2-chloroethyl)amino]phenyl}acetates of the estrane steroids", 
        "pagination": "95-98", 
        "productId": [
          {
            "name": "dimensions_id", 
            "type": "PropertyValue", 
            "value": [
              "pub.1013829165"
            ]
          }, 
          {
            "name": "doi", 
            "type": "PropertyValue", 
            "value": [
              "10.1007/s11172-008-0014-y"
            ]
          }
        ], 
        "sameAs": [
          "https://doi.org/10.1007/s11172-008-0014-y", 
          "https://app.dimensions.ai/details/publication/pub.1013829165"
        ], 
        "sdDataset": "articles", 
        "sdDatePublished": "2021-11-01T18:12", 
        "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
        "sdPublisher": {
          "name": "Springer Nature - SN SciGraph project", 
          "type": "Organization"
        }, 
        "sdSource": "s3://com-springernature-scigraph/baseset/20211101/entities/gbq_results/article/article_469.jsonl", 
        "type": "ScholarlyArticle", 
        "url": "https://doi.org/10.1007/s11172-008-0014-y"
      }
    ]
     

    Download the RDF metadata as:  json-ld nt turtle xml License info

    HOW TO GET THIS DATA PROGRAMMATICALLY:

    JSON-LD is a popular format for linked data which is fully compatible with JSON.

    curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/s11172-008-0014-y'

    N-Triples is a line-based linked data format ideal for batch operations.

    curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/s11172-008-0014-y'

    Turtle is a human-readable linked data format.

    curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/s11172-008-0014-y'

    RDF/XML is a standard XML format for linked data.

    curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/s11172-008-0014-y'


     

    This table displays all metadata directly associated to this object as RDF triples.

