Three-coordinate silver(I) ions and tridentate ligands as complementary tectons in coordination polymer construction: a new example of semiregular 4.82 nets View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2007-09

AUTHORS

S. Z. Vatsadze, I. A. Vatsadze, M. A. Manaenkova, N. V. Zyk, A. V. Churakov, M. Yu. Antipin, J. A. K. Howard, H. Lang

ABSTRACT

The structures of the reaction products of silver nitrate with monoheterotopic tridentate ligands derived from N-alkyl-3,5-bis(3-pyridylmethylene)piperidin-4-one were studied. The aliphatic nitrogen atoms are involved in the coordination, all three nitrogen atoms of the ligands being coordinated to three different silver atoms. In turn, each silver atom is coordinated by two nitrogen atoms of the pyridine ring and one nitrogen atom of the piperidine ring of different ligands. The crystal structures of the complexes are different. Infinite ladder-like chains consisting of 16-membered metallamacrocycles as monomeric building blocks are present in the structure of the N-methyl derivative, whereas two-dimensional 4.82 nets consisting of 16-and 40-membered metallamacrocycles are observed in the crystal structure of the N-benzyl analog. More... »

PAGES

1775-1781

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s11172-007-0276-9

DOI

http://dx.doi.org/10.1007/s11172-007-0276-9

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1027340371


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138 https://www.grid.ac/institutes/grid.4886.2 schema:alternateName Russian Academy of Sciences
139 schema:name A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991, Moscow, Russian Federation
140 N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 119991, Moscow, Russian Federation
141 N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, 31 Leninsky prosp., 119991, Moscow, Russian Federation
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143 https://www.grid.ac/institutes/grid.6810.f schema:alternateName Chemnitz University of Technology
144 schema:name Department of Inorganic Chemistry, Institute of Chemistry, Chemnitz University of Technology, D-09111, Chemnitz, Germany
145 rdf:type schema:Organization
146 https://www.grid.ac/institutes/grid.8250.f schema:alternateName Durham University
147 schema:name Department of Chemistry, University of Durham, South Road, DH1 3LE, Durham, UK
148 rdf:type schema:Organization
 




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