Ontology type: schema:ScholarlyArticle
2006-11
AUTHORSV. I. Ovcharenko, S. V. Fokin, G. V. Romanenko, V. N. Ikorskii, R. Z. Sagdeev, D. S. Yachevskii, D. L. Chizhov, V. N. Charushin
ABSTRACTHeterospin complexes of bis(μ2-1,1,2,2,8,8,9,9-octafluorononane-3,5,7-trionato)dicopper(II) ([Cu2L2]) with nitronyl nitroxides 2-(1-methyl-1H-pyrazol-4-yl)-4,4,5,5-tetramethyl-4,5-dihydro-1H-imidazole-1-oxyl 3-oxide (2) and 4,4,5,5-tetramethyl-2-(3-pyridinyl)-4,5-dihydro-1H-imidazole-1-oxyl 3-oxide (1) were synthesized and structurally characterized. Crystals of the complexes are formed by the discrete bis[1-methyl-4-(4,4,5,5-tetramethyl-3-oxide-1-oxyl-4,5-dihydro-1H-imidazol-2-yl)-1H-pyrazole]-bis (μ2-1,1,2,2,8,8,9,9-octafluorononane-3,5,7-trionato)dicopper(II) etherate (3) and bis[3-(4,4,5,5-tetramethyl-3-oxide-1-oxyl-4,5-dihydro-1H-imidazol-2-yl)pyridine]-bis (μ2-1,1,2,2,8,8,9,9-octafluorononane-3,5,7-trionato)dicopper(II) (4) molecules. Each Cu atom of the dinuclear chelate fragment coordinates one paramagnetic ligand through the N atom of the pyrazole or pyridine fragment, respectively. In complex 3, the paramagnetic ligands are located on one side of the plane of the chelate fragment, whereas the ligands in complex 4 are located above and below the plane of the chelate fragment. The magnetic properties of complexes 3 and 4 are determined by dominant antiferromagnetic exchange interactions between the unpaired electrons of the CuII atoms in the dinuclear Cu2L2 moiety. More... »
PAGES1904-1908
http://scigraph.springernature.com/pub.10.1007/s11172-006-0531-5
DOIhttp://dx.doi.org/10.1007/s11172-006-0531-5
DIMENSIONShttps://app.dimensions.ai/details/publication/pub.1014341460
JSON-LD is the canonical representation for SciGraph data.
TIP: You can open this SciGraph record using an external JSON-LD service: JSON-LD Playground Google SDTT
[
{
"@context": "https://springernature.github.io/scigraph/jsonld/sgcontext.json",
"about": [
{
"id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/03",
"inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/",
"name": "Chemical Sciences",
"type": "DefinedTerm"
},
{
"id": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/0302",
"inDefinedTermSet": "http://purl.org/au-research/vocabulary/anzsrc-for/2008/",
"name": "Inorganic Chemistry",
"type": "DefinedTerm"
}
],
"author": [
{
"affiliation": {
"alternateName": "International Tomography Center, Siberian Branch of the Russian Academy of Sciences, 3a ul. Institutskaya, 630090, Novosibirsk, Russian Federation",
"id": "http://www.grid.ac/institutes/grid.415877.8",
"name": [
"International Tomography Center, Siberian Branch of the Russian Academy of Sciences, 3a ul. Institutskaya, 630090, Novosibirsk, Russian Federation"
],
"type": "Organization"
},
"familyName": "Ovcharenko",
"givenName": "V. I.",
"id": "sg:person.0732145436.56",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0732145436.56"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "International Tomography Center, Siberian Branch of the Russian Academy of Sciences, 3a ul. Institutskaya, 630090, Novosibirsk, Russian Federation",
"id": "http://www.grid.ac/institutes/grid.415877.8",
"name": [
"International Tomography Center, Siberian Branch of the Russian Academy of Sciences, 3a ul. Institutskaya, 630090, Novosibirsk, Russian Federation"
],
"type": "Organization"
},
"familyName": "Fokin",
"givenName": "S. V.",
"id": "sg:person.016617640525.03",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.016617640525.03"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "International Tomography Center, Siberian Branch of the Russian Academy of Sciences, 3a ul. Institutskaya, 630090, Novosibirsk, Russian Federation",
"id": "http://www.grid.ac/institutes/grid.415877.8",
