The Mannich reaction in the synthesis of N,S-containing heterocycles 8. Aminomethylation of 3,5-dicyano-6-oxo-1,4,5,6-tetrahydropyridine-2-thiolates as a method for the synthesis of ... View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2007-12

AUTHORS

V. V. Dotsenko, S. G. Krivokolysko, V. P. Litvinov

ABSTRACT

Aminomethylation of 3,5-dicyano-6-oxo-1,4,5,6-tetrahydropyridine-2-thiolates upon treatment with primary amines and excess formaldehyde leads to 3,7-diazabicyclo[3.3.1]nonane derivatives. N-Methylmorpholinium 4-(2-chlorophenyl)-3,5-dicyano-6-oxo-1,4,5,6-tetrahydropyridine-2-thiolate was obtained by the reaction of (E)-3-(2-chlorophenyl)-2-cyanoprop-2-enethioamide with 1-cyanoacetyl-3,5-dimethylpyrazole and N-methylmorpholine in acetone in quantitative yield.

PAGES

2482-2486

References to SciGraph publications

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s11172-007-0395-3

DOI

http://dx.doi.org/10.1007/s11172-007-0395-3

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1021804602


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/1103", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Clinical Sciences", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/11", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Medical and Health Sciences", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "name": [
            "State Enterprise \u201cLuganskstandartmetrology\u201d, 50 ul. Timiryazeva, 91021, Lugansk, Ukraine", 
            "V. Dal\u2019 East-Ukrainian National University, 20a kv. Molodyozhnyi, 91034, Lugansk, Ukraine"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Dotsenko", 
        "givenName": "V. V.", 
        "id": "sg:person.016426051663.40", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016426051663.40"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "name": [
            "V. Dal\u2019 East-Ukrainian National University, 20a kv. Molodyozhnyi, 91034, Lugansk, Ukraine"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Krivokolysko", 
        "givenName": "S. G.", 
        "id": "sg:person.0661513636.94", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0661513636.94"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Russian Academy of Sciences", 
          "id": "https://www.grid.ac/institutes/grid.4886.2", 
          "name": [
            "N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 119991, Moscow, Russian Federation"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Litvinov", 
        "givenName": "V. P.", 
        "id": "sg:person.016420406747.90", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016420406747.90"
        ], 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "https://doi.org/10.1080/00397910500501243", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1004713043"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/jlac.19596260112", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1025756553"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/cber.19570901218", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1034322335"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1002/jlac.19596260111", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1038855532"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1081/scc-100105335", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1040242051"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "sg:pub.10.1007/s007830050044", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1048842862", 
          "https://doi.org/10.1007/s007830050044"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1080/10426509308038105", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1049782331"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/jf00039a043", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055893388"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1135/cccc19950999", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1062756257"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1135/cccc19960921", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1062756456"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://app.dimensions.ai/details/publication/pub.1079574434", 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "2007-12", 
    "datePublishedReg": "2007-12-01", 
    "description": "Aminomethylation of 3,5-dicyano-6-oxo-1,4,5,6-tetrahydropyridine-2-thiolates upon treatment with primary amines and excess formaldehyde leads to 3,7-diazabicyclo[3.3.1]nonane derivatives. N-Methylmorpholinium 4-(2-chlorophenyl)-3,5-dicyano-6-oxo-1,4,5,6-tetrahydropyridine-2-thiolate was obtained by the reaction of (E)-3-(2-chlorophenyl)-2-cyanoprop-2-enethioamide with 1-cyanoacetyl-3,5-dimethylpyrazole and N-methylmorpholine in acetone in quantitative yield.", 
    "genre": "research_article", 
    "id": "sg:pub.10.1007/s11172-007-0395-3", 
    "inLanguage": [
      "en"
    ], 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1022309", 
        "issn": [
          "1066-5285", 
          "1573-9171"
        ], 
        "name": "Russian Chemical Bulletin", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "12", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "56"
      }
    ], 
    "name": "The Mannich reaction in the synthesis of N,S-containing heterocycles 8. Aminomethylation of 3,5-dicyano-6-oxo-1,4,5,6-tetrahydropyridine-2-thiolates as a method for the synthesis of new functionally substituted 3,7-diazabicyclo[3.3.1]nonane derivatives", 
    "pagination": "2482-2486", 
    "productId": [
      {
        "name": "readcube_id", 
        "type": "PropertyValue", 
        "value": [
          "67e28283ab8a6b77b7ee2f2af93608b708d5a7c7cae798d532e8a081135d04d8"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1007/s11172-007-0395-3"
        ]
      }, 
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1021804602"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1007/s11172-007-0395-3", 
      "https://app.dimensions.ai/details/publication/pub.1021804602"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2019-04-10T15:05", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000001_0000000264/records_8663_00000531.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "http://link.springer.com/10.1007%2Fs11172-007-0395-3"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/s11172-007-0395-3'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/s11172-007-0395-3'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/s11172-007-0395-3'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/s11172-007-0395-3'


 

This table displays all metadata directly associated to this object as RDF triples.