    131 TRIPLES      22 PREDICATES      54 URIs      46 LITERALS      6 BLANK NODES

    Subject Predicate Object
    1 sg:pub.10.1007/s11172-008-0014-y schema:about anzsrc-for:03
    2 schema:author N3c5f4d15f121433f8dfc1514d47223a9
    3 schema:citation sg:pub.10.1071/ap99046
    4 schema:datePublished 2008-01
    5 schema:datePublishedReg 2008-01-01
    6 schema:description ESI MS studies showed that the major collision-activated fragmentation pathway of the [M + Na]+ ions of the title estranes involves elimination of NaCl and HCl molecules. Fragmentation of the [M + H]+ ions involves the functional groups, which provides information on their structures. The fragmentation of the [M + Na]+ and [M + H]+ ions was estimated by quantum-chemical calculations.
    7 schema:genre article
    8 schema:inLanguage en
    9 schema:isAccessibleForFree false
    10 schema:isPartOf N8160e9c4c48545058231145b1d8cac7c
    11 Na8d0754154574084901a71be7e56d202
    12 sg:journal.1022309
    13 schema:keywords ESI MS studies
    14 ESI mass spectrometry
    15 HCl molecules
    16 MS studies
    17 NaCl
    18 Tandem ESI mass spectrometry
    19 calculations
    20 collision-activated fragmentation pathway
    21 elimination
    22 elimination of NaCl
    23 estrane
    24 estrane steroids
    25 fragmentation
    26 fragmentation pathways
    27 functional groups
    28 group
    29 information
    30 ions
    31 major collision-activated fragmentation pathway
    32 mass spectrometry
    33 molecules
    34 pathway
    35 quantum-chemical calculations
    36 spectrometry
    37 steroids
    38 structure
    39 study
    40 title estranes
    41 schema:name Tandem ESI mass spectrometry of 11α- and 11β-{4-[N,N-bis(2-chloroethyl)amino]phenyl}acetates of the estrane steroids
    42 schema:pagination 95-98
    43 schema:productId N07fcbfc103674ac194d3eced2608bd54
    44 Ne5ff2734c69f49c882d805221c90f199
    45 schema:sameAs https://app.dimensions.ai/details/publication/pub.1013829165
    46 https://doi.org/10.1007/s11172-008-0014-y
    47 schema:sdDatePublished 2021-11-01T18:12
    48 schema:sdLicense https://scigraph.springernature.com/explorer/license/
    49 schema:sdPublisher Ndd934e6efc27415e8b0630ae280f2e7d
    50 schema:url https://doi.org/10.1007/s11172-008-0014-y
    51 sgo:license sg:explorer/license/
    52 sgo:sdDataset articles
    53 rdf:type schema:ScholarlyArticle
    54 N0216e1d138de43bc9a800c148f68460e rdf:first sg:person.01311323323.92
    55 rdf:rest N80afcc494c884f73ae6750a45cb1e781
    56 N07fcbfc103674ac194d3eced2608bd54 schema:name doi
    57 schema:value 10.1007/s11172-008-0014-y
    58 rdf:type schema:PropertyValue
    59 N3c5f4d15f121433f8dfc1514d47223a9 rdf:first sg:person.01270127225.37
    60 rdf:rest Nbba5935c024b4d268e652c5757c61569
    61 N80afcc494c884f73ae6750a45cb1e781 rdf:first sg:person.010013357101.22
    62 rdf:rest rdf:nil
    63 N8160e9c4c48545058231145b1d8cac7c schema:issueNumber 1
    64 rdf:type schema:PublicationIssue
    65 Na8d0754154574084901a71be7e56d202 schema:volumeNumber 57
    66 rdf:type schema:PublicationVolume
    67 Nbba5935c024b4d268e652c5757c61569 rdf:first sg:person.01074552527.75
    68 rdf:rest Ndd3f6401d2ee42e1afa7a6736f076dbd
    69 Nd47a6061507040a4af4ac703ea022c06 rdf:first sg:person.0576251203.31
    70 rdf:rest N0216e1d138de43bc9a800c148f68460e
    71 Ndd3f6401d2ee42e1afa7a6736f076dbd rdf:first sg:person.014663256724.68
    72 rdf:rest Ne3cf40d792584dd78a2dff7f531f75ec
    73 Ndd934e6efc27415e8b0630ae280f2e7d schema:name Springer Nature - SN SciGraph project
    74 rdf:type schema:Organization
    75 Ne3cf40d792584dd78a2dff7f531f75ec rdf:first sg:person.016374705303.78
    76 rdf:rest Nd47a6061507040a4af4ac703ea022c06
    77 Ne5ff2734c69f49c882d805221c90f199 schema:name dimensions_id
    78 schema:value pub.1013829165
    79 rdf:type schema:PropertyValue
    80 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
    81 schema:name Chemical Sciences
    82 rdf:type schema:DefinedTerm
    83 sg:journal.1022309 schema:issn 1026-3500
    84 1063-5211
    85 schema:name Russian Chemical Bulletin
    86 schema:publisher Springer Nature
    87 rdf:type schema:Periodical
    88 sg:person.010013357101.22 schema:affiliation grid-institutes:None
    89 schema:familyName Golubovskaya
    90 schema:givenName L. E.
    91 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010013357101.22
    92 rdf:type schema:Person
    93 sg:person.01074552527.75 schema:affiliation grid-institutes:grid.439283.7
    94 schema:familyName Chizhov
    95 schema:givenName A. O.
    96 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01074552527.75
    97 rdf:type schema:Person
    98 sg:person.01270127225.37 schema:affiliation grid-institutes:grid.439283.7
    99 schema:familyName Kadentsev
    100 schema:givenName V. I.
    101 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01270127225.37
    102 rdf:type schema:Person
    103 sg:person.01311323323.92 schema:affiliation grid-institutes:None
    104 schema:familyName Rzheznikov
    105 schema:givenName V. M.
    106 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01311323323.92
    107 rdf:type schema:Person
    108 sg:person.014663256724.68 schema:affiliation grid-institutes:grid.439283.7
    109 schema:familyName Chizhov
    110 schema:givenName O. S.
    111 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014663256724.68
    112 rdf:type schema:Person
    113 sg:person.016374705303.78 schema:affiliation grid-institutes:grid.439283.7
    114 schema:familyName Kolotyrkina
    115 schema:givenName N. G.
    116 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016374705303.78
    117 rdf:type schema:Person
    118 sg:person.0576251203.31 schema:affiliation grid-institutes:grid.439283.7
    119 schema:familyName Kutin
    120 schema:givenName A. A.
    121 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0576251203.31
    122 rdf:type schema:Person
    123 sg:pub.10.1071/ap99046 schema:sameAs https://app.dimensions.ai/details/publication/pub.1021830414
    124 https://doi.org/10.1071/ap99046
    125 rdf:type schema:CreativeWork
    126 grid-institutes:None schema:alternateName Endocrinological Research Center of the Federal Agency for High-Technology Medical Assistance, 11 ul. Dmitriya Ul’yanova, 117036, Moscow, Russian Federation
    127 schema:name Endocrinological Research Center of the Federal Agency for High-Technology Medical Assistance, 11 ul. Dmitriya Ul’yanova, 117036, Moscow, Russian Federation
    128 rdf:type schema:Organization
    129 grid-institutes:grid.439283.7 schema:alternateName N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 119991, Moscow, Russian Federation
    130 schema:name N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 119991, Moscow, Russian Federation
    131 rdf:type schema:Organization
     




    Preview window. Press ESC to close (or click here)


    ...