Unusual magnetic behavior of the new supramolecular ensemble [Ni2L4]2·[NiCl2(LH)2(MeCN)2]·4MeCN (LH is 2-mercaptobenzimidazole) View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2006-12

AUTHORS

M. E. Nikiforova, M. O. Talismanova, G. G. Aleksandrov, S. K. Kotovskaya, A. A. Sidorov, V. M. Novotortsev, V. N. Ikorskii, V. N. Charushin, I. L. Eremenko, I. I. Moiseev

ABSTRACT

The diamagnetic dinuclear complex Ni2L4 was synthesized by the reaction of NiCl2·6H2O with 2-mercaptobenzimidazole (LH) in ethanol in the presence of Et3N. The solid-state reaction (reagent ratio Ni: LH = 1: 2) followed by recrystallization of the reaction product from a MeCN-THF mixture afforded crystals of the associate [Ni2L4]2·[NiCl2(LH)2(MeCN)2] containing four acetonitrile solvate molecules. Crystals of 2·4MeCN exhibit ferromagnetic properties at helium temperatures. More... »

PAGES

2181-2186

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s11172-006-0570-y

DOI

http://dx.doi.org/10.1007/s11172-006-0570-y

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1035310381


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