113 TRIPLES      21 PREDICATES      38 URIs      19 LITERALS      7 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1007/s11172-007-0395-3 schema:about anzsrc-for:11
2 anzsrc-for:1103
3 schema:author Naee4cc14a9784ed9abca48d489c7e5dc
4 schema:citation sg:pub.10.1007/s007830050044
5 https://app.dimensions.ai/details/publication/pub.1079574434
6 https://doi.org/10.1002/cber.19570901218
7 https://doi.org/10.1002/jlac.19596260111
8 https://doi.org/10.1002/jlac.19596260112
9 https://doi.org/10.1021/jf00039a043
10 https://doi.org/10.1080/00397910500501243
11 https://doi.org/10.1080/10426509308038105
12 https://doi.org/10.1081/scc-100105335
13 https://doi.org/10.1135/cccc19950999
14 https://doi.org/10.1135/cccc19960921
15 schema:datePublished 2007-12
16 schema:datePublishedReg 2007-12-01
17 schema:description Aminomethylation of 3,5-dicyano-6-oxo-1,4,5,6-tetrahydropyridine-2-thiolates upon treatment with primary amines and excess formaldehyde leads to 3,7-diazabicyclo[3.3.1]nonane derivatives. N-Methylmorpholinium 4-(2-chlorophenyl)-3,5-dicyano-6-oxo-1,4,5,6-tetrahydropyridine-2-thiolate was obtained by the reaction of (E)-3-(2-chlorophenyl)-2-cyanoprop-2-enethioamide with 1-cyanoacetyl-3,5-dimethylpyrazole and N-methylmorpholine in acetone in quantitative yield.
18 schema:genre research_article
19 schema:inLanguage en
20 schema:isAccessibleForFree false
21 schema:isPartOf N515cdb7262fd4dc3aaae7f313fa9f050
22 Nd12c5dece8364ef09ea891f9f6695254
23 sg:journal.1022309
24 schema:name The Mannich reaction in the synthesis of N,S-containing heterocycles 8. Aminomethylation of 3,5-dicyano-6-oxo-1,4,5,6-tetrahydropyridine-2-thiolates as a method for the synthesis of new functionally substituted 3,7-diazabicyclo[3.3.1]nonane derivatives
25 schema:pagination 2482-2486
26 schema:productId N29d2404463a648dcbcbf5c0c384cd5ab
27 N44e01d94e5ef448995d0106b07da0e82
28 Nc49df8037d25410ca9c50d384acc775e
29 schema:sameAs https://app.dimensions.ai/details/publication/pub.1021804602
30 https://doi.org/10.1007/s11172-007-0395-3
31 schema:sdDatePublished 2019-04-10T15:05
32 schema:sdLicense https://scigraph.springernature.com/explorer/license/
33 schema:sdPublisher N6f79068c01734b32b0b5e0bddd41427b
34 schema:url http://link.springer.com/10.1007%2Fs11172-007-0395-3
35 sgo:license sg:explorer/license/
36 sgo:sdDataset articles
37 rdf:type schema:ScholarlyArticle
38 N29d2404463a648dcbcbf5c0c384cd5ab schema:name doi
39 schema:value 10.1007/s11172-007-0395-3
40 rdf:type schema:PropertyValue
41 N3bc480fc6a3f43cabeaf4f88f95eda04 schema:name V. Dal’ East-Ukrainian National University, 20a kv. Molodyozhnyi, 91034, Lugansk, Ukraine
42 rdf:type schema:Organization
43 N44e01d94e5ef448995d0106b07da0e82 schema:name dimensions_id
44 schema:value pub.1021804602
45 rdf:type schema:PropertyValue
46 N515cdb7262fd4dc3aaae7f313fa9f050 schema:issueNumber 12
47 rdf:type schema:PublicationIssue
48 N6f79068c01734b32b0b5e0bddd41427b schema:name Springer Nature - SN SciGraph project
49 rdf:type schema:Organization
50 N6fa28344720d49f0b1e8394ce2e99b15 rdf:first sg:person.016420406747.90
51 rdf:rest rdf:nil
52 Na1f1478ac11b410c820d0c29439fa4ad rdf:first sg:person.0661513636.94
53 rdf:rest N6fa28344720d49f0b1e8394ce2e99b15
54 Naee4cc14a9784ed9abca48d489c7e5dc rdf:first sg:person.016426051663.40
55 rdf:rest Na1f1478ac11b410c820d0c29439fa4ad
56 Nc49df8037d25410ca9c50d384acc775e schema:name readcube_id
