Hydrogenation on palladium-containing granulated catalysts 3. Synthesis of aminobenzimidazoles by catalytic hydrogenation of dinitroanilines View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2007-06

AUTHORS

V. V. Elkin, L. N. Tolkacheva, N. B. Chernysheva, I. B. Karmanova, L. D. Konyushkin, V. V. Semenov

ABSTRACT

Efficient hydrogenation of o-aminonitrobenzenes on palladium-containing granulated carbon catalysts in carboxylic acid solutions was accompanied by cyclization into aminobenzimidazoles. A simple hydrogenation reactor with a fixed gauze holding a reusable granulated catalyst was designed. Acylated and sulfonylated 4(7)-aminobenzimidazoles were obtained. In terms of electronic and geometrical parameters, they are close analogs of biologically active imidazo[1,5,4-e,f ][1,5]benzodiazepines. More... »

PAGES

1216-1226

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s11172-007-0184-z

DOI

http://dx.doi.org/10.1007/s11172-007-0184-z

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1016417175


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