"name": [
"International Tomography Center, Siberian Branch of the Russian Academy of Sciences, 3a ul. Institutskaya, 630090, Novosibirsk, Russian Federation"
],
"type": "Organization"
},
"familyName": "Romanenko",
"givenName": "G. V.",
"id": "sg:person.0664032236.40",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0664032236.40"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "International Tomography Center, Siberian Branch of the Russian Academy of Sciences, 3a ul. Institutskaya, 630090, Novosibirsk, Russian Federation",
"id": "http://www.grid.ac/institutes/grid.415877.8",
"name": [
"International Tomography Center, Siberian Branch of the Russian Academy of Sciences, 3a ul. Institutskaya, 630090, Novosibirsk, Russian Federation"
],
"type": "Organization"
},
"familyName": "Ikorskii",
"givenName": "V. N.",
"id": "sg:person.012705501235.78",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012705501235.78"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "International Tomography Center, Siberian Branch of the Russian Academy of Sciences, 3a ul. Institutskaya, 630090, Novosibirsk, Russian Federation",
"id": "http://www.grid.ac/institutes/grid.415877.8",
"name": [
"International Tomography Center, Siberian Branch of the Russian Academy of Sciences, 3a ul. Institutskaya, 630090, Novosibirsk, Russian Federation"
],
"type": "Organization"
},
"familyName": "Sagdeev",
"givenName": "R. Z.",
"id": "sg:person.0771743570.83",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0771743570.83"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "I. Ya. Postovsky Institute of Organic Synthesis, Ural Branch of the Russian Academy of Sciences, 22 ul. S. Kovalevskoi, 620219, Ekaterinburg, Russian Federation",
"id": "http://www.grid.ac/institutes/grid.426536.0",
"name": [
"I. Ya. Postovsky Institute of Organic Synthesis, Ural Branch of the Russian Academy of Sciences, 22 ul. S. Kovalevskoi, 620219, Ekaterinburg, Russian Federation"
],
"type": "Organization"
},
"familyName": "Yachevskii",
"givenName": "D. S.",
"id": "sg:person.0611210623.05",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.0611210623.05"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "I. Ya. Postovsky Institute of Organic Synthesis, Ural Branch of the Russian Academy of Sciences, 22 ul. S. Kovalevskoi, 620219, Ekaterinburg, Russian Federation",
"id": "http://www.grid.ac/institutes/grid.426536.0",
"name": [
"I. Ya. Postovsky Institute of Organic Synthesis, Ural Branch of the Russian Academy of Sciences, 22 ul. S. Kovalevskoi, 620219, Ekaterinburg, Russian Federation"
],
"type": "Organization"
},
"familyName": "Chizhov",
"givenName": "D. L.",
"id": "sg:person.01266501523.41",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.01266501523.41"
],
"type": "Person"
},
{
"affiliation": {
"alternateName": "I. Ya. Postovsky Institute of Organic Synthesis, Ural Branch of the Russian Academy of Sciences, 22 ul. S. Kovalevskoi, 620219, Ekaterinburg, Russian Federation",
"id": "http://www.grid.ac/institutes/grid.426536.0",
"name": [
"I. Ya. Postovsky Institute of Organic Synthesis, Ural Branch of the Russian Academy of Sciences, 22 ul. S. Kovalevskoi, 620219, Ekaterinburg, Russian Federation"
],
"type": "Organization"
},
"familyName": "Charushin",
"givenName": "V. N.",
"id": "sg:person.012401643101.50",
"sameAs": [
"https://app.dimensions.ai/discover/publication?and_facet_researcher=ur.012401643101.50"
],
"type": "Person"
}
],
"datePublished": "2006-11",
"datePublishedReg": "2006-11-01",
