Trifluoromethylation and pentafluorophenylation of enamines View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2007-08

AUTHORS

A. D. Dilman, V. V. Gorokhov, P. A. Belyakov, M. I. Struchkova, V. A. Tartakovsky

ABSTRACT

A reaction of enamines with Me3SiCF3 and Me3SiC6F5 in the presence of carboxylic acids leading to α-CF3-and α-C6F5-substituted amines has been studied. 3-Cyanobenzoic acid was found to be the optimal promoter of these reactions.

PAGES

1522-1525

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s11172-007-0235-5

DOI

http://dx.doi.org/10.1007/s11172-007-0235-5

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1040668836


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 119991, Moscow, Russian Federation", 
          "id": "http://www.grid.ac/institutes/grid.439283.7", 
          "name": [
            "N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 119991, Moscow, Russian Federation"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Dilman", 
        "givenName": "A. D.", 
        "id": "sg:person.014204702022.94", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014204702022.94"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 119991, Moscow, Russian Federation", 
          "id": "http://www.grid.ac/institutes/grid.439283.7", 
          "name": [
            "N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 119991, Moscow, Russian Federation"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Gorokhov", 
        "givenName": "V. V.", 
        "id": "sg:person.01343260464.47", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01343260464.47"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 119991, Moscow, Russian Federation", 
          "id": "http://www.grid.ac/institutes/grid.439283.7", 
          "name": [
            "N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 119991, Moscow, Russian Federation"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Belyakov", 
        "givenName": "P. A.", 
        "id": "sg:person.01002352131.93", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01002352131.93"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 119991, Moscow, Russian Federation", 
          "id": "http://www.grid.ac/institutes/grid.439283.7", 
          "name": [
            "N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 119991, Moscow, Russian Federation"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Struchkova", 
        "givenName": "M. I.", 
        "id": "sg:person.01342454222.91", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01342454222.91"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 119991, Moscow, Russian Federation", 
          "id": "http://www.grid.ac/institutes/grid.439283.7", 
          "name": [
            "N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 119991, Moscow, Russian Federation"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Tartakovsky", 
        "givenName": "V. A.", 
        "id": "sg:person.010370656303.84", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010370656303.84"
        ], 
        "type": "Person"
      }
    ], 
    "datePublished": "2007-08", 
    "datePublishedReg": "2007-08-01", 
    "description": "A reaction of enamines with Me3SiCF3 and Me3SiC6F5 in the presence of carboxylic acids leading to \u03b1-CF3-and \u03b1-C6F5-substituted amines has been studied. 3-Cyanobenzoic acid was found to be the optimal promoter of these reactions.", 
    "genre": "article", 
    "id": "sg:pub.10.1007/s11172-007-0235-5", 
    "inLanguage": "en", 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1022309", 
        "issn": [
          "1026-3500", 
          "1066-5285"
        ], 
        "name": "Russian Chemical Bulletin", 
        "publisher": "Springer Nature", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "8", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "56"
      }
    ], 
    "keywords": [
      "optimal promoter", 
      "acid", 
      "presence", 
      "promoter", 
      "reaction", 
      "amines", 
      "carboxylic acids", 
      "enamines", 
      "CF3", 
      "reaction of enamines", 
      "trifluoromethylation", 
      "Me3SiCF3"
    ], 
    "name": "Trifluoromethylation and pentafluorophenylation of enamines", 
    "pagination": "1522-1525", 
    "productId": [
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1040668836"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1007/s11172-007-0235-5"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1007/s11172-007-0235-5", 
      "https://app.dimensions.ai/details/publication/pub.1040668836"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2022-05-20T07:24", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-springernature-scigraph/baseset/20220519/entities/gbq_results/article/article_437.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "https://doi.org/10.1007/s11172-007-0235-5"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/s11172-007-0235-5'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/s11172-007-0235-5'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/s11172-007-0235-5'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/s11172-007-0235-5'


 

This table displays all metadata directly associated to this object as RDF triples.

