Trifluoromethylation and pentafluorophenylation of enamines View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2007-08

AUTHORS

A. D. Dilman, V. V. Gorokhov, P. A. Belyakov, M. I. Struchkova, V. A. Tartakovsky

ABSTRACT

A reaction of enamines with Me3SiCF3 and Me3SiC6F5 in the presence of carboxylic acids leading to α-CF3-and α-C6F5-substituted amines has been studied. 3-Cyanobenzoic acid was found to be the optimal promoter of these reactions.

PAGES

1522-1525

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s11172-007-0235-5

DOI

http://dx.doi.org/10.1007/s11172-007-0235-5

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1040668836


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 119991, Moscow, Russian Federation", 
          "id": "http://www.grid.ac/institutes/grid.439283.7", 
          "name": [
            "N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 119991, Moscow, Russian Federation"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Dilman", 
        "givenName": "A. D.", 
        "id": "sg:person.014204702022.94", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014204702022.94"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 119991, Moscow, Russian Federation", 
          "id": "http://www.grid.ac/institutes/grid.439283.7", 
          "name": [
            "N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 119991, Moscow, Russian Federation"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Gorokhov", 
        "givenName": "V. V.", 
        "id": "sg:person.01343260464.47", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01343260464.47"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 119991, Moscow, Russian Federation", 
          "id": "http://www.grid.ac/institutes/grid.439283.7", 
          "name": [
            "N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 119991, Moscow, Russian Federation"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Belyakov", 
        "givenName": "P. A.", 
        "id": "sg:person.01002352131.93", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01002352131.93"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 119991, Moscow, Russian Federation", 
          "id": "http://www.grid.ac/institutes/grid.439283.7", 
          "name": [
            "N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 119991, Moscow, Russian Federation"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Struchkova", 
        "givenName": "M. I.", 
        "id": "sg:person.01342454222.91", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01342454222.91"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 119991, Moscow, Russian Federation", 
          "id": "http://www.grid.ac/institutes/grid.439283.7", 
          "name": [
            "N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 119991, Moscow, Russian Federation"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Tartakovsky", 
        "givenName": "V. A.", 
        "id": "sg:person.010370656303.84", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010370656303.84"
        ], 
        "type": "Person"
      }
    ], 
    "datePublished": "2007-08", 
    "datePublishedReg": "2007-08-01", 
    "description": "A reaction of enamines with Me3SiCF3 and Me3SiC6F5 in the presence of carboxylic acids leading to \u03b1-CF3-and \u03b1-C6F5-substituted amines has been studied. 3-Cyanobenzoic acid was found to be the optimal promoter of these reactions.", 
    "genre": "article", 
    "id": "sg:pub.10.1007/s11172-007-0235-5", 
    "inLanguage": "en", 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1022309", 
        "issn": [
          "1026-3500", 
          "1066-5285"
        ], 
        "name": "Russian Chemical Bulletin", 
        "publisher": "Springer Nature", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "8", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "56"
      }
    ], 
    "keywords": [
      "optimal promoter", 
      "acid", 
      "presence", 
      "promoter", 
      "reaction", 
      "amines", 
      "carboxylic acids", 
      "enamines", 
      "CF3", 
      "reaction of enamines", 
      "trifluoromethylation", 
      "Me3SiCF3"
    ], 
    "name": "Trifluoromethylation and pentafluorophenylation of enamines", 
    "pagination": "1522-1525", 
    "productId": [
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1040668836"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1007/s11172-007-0235-5"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1007/s11172-007-0235-5", 
      "https://app.dimensions.ai/details/publication/pub.1040668836"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2022-06-01T22:07", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-springernature-scigraph/baseset/20220601/entities/gbq_results/article/article_449.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "https://doi.org/10.1007/s11172-007-0235-5"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/s11172-007-0235-5'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/s11172-007-0235-5'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/s11172-007-0235-5'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/s11172-007-0235-5'


 

This table displays all metadata directly associated to this object as RDF triples.

