New carborane-containing amino acids and their derivatives. Crystal structures of n-protected carboranylalaninates View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2007-04

AUTHORS

S. V. Timofeev, V. I. Bregadze, S. N. Osipov, I. D. Titanyuk, P. V. Petrovskii, Z. A. Starikova, I. V. Glukhov, I. P. Beletskaya

ABSTRACT

New alanine derivatives containing both the carboranyl and trifluoromethyl groups were synthesized by the reaction of organometallic derivatives of o-carborane with methyl trifluoropyruvate imines. When using the 1R-(−)-menthoxycarbonyl protecting group at the nitrogen atom, one of diastereomers was isolated and characterized. Trifluoromethyl-carboranylalanine methyl esters containing different protecting groups at the nitrogen atom were studied by X-ray diffraction. Both complete and partial deprotection of the amino and carboxy groups was performed. More... »

PAGES

791-797

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s11172-007-0118-9

DOI

http://dx.doi.org/10.1007/s11172-007-0118-9

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1046186025


Indexing Status Check whether this publication has been indexed by Scopus and Web Of Science using the SN Indexing Status Tool
Incoming Citations Browse incoming citations for this publication using opencitations.net

JSON-LD is the canonical representation for SciGraph data.

TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT

[
  {
    "@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json", 
    "about": [
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0399", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Other Chemical Sciences", 
        "type": "DefinedTerm"
      }, 
      {
        "id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03", 
        "inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/", 
        "name": "Chemical Sciences", 
        "type": "DefinedTerm"
      }
    ], 
    "author": [
      {
        "affiliation": {
          "alternateName": "Russian Academy of Sciences", 
          "id": "https://www.grid.ac/institutes/grid.4886.2", 
          "name": [
            "A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991, Moscow, Russian Federation"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Timofeev", 
        "givenName": "S. V.", 
        "id": "sg:person.013515115560.47", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013515115560.47"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Russian Academy of Sciences", 
          "id": "https://www.grid.ac/institutes/grid.4886.2", 
          "name": [
            "A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991, Moscow, Russian Federation"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Bregadze", 
        "givenName": "V. I.", 
        "id": "sg:person.01072634024.08", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01072634024.08"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Russian Academy of Sciences", 
          "id": "https://www.grid.ac/institutes/grid.4886.2", 
          "name": [
            "A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991, Moscow, Russian Federation"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Osipov", 
        "givenName": "S. N.", 
        "id": "sg:person.01211416630.10", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01211416630.10"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Moscow State University", 
          "id": "https://www.grid.ac/institutes/grid.14476.30", 
          "name": [
            "Department of Chemistry, M. V. Lomonosov Moscow State University, 1 Leninskie Gory, 119992, Moscow, Russian Federation"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Titanyuk", 
        "givenName": "I. D.", 
        "id": "sg:person.012366765151.31", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012366765151.31"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Russian Academy of Sciences", 
          "id": "https://www.grid.ac/institutes/grid.4886.2", 
          "name": [
            "A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991, Moscow, Russian Federation"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Petrovskii", 
        "givenName": "P. V.", 
        "id": "sg:person.014725472203.42", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014725472203.42"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Russian Academy of Sciences", 
          "id": "https://www.grid.ac/institutes/grid.4886.2", 
          "name": [
            "A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991, Moscow, Russian Federation"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Starikova", 
        "givenName": "Z. A.", 
        "id": "sg:person.014473641160.05", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014473641160.05"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Russian Academy of Sciences", 
          "id": "https://www.grid.ac/institutes/grid.4886.2", 
          "name": [
            "A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991, Moscow, Russian Federation"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Glukhov", 
        "givenName": "I. V.", 