94 TRIPLES      21 PREDICATES      37 URIs      30 LITERALS      6 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1007/s11172-007-0235-5 schema:about anzsrc-for:03
2 schema:author N82693eb365bd40bbb984796203836b63
3 schema:datePublished 2007-08
4 schema:datePublishedReg 2007-08-01
5 schema:description A reaction of enamines with Me3SiCF3 and Me3SiC6F5 in the presence of carboxylic acids leading to α-CF3-and α-C6F5-substituted amines has been studied. 3-Cyanobenzoic acid was found to be the optimal promoter of these reactions.
6 schema:genre article
7 schema:inLanguage en
8 schema:isAccessibleForFree false
9 schema:isPartOf N188ebf3e0ac8475cb10e6617e9105aa4
10 Nd1b44e112e834f4c9139c65df62d9dc0
11 sg:journal.1022309
12 schema:keywords CF3
13 Me3SiCF3
14 acid
15 amines
16 carboxylic acids
17 enamines
18 optimal promoter
19 presence
20 promoter
21 reaction
22 reaction of enamines
23 trifluoromethylation
24 schema:name Trifluoromethylation and pentafluorophenylation of enamines
25 schema:pagination 1522-1525
26 schema:productId N79bac61ab2864112ac66a6b631f15b38
27 Ndaba5c9d56474860b0e0eb1df989df8d
28 schema:sameAs https://app.dimensions.ai/details/publication/pub.1040668836
29 https://doi.org/10.1007/s11172-007-0235-5
30 schema:sdDatePublished 2022-05-20T07:24
31 schema:sdLicense https://scigraph.springernature.com/explorer/license/
32 schema:sdPublisher N8061bd29b92e45a9b1e149ccdf079cad
33 schema:url https://doi.org/10.1007/s11172-007-0235-5
34 sgo:license sg:explorer/license/
35 sgo:sdDataset articles
36 rdf:type schema:ScholarlyArticle
37 N188ebf3e0ac8475cb10e6617e9105aa4 schema:volumeNumber 56
38 rdf:type schema:PublicationVolume
39 N39b9979fee7b4c92ae5617e5f0b06b27 rdf:first sg:person.01002352131.93
40 rdf:rest Nc5e37b31a5b447c2a747a4f11de0f9ea
41 N79bac61ab2864112ac66a6b631f15b38 schema:name doi
42 schema:value 10.1007/s11172-007-0235-5
43 rdf:type schema:PropertyValue
44 N8061bd29b92e45a9b1e149ccdf079cad schema:name Springer Nature - SN SciGraph project
45 rdf:type schema:Organization
46 N82693eb365bd40bbb984796203836b63 rdf:first sg:person.014204702022.94
47 rdf:rest N8516bf305cea4e99a458e9e024d4f098
48 N8516bf305cea4e99a458e9e024d4f098 rdf:first sg:person.01343260464.47
49 rdf:rest N39b9979fee7b4c92ae5617e5f0b06b27
50 Nc5e37b31a5b447c2a747a4f11de0f9ea rdf:first sg:person.01342454222.91
51 rdf:rest Nf5d41cb923074016be8280113110bad5
52 Nd1b44e112e834f4c9139c65df62d9dc0 schema:issueNumber 8
53 rdf:type schema:PublicationIssue
54 Ndaba5c9d56474860b0e0eb1df989df8d schema:name dimensions_id
55 schema:value pub.1040668836
56 rdf:type schema:PropertyValue
57 Nf5d41cb923074016be8280113110bad5 rdf:first sg:person.010370656303.84
58 rdf:rest rdf:nil
59 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
60 schema:name Chemical Sciences
61 rdf:type schema:DefinedTerm
62 sg:journal.1022309 schema:issn 1026-3500
63 1066-5285
64 schema:name Russian Chemical Bulletin
65 schema:publisher Springer Nature
66 rdf:type schema:Periodical
67 sg:person.01002352131.93 schema:affiliation grid-institutes:grid.439283.7
68 schema:familyName Belyakov
69 schema:givenName P. A.
70 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01002352131.93
71 rdf:type schema:Person
72 sg:person.010370656303.84 schema:affiliation grid-institutes:grid.439283.7
73 schema:familyName Tartakovsky
74 schema:givenName V. A.
75 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010370656303.84
76 rdf:type schema:Person
77 sg:person.01342454222.91 schema:affiliation grid-institutes:grid.439283.7
78 schema:familyName Struchkova
79 schema:givenName M. I.
80 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01342454222.91
81 rdf:type schema:Person
82 sg:person.01343260464.47 schema:affiliation grid-institutes:grid.439283.7
83 schema:familyName Gorokhov
84 schema:givenName V. V.
85 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01343260464.47
86 rdf:type schema:Person
87 sg:person.014204702022.94 schema:affiliation grid-institutes:grid.439283.7
88 schema:familyName Dilman
89 schema:givenName A. D.
90 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014204702022.94
91 rdf:type schema:Person
92 grid-institutes:grid.439283.7 schema:alternateName N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 119991, Moscow, Russian Federation
93 schema:name N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 119991, Moscow, Russian Federation
94 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...