57 schema:value 67e28283ab8a6b77b7ee2f2af93608b708d5a7c7cae798d532e8a081135d04d8
58 rdf:type schema:PropertyValue
59 Nd12c5dece8364ef09ea891f9f6695254 schema:volumeNumber 56
60 rdf:type schema:PublicationVolume
61 Nfb36e71e2b8e4778953413223a8ba454 schema:name State Enterprise “Luganskstandartmetrology”, 50 ul. Timiryazeva, 91021, Lugansk, Ukraine
62 V. Dal’ East-Ukrainian National University, 20a kv. Molodyozhnyi, 91034, Lugansk, Ukraine
63 rdf:type schema:Organization
64 anzsrc-for:11 schema:inDefinedTermSet anzsrc-for:
65 schema:name Medical and Health Sciences
66 rdf:type schema:DefinedTerm
67 anzsrc-for:1103 schema:inDefinedTermSet anzsrc-for:
68 schema:name Clinical Sciences
69 rdf:type schema:DefinedTerm
70 sg:journal.1022309 schema:issn 1066-5285
71 1573-9171
72 schema:name Russian Chemical Bulletin
73 rdf:type schema:Periodical
74 sg:person.016420406747.90 schema:affiliation https://www.grid.ac/institutes/grid.4886.2
75 schema:familyName Litvinov
76 schema:givenName V. P.
77 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016420406747.90
78 rdf:type schema:Person
79 sg:person.016426051663.40 schema:affiliation Nfb36e71e2b8e4778953413223a8ba454
80 schema:familyName Dotsenko
81 schema:givenName V. V.
82 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016426051663.40
83 rdf:type schema:Person
84 sg:person.0661513636.94 schema:affiliation N3bc480fc6a3f43cabeaf4f88f95eda04
85 schema:familyName Krivokolysko
86 schema:givenName S. G.
87 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0661513636.94
88 rdf:type schema:Person
89 sg:pub.10.1007/s007830050044 schema:sameAs https://app.dimensions.ai/details/publication/pub.1048842862
90 https://doi.org/10.1007/s007830050044
91 rdf:type schema:CreativeWork
92 https://app.dimensions.ai/details/publication/pub.1079574434 schema:CreativeWork
93 https://doi.org/10.1002/cber.19570901218 schema:sameAs https://app.dimensions.ai/details/publication/pub.1034322335
94 rdf:type schema:CreativeWork
95 https://doi.org/10.1002/jlac.19596260111 schema:sameAs https://app.dimensions.ai/details/publication/pub.1038855532
96 rdf:type schema:CreativeWork
97 https://doi.org/10.1002/jlac.19596260112 schema:sameAs https://app.dimensions.ai/details/publication/pub.1025756553
98 rdf:type schema:CreativeWork
99 https://doi.org/10.1021/jf00039a043 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055893388
100 rdf:type schema:CreativeWork
101 https://doi.org/10.1080/00397910500501243 schema:sameAs https://app.dimensions.ai/details/publication/pub.1004713043
102 rdf:type schema:CreativeWork
103 https://doi.org/10.1080/10426509308038105 schema:sameAs https://app.dimensions.ai/details/publication/pub.1049782331
104 rdf:type schema:CreativeWork
105 https://doi.org/10.1081/scc-100105335 schema:sameAs https://app.dimensions.ai/details/publication/pub.1040242051
106 rdf:type schema:CreativeWork
107 https://doi.org/10.1135/cccc19950999 schema:sameAs https://app.dimensions.ai/details/publication/pub.1062756257
108 rdf:type schema:CreativeWork
109 https://doi.org/10.1135/cccc19960921 schema:sameAs https://app.dimensions.ai/details/publication/pub.1062756456
110 rdf:type schema:CreativeWork
111 https://www.grid.ac/institutes/grid.4886.2 schema:alternateName Russian Academy of Sciences
112 schema:name N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 119991, Moscow, Russian Federation
113 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...