        "id": "sg:person.014570657047.52", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014570657047.52"
        ], 
        "type": "Person"
      }, 
      {
        "affiliation": {
          "alternateName": "Moscow State University", 
          "id": "https://www.grid.ac/institutes/grid.14476.30", 
          "name": [
            "Department of Chemistry, M. V. Lomonosov Moscow State University, 1 Leninskie Gory, 119992, Moscow, Russian Federation"
          ], 
          "type": "Organization"
        }, 
        "familyName": "Beletskaya", 
        "givenName": "I. P.", 
        "id": "sg:person.01072276731.77", 
        "sameAs": [
          "https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01072276731.77"
        ], 
        "type": "Person"
      }
    ], 
    "citation": [
      {
        "id": "https://doi.org/10.1002/anie.199309501", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1003189122"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/cr941195u", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1053981434"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/cr941195u", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1053981434"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/jm00055a001", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055933820"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/jm00396a007", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1055946134"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/jo9608331", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056036034"
        ], 
        "type": "CreativeWork"
      }, 
      {
        "id": "https://doi.org/10.1021/jo9608331", 
        "sameAs": [
          "https://app.dimensions.ai/details/publication/pub.1056036034"
        ], 
        "type": "CreativeWork"
      }
    ], 
    "datePublished": "2007-04", 
    "datePublishedReg": "2007-04-01", 
    "description": "New alanine derivatives containing both the carboranyl and trifluoromethyl groups were synthesized by the reaction of organometallic derivatives of o-carborane with methyl trifluoropyruvate imines. When using the 1R-(\u2212)-menthoxycarbonyl protecting group at the nitrogen atom, one of diastereomers was isolated and characterized. Trifluoromethyl-carboranylalanine methyl esters containing different protecting groups at the nitrogen atom were studied by X-ray diffraction. Both complete and partial deprotection of the amino and carboxy groups was performed.", 
    "genre": "research_article", 
    "id": "sg:pub.10.1007/s11172-007-0118-9", 
    "inLanguage": [
      "en"
    ], 
    "isAccessibleForFree": false, 
    "isPartOf": [
      {
        "id": "sg:journal.1022309", 
        "issn": [
          "1066-5285", 
          "1573-9171"
        ], 
        "name": "Russian Chemical Bulletin", 
        "type": "Periodical"
      }, 
      {
        "issueNumber": "4", 
        "type": "PublicationIssue"
      }, 
      {
        "type": "PublicationVolume", 
        "volumeNumber": "56"
      }
    ], 
    "name": "New carborane-containing amino acids and their derivatives. Crystal structures of n-protected carboranylalaninates", 
    "pagination": "791-797", 
    "productId": [
      {
        "name": "readcube_id", 
        "type": "PropertyValue", 
        "value": [
          "dc01ae4f099fe587110c2f8d25b41525999f61e817c57cf717126fe8cc43692b"
        ]
      }, 
      {
        "name": "doi", 
        "type": "PropertyValue", 
        "value": [
          "10.1007/s11172-007-0118-9"
        ]
      }, 
      {
        "name": "dimensions_id", 
        "type": "PropertyValue", 
        "value": [
          "pub.1046186025"
        ]
      }
    ], 
    "sameAs": [
      "https://doi.org/10.1007/s11172-007-0118-9", 
      "https://app.dimensions.ai/details/publication/pub.1046186025"
    ], 
    "sdDataset": "articles", 
    "sdDatePublished": "2019-04-11T02:14", 
    "sdLicense": "https://scigraph.springernature.com/explorer/license/", 
    "sdPublisher": {
      "name": "Springer Nature - SN SciGraph project", 
      "type": "Organization"
    }, 
    "sdSource": "s3://com-uberresearch-data-dimensions-target-20181106-alternative/cleanup/v134/2549eaecd7973599484d7c17b260dba0a4ecb94b/merge/v9/a6c9fde33151104705d4d7ff012ea9563521a3ce/jats-lookup/v90/0000000001_0000000264/records_8700_00000534.jsonl", 
    "type": "ScholarlyArticle", 
    "url": "http://link.springer.com/10.1007%2Fs11172-007-0118-9"
  }
]
 

Download the RDF metadata as:  json-ld nt turtle xml License info

HOW TO GET THIS DATA PROGRAMMATICALLY:

JSON-LD is a popular format for linked data which is fully compatible with JSON.

curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/s11172-007-0118-9'

N-Triples is a line-based linked data format ideal for batch operations.

curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/s11172-007-0118-9'

Turtle is a human-readable linked data format.

curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/s11172-007-0118-9'

RDF/XML is a standard XML format for linked data.

curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/s11172-007-0118-9'


 

This table displays all metadata directly associated to this object as RDF triples.

