Synthesis and structures of tris(pentafluorophenyl)silylamines View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2007-07

AUTHORS

V. V. Levin, A. D. Dilman, A. A. Korlyukov, P. A. Belyakov, M. I. Struchkova, M. Yu. Antipin, V. A. Tartakovsky

ABSTRACT

Tris(pentafluorophenyl)silylamines were synthesized by silylation of amines and imines with (C6F5)3SiCl or (C6F5)3SiOTf in the presence of triethylamine. The crystal structures of the (C6F5)3SiN(H)CH2Ph and (C6F5)3SiN(CH=CMe2)CH2Ph compounds were studied by X-ray diffraction. The crystal packings were analyzed by quantum chemical calculations in terms of the density functional theory (PBE exchange-correlation functional). More... »

PAGES

1394-1401

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s11172-007-0213-y

DOI

http://dx.doi.org/10.1007/s11172-007-0213-y

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1038608261


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