94 TRIPLES      21 PREDICATES      37 URIs      30 LITERALS      6 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1007/s11172-007-0235-5 schema:about anzsrc-for:03
2 schema:author N17f2044f40f14daa81052c975a53e134
3 schema:datePublished 2007-08
4 schema:datePublishedReg 2007-08-01
5 schema:description A reaction of enamines with Me3SiCF3 and Me3SiC6F5 in the presence of carboxylic acids leading to α-CF3-and α-C6F5-substituted amines has been studied. 3-Cyanobenzoic acid was found to be the optimal promoter of these reactions.
6 schema:genre article
7 schema:inLanguage en
8 schema:isAccessibleForFree false
9 schema:isPartOf N360434c9484e422280e3a922635b5c1e
10 Ncc015d77ba164b1ca60b6198968c20e3
11 sg:journal.1022309
12 schema:keywords CF3
13 Me3SiCF3
14 acid
15 amines
16 carboxylic acids
17 enamines
18 optimal promoter
19 presence
20 promoter
21 reaction
22 reaction of enamines
23 trifluoromethylation
24 schema:name Trifluoromethylation and pentafluorophenylation of enamines
25 schema:pagination 1522-1525
26 schema:productId N4505476c57b14fddb8040dc5a053565b
27 N7a8ce352f09645819b80bcae4ed22ccd
28 schema:sameAs https://app.dimensions.ai/details/publication/pub.1040668836
29 https://doi.org/10.1007/s11172-007-0235-5
30 schema:sdDatePublished 2022-06-01T22:07
31 schema:sdLicense https://scigraph.springernature.com/explorer/license/
32 schema:sdPublisher N93ffb767dcfa44f6a252ad2d7499d250
33 schema:url https://doi.org/10.1007/s11172-007-0235-5
34 sgo:license sg:explorer/license/
35 sgo:sdDataset articles
36 rdf:type schema:ScholarlyArticle
37 N11af267264274118b269467e8b2936c7 rdf:first sg:person.01342454222.91
38 rdf:rest N28efea7db25b46d8821c9c8d7af4b141
39 N17f2044f40f14daa81052c975a53e134 rdf:first sg:person.014204702022.94
40 rdf:rest Ne48e264e06ac43ffa177eee0332456ec
41 N28efea7db25b46d8821c9c8d7af4b141 rdf:first sg:person.010370656303.84
42 rdf:rest rdf:nil
43 N360434c9484e422280e3a922635b5c1e schema:issueNumber 8
44 rdf:type schema:PublicationIssue
45 N4505476c57b14fddb8040dc5a053565b schema:name doi
46 schema:value 10.1007/s11172-007-0235-5
47 rdf:type schema:PropertyValue
48 N7a8ce352f09645819b80bcae4ed22ccd schema:name dimensions_id
49 schema:value pub.1040668836
50 rdf:type schema:PropertyValue
51 N93ffb767dcfa44f6a252ad2d7499d250 schema:name Springer Nature - SN SciGraph project
52 rdf:type schema:Organization
53 Ncc015d77ba164b1ca60b6198968c20e3 schema:volumeNumber 56
54 rdf:type schema:PublicationVolume
55 Ne48e264e06ac43ffa177eee0332456ec rdf:first sg:person.01343260464.47
56 rdf:rest Ned8f65e169d64ed3a7b825f18dc22315
57 Ned8f65e169d64ed3a7b825f18dc22315 rdf:first sg:person.01002352131.93
58 rdf:rest N11af267264274118b269467e8b2936c7
59 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
60 schema:name Chemical Sciences
61 rdf:type schema:DefinedTerm
62 sg:journal.1022309 schema:issn 1026-3500
63 1066-5285
64 schema:name Russian Chemical Bulletin
65 schema:publisher Springer Nature
66 rdf:type schema:Periodical
67 sg:person.01002352131.93 schema:affiliation grid-institutes:grid.439283.7
68 schema:familyName Belyakov
69 schema:givenName P. A.
70 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01002352131.93
71 rdf:type schema:Person
72 sg:person.010370656303.84 schema:affiliation grid-institutes:grid.439283.7
73 schema:familyName Tartakovsky
74 schema:givenName V. A.
75 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.010370656303.84
76 rdf:type schema:Person
77 sg:person.01342454222.91 schema:affiliation grid-institutes:grid.439283.7
78 schema:familyName Struchkova
79 schema:givenName M. I.
80 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01342454222.91
81 rdf:type schema:Person
82 sg:person.01343260464.47 schema:affiliation grid-institutes:grid.439283.7
83 schema:familyName Gorokhov
84 schema:givenName V. V.
85 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01343260464.47
86 rdf:type schema:Person
87 sg:person.014204702022.94 schema:affiliation grid-institutes:grid.439283.7
88 schema:familyName Dilman
89 schema:givenName A. D.
90 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014204702022.94
91 rdf:type schema:Person
92 grid-institutes:grid.439283.7 schema:alternateName N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 119991, Moscow, Russian Federation
93 schema:name N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky prosp., 119991, Moscow, Russian Federation
94 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...