128 TRIPLES      21 PREDICATES      32 URIs      19 LITERALS      7 BLANK NODES

Subject Predicate Object
1 sg:pub.10.1007/s11172-007-0118-9 schema:about anzsrc-for:03
2 anzsrc-for:0399
3 schema:author Nf551904d923144f18eebd36a58cfb868
4 schema:citation https://doi.org/10.1002/anie.199309501
5 https://doi.org/10.1021/cr941195u
6 https://doi.org/10.1021/jm00055a001
7 https://doi.org/10.1021/jm00396a007
8 https://doi.org/10.1021/jo9608331
9 schema:datePublished 2007-04
10 schema:datePublishedReg 2007-04-01
11 schema:description New alanine derivatives containing both the carboranyl and trifluoromethyl groups were synthesized by the reaction of organometallic derivatives of o-carborane with methyl trifluoropyruvate imines. When using the 1R-(−)-menthoxycarbonyl protecting group at the nitrogen atom, one of diastereomers was isolated and characterized. Trifluoromethyl-carboranylalanine methyl esters containing different protecting groups at the nitrogen atom were studied by X-ray diffraction. Both complete and partial deprotection of the amino and carboxy groups was performed.
12 schema:genre research_article
13 schema:inLanguage en
14 schema:isAccessibleForFree false
15 schema:isPartOf N418da972691e4422b880eaab980c3485
16 Nfb33385e17c94075a46dcebe7b234d2c
17 sg:journal.1022309
18 schema:name New carborane-containing amino acids and their derivatives. Crystal structures of n-protected carboranylalaninates
19 schema:pagination 791-797
20 schema:productId N8414de64dd244d6b8fa31afb15ab972d
21 N95613cb6481e44c09d89e113b6f1cfe9
22 Nf65037d1e35d45f58f8d00cadfdbde56
23 schema:sameAs https://app.dimensions.ai/details/publication/pub.1046186025
24 https://doi.org/10.1007/s11172-007-0118-9
25 schema:sdDatePublished 2019-04-11T02:14
26 schema:sdLicense https://scigraph.springernature.com/explorer/license/
27 schema:sdPublisher N1d71de217aaa40268a3b75724f08d9cf
28 schema:url http://link.springer.com/10.1007%2Fs11172-007-0118-9
29 sgo:license sg:explorer/license/
30 sgo:sdDataset articles
31 rdf:type schema:ScholarlyArticle
32 N12e6a16741dd44c2aa8e3474ce774770 rdf:first sg:person.01072634024.08
33 rdf:rest N2be5e1acda9744fa944e0f0c1ef33581
34 N1d71de217aaa40268a3b75724f08d9cf schema:name Springer Nature - SN SciGraph project
35 rdf:type schema:Organization
36 N2be5e1acda9744fa944e0f0c1ef33581 rdf:first sg:person.01211416630.10
37 rdf:rest N95e7f038d8a2459fb83afecb18b1b275
38 N418da972691e4422b880eaab980c3485 schema:issueNumber 4
39 rdf:type schema:PublicationIssue
40 N8414de64dd244d6b8fa31afb15ab972d schema:name dimensions_id
41 schema:value pub.1046186025
42 rdf:type schema:PropertyValue
43 N95613cb6481e44c09d89e113b6f1cfe9 schema:name doi
44 schema:value 10.1007/s11172-007-0118-9
45 rdf:type schema:PropertyValue
46 N95e7f038d8a2459fb83afecb18b1b275 rdf:first sg:person.012366765151.31
47 rdf:rest Nbf47cf3d3b9d4e1dbe617e7eeaa0800f
48 Nbf47cf3d3b9d4e1dbe617e7eeaa0800f rdf:first sg:person.014725472203.42
49 rdf:rest Nf239b93619e24e619509f8949e48ad5e
50 Ne30edef47dba4393abaaba055a7d2711 rdf:first sg:person.014570657047.52
51 rdf:rest Ne6448b5c38264d64821d86bcf735f5aa
52 Ne6448b5c38264d64821d86bcf735f5aa rdf:first sg:person.01072276731.77
53 rdf:rest rdf:nil
54 Nf239b93619e24e619509f8949e48ad5e rdf:first sg:person.014473641160.05
55 rdf:rest Ne30edef47dba4393abaaba055a7d2711
56 Nf551904d923144f18eebd36a58cfb868 rdf:first sg:person.013515115560.47
57 rdf:rest N12e6a16741dd44c2aa8e3474ce774770
58 Nf65037d1e35d45f58f8d00cadfdbde56 schema:name readcube_id
59 schema:value dc01ae4f099fe587110c2f8d25b41525999f61e817c57cf717126fe8cc43692b
60 rdf:type schema:PropertyValue
61 Nfb33385e17c94075a46dcebe7b234d2c schema:volumeNumber 56
