Synthesis and comparative X-ray diffraction study of first ruthenocene-based pincer palladium complexes, PdCl[{2,5-(But2PCH2)2C5H2}Ru(Cp′)] (Cp′ = C5H5 or C5Me5) View Full Text


Ontology type: schema:ScholarlyArticle     


Article Info

DATE

2006-11

AUTHORS

S. A. Kuklin, F. M. Dolgushin, P. V. Petrovskii, A. A. Koridze

ABSTRACT

First ruthenocene-based palladium complexes PdCl[{2,5-(But2PCH2)2C5H2} Ru(Cp′)] (Cp′ = C5H5 (4) or C5Me5 (5)) were synthesized. Comparative single-crystal X-ray diffraction study of complexes 4 and 5 showed that the deviations of the cyclopentadienyl rings in these complexes from being parallel are 2.6 and 10.1°, respectively. In addition, the shift of the palladium atom relative to the plane of the metallated cyclopentadienyl ligand is 0.007 Å for 4 and 0.336 Å for 5. These differences in the structures of complexes 4 and 5 are due to close contacts between the pseudoequatorial tert-butyl groups at the phosphorus atoms and the unmetallated cyclopentadienyl ring. More... »

PAGES

1950-1955

Identifiers

URI

http://scigraph.springernature.com/pub.10.1007/s11172-006-0536-0

DOI

http://dx.doi.org/10.1007/s11172-006-0536-0

DIMENSIONS

https://app.dimensions.ai/details/publication/pub.1039688893


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