Reaction of 2-methyl-3-morpholino-1-phenylprop-2-en-1-one with Ru3(CO)12 View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2006-12-01

AUTHORS

N. A. Shtel’tser, S. V. Osintseva, P. V. Petrovskii, A. Z. Kreindlin, F. M. Dolgushin

ABSTRACT

The reaction of Ru3(CO)12 with 2-methyl-3-morpholino-1-phenylprop-2-en-1-one (1) produced the Ru6(CO)16(µ4-η1:η1:η2:η2-PhC(O)-C(Me)=C)2 (2), Ru2O2(CO)4(η3-OC(Ph)C(Me)C(H)C(Me)2C(Ph))2 (3), and [Ru(CO)2(PhCO2)(O(CH2-CH2)2NH]2 (4) complexes, which were characterized by IR and NMR spectroscopy. The structures of the complexes were established by X-ray diffraction. The formation of the complexes is accompanied by deamination of ligand 1. Complexes 2 and 3 bearing the vinyl ketone groups contain five-membered oxaruthenacycles and dihydropyran rings. Morpholine is not removed from the reaction mixture and leads to the formation of complex 4. More... »

PAGES

2143-2148

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s11172-006-0565-8

DOI

http://dx.doi.org/10.1007/s11172-006-0565-8

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1008797337


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