62 rdf:type schema:PublicationVolume
63 anzsrc-for:03 schema:inDefinedTermSet anzsrc-for:
64 schema:name Chemical Sciences
65 rdf:type schema:DefinedTerm
66 anzsrc-for:0399 schema:inDefinedTermSet anzsrc-for:
67 schema:name Other Chemical Sciences
68 rdf:type schema:DefinedTerm
69 sg:journal.1022309 schema:issn 1066-5285
70 1573-9171
71 schema:name Russian Chemical Bulletin
72 rdf:type schema:Periodical
73 sg:person.01072276731.77 schema:affiliation https://www.grid.ac/institutes/grid.14476.30
74 schema:familyName Beletskaya
75 schema:givenName I. P.
76 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01072276731.77
77 rdf:type schema:Person
78 sg:person.01072634024.08 schema:affiliation https://www.grid.ac/institutes/grid.4886.2
79 schema:familyName Bregadze
80 schema:givenName V. I.
81 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01072634024.08
82 rdf:type schema:Person
83 sg:person.01211416630.10 schema:affiliation https://www.grid.ac/institutes/grid.4886.2
84 schema:familyName Osipov
85 schema:givenName S. N.
86 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01211416630.10
87 rdf:type schema:Person
88 sg:person.012366765151.31 schema:affiliation https://www.grid.ac/institutes/grid.14476.30
89 schema:familyName Titanyuk
90 schema:givenName I. D.
91 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012366765151.31
92 rdf:type schema:Person
93 sg:person.013515115560.47 schema:affiliation https://www.grid.ac/institutes/grid.4886.2
94 schema:familyName Timofeev
95 schema:givenName S. V.
96 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.013515115560.47
97 rdf:type schema:Person
98 sg:person.014473641160.05 schema:affiliation https://www.grid.ac/institutes/grid.4886.2
99 schema:familyName Starikova
100 schema:givenName Z. A.
101 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014473641160.05
102 rdf:type schema:Person
103 sg:person.014570657047.52 schema:affiliation https://www.grid.ac/institutes/grid.4886.2
104 schema:familyName Glukhov
105 schema:givenName I. V.
106 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014570657047.52
107 rdf:type schema:Person
108 sg:person.014725472203.42 schema:affiliation https://www.grid.ac/institutes/grid.4886.2
109 schema:familyName Petrovskii
110 schema:givenName P. V.
111 schema:sameAs https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.014725472203.42
112 rdf:type schema:Person
113 https://doi.org/10.1002/anie.199309501 schema:sameAs https://app.dimensions.ai/details/publication/pub.1003189122
114 rdf:type schema:CreativeWork
115 https://doi.org/10.1021/cr941195u schema:sameAs https://app.dimensions.ai/details/publication/pub.1053981434
116 rdf:type schema:CreativeWork
117 https://doi.org/10.1021/jm00055a001 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055933820
118 rdf:type schema:CreativeWork
119 https://doi.org/10.1021/jm00396a007 schema:sameAs https://app.dimensions.ai/details/publication/pub.1055946134
120 rdf:type schema:CreativeWork
121 https://doi.org/10.1021/jo9608331 schema:sameAs https://app.dimensions.ai/details/publication/pub.1056036034
122 rdf:type schema:CreativeWork
123 https://www.grid.ac/institutes/grid.14476.30 schema:alternateName Moscow State University
124 schema:name Department of Chemistry, M. V. Lomonosov Moscow State University, 1 Leninskie Gory, 119992, Moscow, Russian Federation
125 rdf:type schema:Organization
126 https://www.grid.ac/institutes/grid.4886.2 schema:alternateName Russian Academy of Sciences
127 schema:name A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991, Moscow, Russian Federation
128 rdf:type schema:Organization
 




Preview window. Press ESC to close (or click here)


...