"description": "Heterospin complexes of bis(\u03bc2-1,1,2,2,8,8,9,9-octafluorononane-3,5,7-trionato)dicopper(II) ([Cu2L2]) with nitronyl nitroxides 2-(1-methyl-1H-pyrazol-4-yl)-4,4,5,5-tetramethyl-4,5-dihydro-1H-imidazole-1-oxyl 3-oxide (2) and 4,4,5,5-tetramethyl-2-(3-pyridinyl)-4,5-dihydro-1H-imidazole-1-oxyl 3-oxide (1) were synthesized and structurally characterized. Crystals of the complexes are formed by the discrete bis[1-methyl-4-(4,4,5,5-tetramethyl-3-oxide-1-oxyl-4,5-dihydro-1H-imidazol-2-yl)-1H-pyrazole]-bis (\u03bc2-1,1,2,2,8,8,9,9-octafluorononane-3,5,7-trionato)dicopper(II) etherate (3) and bis[3-(4,4,5,5-tetramethyl-3-oxide-1-oxyl-4,5-dihydro-1H-imidazol-2-yl)pyridine]-bis (\u03bc2-1,1,2,2,8,8,9,9-octafluorononane-3,5,7-trionato)dicopper(II) (4) molecules. Each Cu atom of the dinuclear chelate fragment coordinates one paramagnetic ligand through the N atom of the pyrazole or pyridine fragment, respectively. In complex 3, the paramagnetic ligands are located on one side of the plane of the chelate fragment, whereas the ligands in complex 4 are located above and below the plane of the chelate fragment. The magnetic properties of complexes 3 and 4 are determined by dominant antiferromagnetic exchange interactions between the unpaired electrons of the CuII atoms in the dinuclear Cu2L2 moiety.",
"genre": "article",
"id": "sg:pub.10.1007/s11172-006-0531-5",
"inLanguage": "en",
"isAccessibleForFree": false,
"isPartOf": [
{
"id": "sg:journal.1022309",
"issn": [
"1063-5211",
"1026-3500"
],
"name": "Russian Chemical Bulletin",
"publisher": "Springer Nature",
"type": "Periodical"
},
{
"issueNumber": "11",
"type": "PublicationIssue"
},
{
"type": "PublicationVolume",
"volumeNumber": "55"
}
],
"keywords": [
"chelate fragment",
"paramagnetic ligands",
"heterospin complexes",
"nitronyl nitroxide 2",
"antiferromagnetic exchange interactions",
"dominant antiferromagnetic exchange interactions",
"complexes 3",
"CuII atom",
"pyridine fragment",
"unpaired electron",
"N atoms",
"Cu atoms",
"oxyl",
"methyl-4",
"ligands",
"tetramethyl-2",
"magnetic properties",
"atoms",
"complexes",
"\u03bc2",
"exchange interaction",
"Bi",
"tetramethyl",
"moiety",
"pyrazole",
"etherate",
"molecules",
"fragments",
"crystals",
"electrons",
"properties",
"interaction",
"plane",
"side"
],
"name": "Heterospin complexes based on dinuclear CuII triketonate and nitroxides",
"pagination": "1904-1908",
"productId": [
{
"name": "dimensions_id",
"type": "PropertyValue",
"value": [
"pub.1014341460"
]
},
{
"name": "doi",
"type": "PropertyValue",
"value": [
"10.1007/s11172-006-0531-5"
]
}
],
"sameAs": [
"https://doi.org/10.1007/s11172-006-0531-5",
"https://app.dimensions.ai/details/publication/pub.1014341460"
],
"sdDataset": "articles",
"sdDatePublished": "2022-05-10T09:55",
"sdLicense": "https://scigraph.springernature.com/explorer/license/",
"sdPublisher": {
"name": "Springer Nature - SN SciGraph project",
"type": "Organization"
},
"sdSource": "s3://com-springernature-scigraph/baseset/20220509/entities/gbq_results/article/article_429.jsonl",
"type": "ScholarlyArticle",
"url": "https://doi.org/10.1007/s11172-006-0531-5"
}
]Download the RDF metadata as: json-ld nt turtle xml License info
JSON-LD is a popular format for linked data which is fully compatible with JSON.
curl -H 'Accept: application/ld+json' 'https://scigraph.springernature.com/pub.10.1007/s11172-006-0531-5'
N-Triples is a line-based linked data format ideal for batch operations.
curl -H 'Accept: application/n-triples' 'https://scigraph.springernature.com/pub.10.1007/s11172-006-0531-5'
Turtle is a human-readable linked data format.
curl -H 'Accept: text/turtle' 'https://scigraph.springernature.com/pub.10.1007/s11172-006-0531-5'
RDF/XML is a standard XML format for linked data.
curl -H 'Accept: application/rdf+xml' 'https://scigraph.springernature.com/pub.10.1007/s11172-006-0531-5'
This table displays all metadata directly associated to this object as RDF triples.
144 TRIPLES
21 PREDICATES
60 URIs
52 LITERALS
6 BLANK NODES